Methyl, alcohol ethyl ether

Tonomura and Chujo, Bull, Chem, Soc, Japan, 1932, 7, 259 (methyl alcohol, ethyl ether, toluene). 

Ethyl Alcohol Gasoline Ethyl Acetate Methyl Alcohol Ethyl Ether Water... 

Triefhylamine is a colorless liquid, freely soluble in wafer at temperatures below 18 C., soluble in ethyl alcohol, methyl alcohol, ethyl ether, ethyl acetate, oliphatic ond aromatic hydrocarbons, acetone, fixed oils, mineral oil, oleic and stearic acids, and in hot carnauba ond paraffin waxes, the latter two solidifying when cooled. It is used in the manufacture of corrosion inhibitors, emulsifying ogents, dyestuffs, ond insecticides. 

It is soluble in ethyl and methyl alcohols, ethyl ether, ethyl acetate, acetone, aliphatic, and aromatic hydrocarbons, fixed ails, mineral ail, oleic and stearic acids. While it dissolves hot paraffin and carnauba waxes, these solidify an coaling. It is used in organic synthesis where its derivatives ore used as flotation reagents, dyestuffs, rubber vulcanization accelerators and corrosion inhibitors. 

Oioclylamine Is a colorless liquid with o faintly amine odor. It is soluble in methyl alcohol, ethyl ether, ethyl acetate, acetone, aromotic and aliphatic hydrocarbons, fixed oils, mineral oil, oleic artd stearic acids. It is insoluble In water and while soluble In hat paraffin artd cartKiuba waxes, these solidify when cooled. Among the large number of substances it will dissolve are natural and synthetic resins. 

This alkylol amine is a watefwhite to light-straw liquid with a faintly ammoniacal odor. It is soluble in water, methyl alcohol, ethyl ether, ethyl, acetate, acetone, aromatic hydrocarbons, fixed ails, oleic and hot stearic acids, and hat carnoubo wox, the latter solidifying when cooled. It is insoluble in mineral oil and paraffin wax. 

This secondary omine is a light straw to amber-colored liquid with an aniline adar. It is insoluble in water but saluble in ethyl alcohol, methyl alcohol, ethyl ether, ethyl acetate, acetone, oromatic and aliphatic hydrocarbons, fixed ails, mineral oil, oleic acid, and hot stearic ocid. It is also soluble in hot paroffin and carnauba waxes which solidify upon cooling. 

Outside of hydrocarbons, certain organic oxygenated compounds such as the alcohols and ethers are henceforth utilized in the formulation of gasolines. These are mostly methanol, ethanol, propanols and butanols, as well as methyl and ethyl ethers obtained from and Cj olefins ... 

Tetrahydronaphthalene [119-64-2] (Tetralin) is a water-white Hquid that is insoluble in water, slightly soluble in methyl alcohol, and completely soluble in other monohydric alcohols, ethyl ether, and most other organic solvents. It is a powerhil solvent for oils, resins, waxes, mbber, asphalt, and aromatic hydrocarbons, eg, naphthalene and anthracene. Its high flash point and low vapor pressure make it usehil in the manufacture of paints, lacquers, and varnishes for cleaning printing ink from rollers and type in the manufacture of shoe creams and floor waxes as a solvent in the textile industry and for the removal of naphthalene deposits in gas-distribution systems (25). The commercial product typically has a tetrahydronaphthalene content of >97 wt%, with some decahydronaphthalene and naphthalene as the principal impurities. 

Methyl alcohol. Ethyl alcohol. Isopropyl alcohol. Ether. Acetone. Cane BUgar. 

Temper- ature °C Methyl alcohol Ethyl alcohol Isoamyl alcohol Ethyl ether Acetone Benzene Toluene Carbon tetra- chloride... 

Methyl alcohol Ethyl alcohol Diethyl ether Acetone Formic acid Acetic acid... 

An interesting example of the salting out by nonelectrolytes in water was given by Grigorovich and Samoilov (69). They studied the solubility of praseodymium chloride and sulfate in water in the presence of various nonelectrolytes (methyl alcohol, ethyl alcohol, and diethyl ether.) Their results show that the decrease in solubility of praseodymium chloride is only of the order of a few percent but that this decrease is probably highly significant because praseodymium chloride is more soluble in pure methyl and ethyl alcohol than in pure water. (The... 

Isoprene [78-79-5] (2-methyl-1,3-butadiene) is a colorless, volatile liquid that is soluble in most hydrocarbons but is practically insoluble in water. Isoprene forms binary azeotropes with water, methanol, methyl amine, acetonitrile, methyl formate, bromoethane, ethyl alcohol, methyl sulfide, acetone, propylene oxide, ethyl formate, isopropyl nitrate, methylal (dimethoxymethane), ethyl ether, and -pentane. Ternary azeotropes form with water—acetone, water—acetonitrile, and methyl formate—ethyl bromide (8). Typical properties of isoprene are listed in Table 1. 

Thiazole itself can be obtained by condensing chloroacetaldehyde and thioformamide (Scheme 159). The reaction is explosive and proceeds in low yield because of the instability of the thioformamide under acid conditions. Higher thioamides are more stable and react under milder conditions with chloroacetaldehyde, affording 2-substituted thiazoles in moderate yields. It is possible, and often preferable, to prepare the thioamide in situ in dioxane solution by the action of phosphorus pentasulfide on the corresponding amide and in the presence of solid MgC03 (Scheme 160). With arylthioamides, except for some nitrothiobenzamides, yields are usually higher and the cyclization is carried out over several hours in boiling absolute alcohol. Chloroacetaldehyde can be replaced in these reaction by derivatives such as 1,2-dichloro- or dibromo-ethyl methyl or ethyl ether, 1,2-dichloro- or dibromo-ethyl acetate, 2-chloro- or dibromo-ethyl acetate, and 2-chloro or bromo-diethyl-acetal. 

The degree of decomposition by the voltaic arc depends of course, to a great extent upon the chemical nature of the liquids and vapors in which the luminous arc is produced While ether, methyl alcohol, ethyl alcohol, glacial acetic acid, and other aliphatic fluids and their vapors are subject to decompositions with very trifling charring, and give products which are chemically closely related to the products started with, benzene, toluene, nitrobenzene, aniline, naphthalene, phenol, and other members of the aromatic series are destroyed, and considerable charring results. 

The (2-hydroxy)indane product from Step 2 (8.27 mmol), N-t-butoxycarbonyl-spiro[(2-hydroxy)indane-l,4 -piperidine] were dissolved in 10ml ethyl alcohol, 10.0ml 4M HCl (40.0 mmol) dissolved in dioxane added, the mixture stirred 30 minutes under ice cooling, and then further stirred at ambient temperature 4 hours. The solvent was distilled off under reduced pressure, the residue recrystallized from methyl alcohol/diethyl ether, and the product isolated in 83% yield, mp = 250-251 °C. H-NMR, IR, and MS data supplied. 

Methyl alcohol Ethyl alcohol Ethyl ether... 

Carbon disulphide -Ether Chloroform Carbon tetrachloride Methyl alcohol Ethyl alcohol -w-Propyl alcohol Isopropyl alcohol -%-Butyl alcohol... 

Two grams of the ethyl ester (1 mol.) in 10 c.c. of metliyl alcohol are added to 8 grams of mercuric acetate (2 mols.) in 50 c.c. of the same solvent, and the mixture allowed to stand for a day. A pale yellow, non-crystalline product separates out, and this is filtered and washed with methyl alcohol and ether. Yield 7 7 grams, 93 per cent. It cannot be rccrystallised, melts about 245 C., and is soluble in ammonium hydroxide, acetic add or mineral acids, but with decomposition in latter in the usual organic solvents it is practically insoluble. Its acetic acid solution after neutralisation with ammonium hydroxide splits off mercuric sulphide when treated with cold ammonium sulphide. 

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