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Multiple field natural

Multiple Field Natural Abundance NMR Studies of DNA Dynamics... [Pg.269]

As before o is the cross section in the absence of a microwave field. Naturally <70(0) = o. This expression is the origin of the lines drawn in Fig. 9, which evidently match the experimental cross sections. Similar results have also been observed with the K system of Eq. (10) using velocity selected beams to obtain narrower collisional linewidths allowing, the use of rf frequencies of 4 MHz, instead of 15 GHz [Thomson 1992], Since the collisions last longer, the rf fields can be very weak, < 0.1 V/cm. An interesting aspect of both the 15 GHz and the 4 MHz measurements is that the Bessel function oscillation of the cross section with microwave or rf field amplitude is observed indicating that the coherence of the colliding atoms is maintained over multiple field cycles. [Pg.421]

While clinical and pathological observations of natural goat scrapie also indicate the existence of multiple field isolates, strain characterization of prions from goats... [Pg.83]

When coding a BVP widi multiple fields, it is easiest to write the routines to use, as much as is possible, natural names and indices, e.g. cy(zt), and to rely upon routines to stack and unstack the state vector and to place the matrix and vector elements in the appropriate positions. This approach is used in tubular.reactor rxn SS.m. Sample results are shown... [Pg.281]

The ortho effect may consist of several components. The normal electronic effect may receive contributions from inductive and resonance factors, just as with tneta and para substituents. There may also be a proximity or field electronic effect that operates directly between the substituent and the reaction site. In addition there may exist a true steric effect, as a result of the space-filling nature of the substituent (itself ultimately an electronic effect). Finally it is possible that non-covalent interactions, such as hydrogen bonding or charge transfer, may take place. The role of the solvent in both the initial state and the transition state may be different in the presence of ortho substitution. Many attempts have been made to separate these several effects. For example. Farthing and Nam defined an ortho substituent constant in the usual way by = log (K/K ) for the ionization of benzoic acids, postulating that includes both electronic and steric components. They assumed that the electronic portion of the ortho effect is identical to the para effect, writing CTe = o-p, and that the steric component is equal to the difference between the total effect and the electronic effect, or cts = cr — cte- They then used a multiple LFER to correlate data for orrAo-substituted reactants. [Pg.336]

It is interesting that the stimulus compounds used in the study differ widely in their molecular structures, and yet they all interact with antibodies to thaumatin. It is, therefore, probable that a single receptor-structure responds to all sweet stimuli,there being a variation in the relative effectiveness of sweet stimuli across individual nerve-fibers, and the characteristics of all receptor sites do not appear to be identical. Earlier elec-trophysiological studies of single primary, afferent taste-neurons uniformly agreed that individual fibers very often have multiple sensitivities, and that individual, gustatory receptors are part of the receptive field of more than one afferent fiber. " We have yet to learn how these interact, and the nature of their excitatory, or possible inhibitory, relations, or both. [Pg.334]

In 1956 Brown, in a series of patents(68-75), disclosed that clays could be treated with di-, tri-, or tetra-substituted ammonia derivatives. Later, McLaughlin, et al.(76,77), introduced cationic polymers as permanent clay protective chemicals. A series of published results describing laboratory and field applications soon became available(78-81). Structural details of the cationic polymers appeared in patents(82-85). In general the polymers are polyamine derivatives, mostly quaternary in nature. Theng(86,87) has discussed how the multiple cationic centers in these polymers can interact and permanently protect clays. Callaway(88) et al. has noted that cationic polymers may interfere with the performance of crosslinked fracturing fluids. [Pg.72]

Those inventions that are valuable for society, which include innovative pharmaceuticals, generate positive externalities, that is, the benefits falls to society at large. The sum of these benefits gives the social benefit or value of the invention. In this way, patents represent the appropriation of part of this social value. Naturally, when businesses decide to undertake a project they do so with their own benefit in mind. Some research, particularly basic research, might not be undertaken in these circumstances, and therefore governments decide to invest to fill the gap that may be left by the patent system. Basic research allows the development of multiple applications and the discovery of scientific principles. The field of genetics is a prime example of this. [Pg.26]

In spite of the frequency-shifted excitation, the quantized PIP inevitably excites multiple sidebands located at n/At ( = 1, 2,...) from the centre band. An attempt was made16 to calculate the excitation profile of multiple bands created by a PIP of a constant RF field strength, using an approximate method based on the Fourier analysis. The accuracy of the method relies partly on the linear response of the spin system, which is, unfortunately, not true in most cases except for a small angle excitation. In addition, the spins inside a magnet consitute a quantum system, which is sensitive not only to the strengths but also to the phases of the RF fields. Any classical description is doomed to failure if the quantum nature of the spin system emerges. [Pg.4]


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Multiple field natural dynamics

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