Oxide magnetic materials

M-type ferrites are mainly used as permanent magnet material. They have largely replaced the alnicos as preferred permanent magnet material, as a result of the lower material and processing costs. These ferrites were first introduced under the trade name Ferroxdure, the isotropic form in 1952 (22) and the anisotropic (crystal oriented) form in 1954 (23), and are widely available commercially under various trade names such as Oxid and Koerox. They cover about 55% of the world market of permanent magnet materials, corresponding to 1100 million U.S. doUars (1991), as weU as 55% of the U.S. market, at 300 million. 

Pure iron is a silvery white, relatively soft metal and is rarely used commercially. Typical properties are Hsted in Table 1. Electrolytic (99.9% pure) iron is used for magnetic cores (2) (see Magnetic materials, bulk). Native metallic iron is rarely found in nature because iron which commonly exhibits valences of +2 and +3 combines readily with oxygen and sulfur. Iron oxides are the most prevalent form of iron (see Iron compounds). Generally, these iron oxides (iron ores) are reduced to iron and melted in a blast furnace. The hot metal (pig iron) from the blast furnace is refined in steelmaking furnaces to make steel... 

Particulate Materials. There are three principal classes of particulate magnetic materials y-ferric oxide, y-Fe202, and its modifications chromium dioxide [12018-01 -8] and iron [7439-89-6]. A comparison of the remanent magnetization, and coercivity, for several y-Fe202... 

K. J. Standley, "Electrical Properties of Ferrites and Garnets," Oxide Magnetic Materials, 2nd ed.. Clarendon Press, Oxford, UK, 1972. 

Mag netic Tapes. Chromium dioxide, Cr02, is used as a ferromagnetic material in high fidelity magnetic tapes (qv). Chromium dioxide has several technical advantages over the magnetic iron oxides generally used (58,246). 

Finally, selective separation and dewatering of one suspended substance in a slurry containing different minerals or precipitates is possible by selectively adsorbing a magnetic material (usually hydrophobic) onto a soHd that is also naturally or chemically conditioned to a hydrophobic state. This process (Murex) was used on both sulfide ores and some oxides (145). More recently, hydrocarbon-based ferrofluids were tested and shown to selectively adsorb on coal from slurries of coal and mineral matter, allowing magnetic recovery (147). Copper and zinc sulfides were similarly recoverable as a dewatered product from waste-rock slurries (148). 

Geothite is produced by air oxidation of alkaline suspension of ferrous hydroxide (Sada etal., 1988). As a starting material for ferrous oxide, the preparation of fine particles with prescribed size, size distribution and shape is required in its application to magnetic materials for recording tapes and disks. With increasing oxidation rate, the crystal size decreases and the size distribution becomes sharper (Sada etal., 1988). The first step of the reaction. 

On the other hand, internal magnetic fields at the iron nucleus arising from the magnetic moments of unpaired valence electrons can be much stronger than any applied field and their effect can easily exceed the quadrupole interaction. For instance, Mossbauer nuclei in magnetic materials such as metals or oxides may experience fields of 30-50 T even without applied field. Similarly, the typical... 

Nearly no eddy current losses occur in electrically insulating magnetic materials. This is one of the reasons for the importance of oxidic materials, especially of spinels and garnets. Another reason is the large variability of the magnetic properties that can be achieved with spinels and garnets of different compositions. The tolerance of the spinel structure to substitution at the metal atom sites and the interplay between normal and inverse spinels allow the adaptation of the properties to given requirements. 

Cyanide complexes have a venerable history (see CCC S )),1 and find utilization in many industrial processes including as synthetic catalysts e.g., Co cyanides on inorganic supports catalyze alkylene oxide polymerization,187 molecular magnetic materials, in electroplating, and in mining. Their pharmacology and toxicology is well explored... 

Single and mixed oxides synthesised using these procedures are widely probed as cathode materials, superionics, magnetic materials, catalysts, and other multipurpose materials [4-20],... 

Dr. Hui has worked on various projects, including chemical sensors, solid oxide fuel cells, magnetic materials, gas separation membranes, nanostruc-tured materials, thin film fabrication, and protective coatings for metals. He has more than 80 research publications, one worldwide patent, and one U.S. patent (pending). He is currently leading and involved in several projects for the development of metal-supported solid oxide fuel cells (SOFCs), ceramic nanomaterials as catalyst supports for high-temperature PEM fuel cells, protective ceramic coatings on metallic substrates, ceramic electrode materials for batteries, and ceramic proton conductors. Dr. Hui is also an active member of the Electrochemical Society and the American Ceramic Society. 

Lodestone, also known as magnetite, was one of the first known magnetic materials. Its ability to attract iron was known as far back as 600 B.C., and it was used in compasses beginning in the thirteenth century. It was studies by I. L. Snoeck at the Philips Laboratories in Holland in the 1940s, however, that led to the first application of oxide ceramics with strong magnetic properties. 

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