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Nylon catalysts

The addition of tin to Pt led to an increase in the turnover frequency (TOF) by a factor of 2. TOF showed maximum at surface atomic ratio of Sn/Pt = 1 as shown in Figure 17. These results are in good agreement with earlier findings obtained in the liquid-phase hydrogenation of benzonitrile on catalysts prepared by the addition of tin chloride to Pt/nylon catalyst. ... [Pg.30]

High catalytic activity is exhibited when one unit cell of NHCO is occupied by one (Pt)2 or (Pt)3 cluster. Hydrogen activation is caused by decomposition of H2 molecules to the atomic state with subsequent formation of the hydride complex. Oxidation-reduction titration as well as electron-microscopy measurements show the incorporation of Pd crystallites inside nylon grains [114]. Most have a mean diameter of about 30 A. However, under the assumption that all the metal is located on the polymeric support surface, the calculated accessible metal surface amounts to several hundred Angstroms. Therefore, during preparation of the Pd-nylon catalyst, part of the metal penetrates into the organic matrix. [Pg.89]

Whereas cyclohexene and cyclohexane were formed by hydrogenation of benzene with a Pt/nylon catalyst, only cyclohexane was detected with a Pt/Si02 catalyst [119]. Increased selectivity was observed for cyclohexane at elevated temperatures and after air pretreatment. Apparently oxidized platinum particles were responsible for cyclohexene formation. [Pg.90]

Colourless liquid with a strong peppermintlike odour b.p. 155" C. Manufactured by passing cyclohexanol vapour over a heated copper catalyst. Volatile in steam. Oxidized to adipic acid. Used in the manufacture of caprolactam. Nylon, adipic acid, nitrocellulose lacquers, celluloid, artificial leather and printing inks. [Pg.122]

C, b.p. 81"C. Manufactured by the reduction of benzene with hydrogen in the presence of a nickel catalyst and recovered from natural gase.s. It is inflammable. Used as an intermediate in the preparation of nylon [6] and [66] via caprolactam and as a solvent for oils, fats and waxes, and also as a paint remover. For stereochemistry of cyclohexane see conformation. U.S. production 1980 1 megatonne. [Pg.122]

C, b.p. 16UC. Manufactured by heating phenol with hydrogen under pressure in the presence of suitable catalysts. Oxidized to adipic acid (main use as intermediate for nylon production) dehydrogenated to cyclohexanone. [Pg.122]

Reaction (5.N) describes the nylon salt nylon equilibrium. Reactions (5.0) and (5.P) show proton transfer with water between carboxyl and amine groups. Since proton transfer equilibria are involved, the self-ionization of water, reaction (5.Q), must also be included. Especially in the presence of acidic catalysts, reactions (5.R) and (5.S) are the equilibria of the acid-catalyzed intermediate described in general in reaction (5.G). The main point in including all of these equilibria is to indicate that the precise concentration of A and B... [Pg.306]

As improvements over P-methylumbeUiferone (55—57), 4-methyl-7-amino-coumarin [26093-31-2] (12a) and 7-dimethylamino-4-methylcoumarin [87-014] (12b) (58—61) were proposed. These compounds are used for brightening wool and nylon either in soap powders or detergents, or as salts under acid dyeing conditions. They are obtained by the Pechmaim synthesis from appropriately substituted phenols and P-ketocarboxyflc acid esters or nitriles in the presence of Lewis acid catalysts (see Coumarin). [Pg.117]

Cyclohexane. The LPO of cyclohexane [110-82-7] suppUes much of the raw materials needed for nylon-6 and nylon-6,6 production. Cyclohexanol (A) and cyclohexanone (K) maybe produced selectively by using alow conversion process with multiple stages (228—232). The reasons for low conversion and multiple stages (an approach to plug-flow operation) are apparent from Eigure 2. Several catalysts have been reported. The selectivity to A as well as the overall process efficiency can be improved by using boric acid (2,232,233). K/A mixtures are usually oxidized by nitric acid in a second step to adipic acid (233) (see Cyclohexanol and cyclohexanone). [Pg.344]

Catalysts. Iodine and its compounds ate very active catalysts for many reactions (133). The principal use is in the production of synthetic mbber via Ziegler-Natta catalysts systems. Also, iodine and certain iodides, eg, titanium tetraiodide [7720-83-4], are employed for producing stereospecific polymers, such as polybutadiene mbber (134) about 75% of the iodine consumed in catalysts is assumed to be used for polybutadiene and polyisoprene polymeri2a tion (66) (see RUBBER CHEMICALS). Hydrogen iodide is used as a catalyst in the manufacture of acetic acid from methanol (66). A 99% yield as acetic acid has been reported. In the heat stabiH2ation of nylon suitable for tire cordage, iodine is used in a system involving copper acetate or borate, and potassium iodide (66) (see Tire cords). [Pg.366]

Lewis acids, such as the haUde salts of the alkaline-earth metals, Cu(I), Cu(II), 2inc, Fe(III), aluminum, etc, are effective catalysts for this reaction (63). The ammonolysis of polyamides obtained from post-consumer waste has been used to cleave the polymer chain as the first step in a recycle process in which mixtures of nylon-6,6 and nylon-6 can be reconverted to diamine (64). The advantage of this approach Hes in the fact that both the adipamide [628-94-4] and 6-aminohexanoamide can be converted to hexarnethylenediarnine via their respective nitriles in a conventional two-step process in the presence of the diamine formed in the original ammonolysis reaction, thus avoiding a difficult and cosdy separation process. In addition, the mixture of nylon-6,6 and nylon-6 appears to react faster than does either polyamide alone. [Pg.225]

Adipic acid (qv) has a wide variety of commercial uses besides the manufacture of nylon-6,6, and thus is a common industrial chemical. Many routes to its manufacture have been developed over the years but most processes in commercial use proceed through a two-step oxidation of cyclohexane [110-83-8] or one of its derivatives. In the first step, cyclohexane is oxidized with air at elevated temperatures usually in the presence of a suitable catalyst to produce a mixture of cyclohexanone [108-94-1] and cyclohexanol [108-93-0] commonly abbreviated KA (ketone—alcohol) or KA oil ... [Pg.232]

Nylon-11. Nylon-11 [25035-04-5] made by the polycondensation of 11-aminoundecanoic acid [2432-99-7] was first prepared by Carothers in 1935 but was first produced commercially in 1955 in France under the trade name Kilsan (167) Kilsan is a registered trademark of Elf Atochem Company. The polymer is prepared in a continuous process using phosphoric or hypophosphoric acid as a catalyst under inert atmosphere at ambient pressure. The total extractable content is low (0.5%) compared to nylon-6 (168). The polymer is hydrophobic, with a low melt point (T = 190° C), and has excellent electrical insulating properties. The effect of formic acid on the swelling behavior of nylon-11 has been studied (169), and such a treatment is claimed to produce a hard elastic fiber (170). [Pg.236]

Its manufacture begins with the formation of dodecanedioic acid produced from the trimeri2ation of butadiene in a process identical to that used in the manufacture of nylon-6,12. The other starting material, 1,12-dodecanediamine, is prepared in a two-step process that first converts the dodecanedioic acid to a diamide, and then continues to dehydrate the diamide to the dinitrile. In the second step, the dinitrile is then hydrogenated to the diamine with hydrogen in the presence of a suitable catalyst. [Pg.236]

In Europe, 1. G. Earbenindustrie decided to develop nylon-6 that had been synthesized from S-caprolactam using an aminocaproic acid catalyst (1) and commercially introduced as Pedon L in 1940 (11,12). 1. G. Earbenindustrie had evaluated over 3000 polyamide constituents without finding an improvement over nylon-6 and nylon-6,6 (13). In Italy, Societa Rhodiaceta started making nylon-6,6 in 1939. In the United Kingdom, ICl and Courtaulds formed British Nylon Spinners in 1940 and started to manufacture nylon-6,6 in 1941. [Pg.246]

Nylon-6 can also be produced from molten caprolactam using strong bases as catalysts (anionic polymerization) this is used as the basis of monomer casting and reaction injection mol ding (RIM). Anionic polymerization proceeds much faster than the hydrolytic route but products retain catalysts which may need to be extracted. [Pg.271]

Nylon-11. This nylon is produced from 11-aminoundecanoic acid, which is derived from castor oil. The acid is polymerized by heating to 200°C with continuous removal of water. Catalysts such as phosphoric acid are frequentiy used. There is no appreciable amount of unreacted monomer left in the product. [Pg.271]

The process uses a catalyst and higher temperatures than nylon-6 (300—350°C) on account of the stabihty of the 13-membered ring. Again, there is Htde residual unreacted monomer. [Pg.272]

Reaction Injection Molding. RIM uses the anionic polymeri2ation of nylon-6 to carry out polymeri2ation in the mold. A commercial process involves the production of block copolymers of nylon-6 and a polyether by mixing molten caprolactam, catalyst, and polyether prepolymer, and reacting in a mold (27,28). [Pg.274]

Flame Retardants. Flame retardants are added to nylon to eliminate burning drips and to obtain short self-extinguishing times. Halogenated organics, together with catalysts such as antimony trioxide, are commonly used to give free-radical suppression in the vapor phase, thus inhibiting the combustion process. Some common additives are decabromodiphenyl oxide, brominated polystyrene, and chlorinated... [Pg.274]

The solution (pad bath) contains one or more of the amino resias described above, a catalyst, and other additives such as a softener, a stiffening agent, or a water repeUant. The catalyst may be an ammonium or metal salt, eg, magnesium chloride or ziac nitrate. Synthetic fabrics, such as nylon or polyester, are treated with amino resias to obtaia a stiff finish. Cotton (qv) or rayon fabrics or blends with synthetic fibers are treated with amino resias to obtain shrinkage control and a durable-press finish. [Pg.331]

Benzoic Acid. Ben2oic acid is manufactured from toluene by oxidation in the liquid phase using air and a cobalt catalyst. Typical conditions are 308—790 kPa (30—100 psi) and 130—160°C. The cmde product is purified by distillation, crystallization, or both. Yields are generally >90 mol%, and product purity is generally >99%. Kalama Chemical Company, the largest producer, converts about half of its production to phenol, but most producers consider the most economic process for phenol to be peroxidation of cumene. Other uses of benzoic acid are for the manufacture of benzoyl chloride, of plasticizers such as butyl benzoate, and of sodium benzoate for use in preservatives. In Italy, Snia Viscosa uses benzoic acid as raw material for the production of caprolactam, and subsequendy nylon-6, by the sequence shown below. [Pg.191]

AH commercial processes for the manufacture of caprolactam ate based on either toluene or benzene, each of which occurs in refinery BTX-extract streams (see BTX processing). Alkylation of benzene with propylene yields cumene (qv), which is a source of phenol and acetone ca 10% of U.S. phenol is converted to caprolactam. Purified benzene can be hydrogenated over platinum catalyst to cyclohexane nearly aH of the latter is used in the manufacture of nylon-6 and nylon-6,6 chemical intermediates. A block diagram of the five main process routes to caprolactam from basic taw materials, eg, hydrogen (which is usuaHy prepared from natural gas) and sulfur, is given in Eigute 2. [Pg.428]

Rhodium catalyst is used to convert linear alpha-olefins to heptanoic and pelargonic acids (see Carboxylic acids, manufacture). These acids can also be made from the ozonolysis of oleic acid, as done by the Henkel Corp. Emery Group, or by steam cracking methyl ricinoleate, a by-product of the manufacture of nylon-11, an Atochem process in France (4). Neoacids are derived from isobutylene and nonene (4) (see Carboxylic acids, trialkylacetic acids). [Pg.94]

Alkali Fusion. Tha alkaU fusion of castor oil using sodium or potassium hydroxide in the presence of catalysts to spHt the ricinoleate molecule, results in two different products depending on reaction conditions (37,38). At lower (180—200°C) reaction temperatures using one mole of alkah, methylhexyl ketone and 10-hydroxydecanoic acid are prepared. The 10-hydroxydecanoic acid is formed in good yield when either castor oil or methyl ricinoleate [141-24-2] is fused in the presence of a high boiling unhindered primary or secondary alcohol such as 1- or 2-octanol. An increase to two moles of alkali/mole ricinoleate and a temperature of 250—275°C produces capryl alcohol [123-96-6] CgH gO, and sebacic acid [111-20-6] C QH gO, (39—41). Sebacic acid is used in the manufacture of nylon-6,10. [Pg.154]

Most electroless silver appHcations are for silvering glass or metallizing record masters. Mirror production is the principal usage for electroless silver. The glass support is cleaned, catalyzed using a two-step catalyst, and coated on one side with an opaque silver film (46). Silver-plated nylon cloth is used as a bacteriostatic wound dressing. A tiny current appHed to the cloth causes slow silver dissolution. The silver acts as a bactericide (47). [Pg.112]

The polymerisation casting of nylon 6 in situ in the mould has been developed in recent years. Anionic polymerisation is normally employed a typical system uses as a catalyst 0.1-1 mol.% of acetic caprolactam and 0.15-0.50 mol.% of the... [Pg.486]


See other pages where Nylon catalysts is mentioned: [Pg.13]    [Pg.458]    [Pg.216]    [Pg.30]    [Pg.13]    [Pg.458]    [Pg.216]    [Pg.30]    [Pg.30]    [Pg.212]    [Pg.2696]    [Pg.341]    [Pg.68]    [Pg.70]    [Pg.144]    [Pg.173]    [Pg.229]    [Pg.234]    [Pg.235]    [Pg.236]    [Pg.360]    [Pg.94]    [Pg.268]    [Pg.155]    [Pg.168]    [Pg.300]    [Pg.2094]    [Pg.486]   
See also in sourсe #XX -- [ Pg.285 , Pg.286 , Pg.287 , Pg.289 , Pg.290 ]




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