Multiresidue methods for pesticides

A Di Corcia, M Marchetti. Multiresidue method for pesticides in drinking water using a graphitized carbon black cartridge extraction and liquid chromatographic analysis. Anal Chem 63 580-585,1991. 

Cabras, P., Tuberoso, C., Melis, M. and Martini, M.G. (1992) Multiresidue method for pesticide determination in wine by high-performance liquid chromatography, T. Agric. Food Chem., 40(5), 817-819. 

Banerjee, K., Oulkar, D.P., Dasgupta, S., Patil, S.B., Patil, S.H., Savant, R., and Adsule, P.G. (2007). Validation and uncertainty analysis of a multiresidue method for pesticides in grapes using ethyl acetate extraction and liquid chromatography-tandem mass spectrometry,/. Chromatogr. A, 1173, 98-109. 

Multiresidue Methods for Pesticides and Related Contaminants in Food... 

MULTIRESIDUE METHODS FOR PESTICIDES AND RELATED CONTAMINANTS TABLE 12.1 Validation Parameters and Criteria ... 

R., Roding, M., Arondeus, K., and Sunarto, S. (2007) Modification and revalidation of the ethyl acetate-based multiresidue method for pesticides in produce. Anal. Bioanal. Chem., 89 (6), 1715-1754. 

Bennett DA, Chung AC, Lee SM. 1997. Multiresidue method for analysis of pesticides in liquid whole milk. JAOACInt 80(5) 1065-1077. 

Since the analytical point of view most of current analytical methods are based on LC-MS/MS, but for some classes of pesticides GC-MS continues being the technique of choice. The use of quadrupole ion trap (QIT) to analyze multiple pesticide residues is limited to several multiclass pesticides in fruit [162], because of the limited number of ions that can be isolated at the same time. For this reason, the use of several time windows is required and this is indeed a strong limitation in practice. The use of hybrid triple quadrupole linear ion trap (QqLlT) mass spectrometer has provided significant contribution to the development of high-sensitive multiresidue analytical methods for pesticide control. An example of application is the method reported by Hernando et al. for the analysis of pesticide residues in olive oil [65]. 

Carvalho JJ, Jeronimo PCA, Goncalves C et al (2008) Evaluation of a multiresidue method for measuring fourteen chemical groups of pesticides in water by use of LC-MS-MS. Anal Bioanal Chem 392 955-968... 

Leoni V, Caricchia AM, Chiavarini S. 1992. Multiresidue method for quantitation of organophosphorus pesticides in vegetable and animal foods. J AOAC International 75(3) 511-518. 

Miyahara M, Suzuki T, Saito Y. 1992. Multiresidue method for some pesticides in lanolin by capillary gas chromatography with detection by electron capture, flame photometric, mass spectrometric, and atomic emission techniques. J Agric Fd Chem 40 64-69. 

RT Krause. Multiresidue methods for carbamate pesticides. Emerging Strategies for Pesticide Analysis 5 99-123, 1992. 

A multiresidue method for analyzing 28 common organophosphorus pesticides and three of their main metabolites (paraoxon-ethyl, paraoxon-methyl, and malaoxon) in a variety of crop samples has been developed (59). The use of LC-DAD techniques allowed identification of both organophosphorus pesticides and metabolites by means of standard and spectral comparisons, respectively. A typical chromatogram for fortified apple extract is shown in Figure 4. 

BP Ioerger, JS Smith. Multiresidue method for the extraction and detection of organophosphate pesticides and their primary and secundary metabolites from beef tissue using HPLC. J Agric Food Chem 41 303-307, 1993. 

JJ Blaha, PJ Jackson. Multiresidue method for quantitative determination of organophosphorus pesticides in food. J Assoc Off Anal Chem 68 1095-1099, 1985. 

J Slobodnik, MGM Groenewegen, ER Brouwer, H Lingeman, UAT Brinkman. Fully automated multiresidue method for trace level monitoring of polar pesticides by liquid chromatography. J Chromatogr 642 359-370, 1993. 

Work Item A multiresidue methods for the gas chromatographic determination of pesticide residues ... 

Crescenzi, C., A. Di Corcia, E. Guerriero, and R. Samperi (1997). Development of a multiresidue method for analyzing pesticide traces in water based on solid-phase extraction and electrospray liquid chromatography mass spectrometry. Environ. Sci. Technol., 31 479 188. 

Schulein, J., D. Martens, P. Spitzauer, and A. Kettrup (1995). Comparison of different solid phase extraction materials and techniques by application of multiresidue methods for the determination of pesticides in water by high-performance hquid chromatography (HPLC). Fresenius J. Anal. Chem., 352 565-571. 

M.J. Taylor, K. Hunter, K.B. Hunter, D. Lindsay, S. Le Bouhellec, Multiresidue method for rapid screening and confirmation of pesticides in crude extracts offruits and vegetables using isocratic LC-ESI-MS-MS, J. Chromatogr. A, 982 (2002) 225. 

For the set up a GC-based multiresidue method for a specific pesticide-matrix combination, information is needed on GC retention and detectability of the analytes also, the need for a cleanup procedure must be evaluated. 

Table 6.3 Characteristics of monoresidue and multiresidue methods for the analysis of pesticide residues.

Figure 6.2 GC and electron-capture-detector (GC-ECD) analysis of a chloroor-ganic and pyrethroids pesticides standard solution. (From Holland, P.T. and Malcolm, C.P. (1992) Multiresidue analysis in fruits and vegetables , in T. Cairns and J. Sherma (Eds) Emerging Strategies for Pesticide Analysis, Modern Methods for Pesticide Analysis Series, CRC Press, Boca Raton)...

Multiresidue method for the determination of pesticides residues in grape (QuEChERS)(Anastassiades et al., 2003)... 

Jansson, C., Pihlstrom, T., Osterdahl, B.G. andMarkides, K.E. (2004) Anew multiresidue method for analysis of pesticides residues in fruit and vegetables using liquid chromatography with tandem mass spectrometric detection, J. Chromatogr. A., 1023(1), 93-104. 

Lacassie E, Marquet P, Gaulier JM, Dreyfuss MF, Lachatre G. Sensitive and specific multiresidue methods for the determination of pesticides of various classes in clinical and forensic toxicology. Forensic Sci Int 2001 121 116-25. 

Gongalves, C. and Alpendurada, M. E., Multiresidue method for the simultaneous determination of four groups of pesticides in ground and drinking waters, using solid-phase microextraction-GC with electron-capture and thermionic specific detection, J. Chromatogr. A, 968, 177-190, 2002. 

Bruchet, A., Patty, L., and Jaskulke, E., Optimization and Evaluation of Multiresidue Methods for Priority Pesticides in Drinking and Related Waters (European Project SMT4-CT96-2142), 1998. 

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