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Literature, of organometallic chemistry

The increasing growth of the primary literature of organometallic chemistry has necessarily led our Reporters to expand the bibliographies of papers not reviewed in the cursive text. [Pg.557]

Comprehensive coverage has not been attempted, but rather the intention has been to provide an introduction for the non-specialist which illustrates the scope of the field and highlights the main features of interest to organic chemists. Citation of all relevant publications is impracticable because of the large volume of literature. However, it is hoped that those key papers and specialist review articles which are included will enable the reader to locate related literature of interest. Advances in the chemistry of metallacycles and metal-hydrocarbon ir-complexes are thoroughly reviewed in surveys of organometallic chemistry published annually since 1972 (B-72MI12200). [Pg.665]

It is likely that more silicon-carbon bonds are produced by the hydrosilylation of olefins than by any other method except the direct process. This deceptively simple addition of an Si-H bond to a C-C multiple bond can be promoted by a variety of means, but transition metal catalysis is by far the most significant. Two relatively old catalysts, H2PtCl6 ( Speier s catalyst ) and Pt2(Me2ViSiOSiMe2Vi)3 ( Karstedt s catalyst ), remain the most effective, and the remarkable rates and turnover numbers observed in these systems are among the most impressive in all of organometallic chemistry. The bulk of the literature on hydrosilylation falls outside the scope of this review, and readers are directed to the comprehensive work on hydrosilylation edited by Marciniec.93... [Pg.199]

The development of metal atom vapor technology over the last 15 years has made available to the chemist a new and useful synthetic technique. A number of novel transition metal compounds have been isolated by the method, particularly in the field of organometallic chemistry. However, the use of vaporized metal atoms for the synthesis of metal alkoxides and phenoxides by condensation into the neat alcohol has been only briefly mentioned in the literature.27... [Pg.337]

There seems to be no stemming the flow of the primary literature, and the appearance of Volume 1 of the Chemical Society s Specialist Periodical Report on Organometallic Chemistry will be welcomed by all. Further details of this book, which covers both Main Group and Transition Metal derivatives, can be found in Section B. The Journal of Organometallic Chemistry continues to expand, with 1972 seeing the publication of thirteen volumes (34-46), which include subject reviews, annual reports, and preliminary communications, as well as the usual selection of papers. Fortunately it is now possible to purchase the individual volumes given over to the annual reviews. [Pg.379]

B7. R. B. King and D. Seyferth, eds., Annual Survey of Organometallic Chemistry, Elsevier, Amsterdam, vols. 1 (1965), 2 (1966), 3 (1967). Each volume surveys the literature appearing in the previous year. The series then became Organometallic Chemistry Reviews, Series B, Annual Surveys, vols. 4 (1968), 5 (1969), 6 and 7 (1970), 8 and 9 (1971). Beginning in 1972, this publication will merge with the Journal of Organometallic Chemistry. [Pg.284]

The only abstract journal concerned solely with the field of organometallic chemistry is Organometallic Compounds (Dl), which covers patents and some of the chemical literature. About 5000 abstracts were published in 1969, relating to all aspects of Main Group and Transition element organometallic chemistry. Sections on olefin polymerization, polymerization catalysts, additives for plastics, paints, fuels, and lubricants, and related topics, follow a large section on organometallic chemistry. [Pg.289]

Organometallic chemistry is currently reviewed element by element in at least three independent publications. The first in-depth review appeared as a single volume in 1965 entitled Annual Survey of Organometallic Chemistry (Bl). This covered the literature of the previous year. After three annual issues the publication became multi-authored and was incorporated into Organometallic Chemistry Reviews as Series B (as distinct from Series A, subject reviews). In January 1973, the surveys became part of the Journal of Organometallic Chemistry. At the time of writing, coverage is complete for all elements to the end of 1973, except Si (1970) Be, Ca, Sr, Ba, Si, Pb (1971) Si (1972) and Li, Na, K, Ge, Pb, As, Sb, Bi (1973). [Pg.469]

Nature of the present surrey. Although study of the interaction of nickel carbonyl with unsaturated organic compounds has been under way for little more than two decades, reviews by Bird (1962) and by Schrauzer (1964) bear evidence to the extensive literature already on record in documentation of a highly specialized field of organometallic chemistry. Our account will then be limited to a very brief survey of types of reactions now clearly defined, if not us yet fully understood. [Pg.363]

Catalytic, selective functionalization of hydrocarbons is one of the most important goals of organometallic chemistry. A report in the literature describes the Rh-catalyzed conversion of benzene to benzaldehyde under photochemical conditions.122... [Pg.388]

In recent years, metal-metal bonds in clusters have also attracted much attention in relation to catalysis and solid state chemistry. They show more complicated bonding schemes in a sense of classical bonding. There are increasing numbers of reports that show not only their novel structure but also unusual and surprising chemical reactivities of complexes having more than two transition metals. Mechanisms and applications of many of these reactions are not well understood and still remain unresolved. These will be serendipitous research areas to be developed in the field of organometallic chemistry. Chemistry of clusters and metal-metal bonds are not described here in detail, but readers are strongly recommended to refer to the literature. [Pg.5]

The wealth of derivatives known is documented by an enormous number of publications. Despite progress in the use of electronic databases, systematic literature searches on ferrocenes still remain difficult. The most viable, useful, and comprehensive source of information about ferrocene is the ten volumes of Gmelin s Handbook of Inorganic and Organometallic Chemistry [2] covering the literature up to 1986. The annual reviews on ferrocene, appearing in the Journal of Organometallic Chemistry also provide fairly systematic and up-to-date accounts... [Pg.547]

This extremely wide field has been the subject of many books and reviews, e.g., the book by Krause and von Grosse1 (which includes almost all work published up to 1936) and that by Runge (1944).2 The main feature of organometallic chemistry, with many valuable literature references, are given in books by Coates (1956),3 Rochow, Hurd, and Lewis (1957),4 and Rochow (1964).5 A review by Coates (1950)3 treats the organometallic compounds of the first three Groups of the Periodic System. [Pg.748]

A review of the literature reveals that cyclopentadienyl or substituted cyclopentadienyl ligands play an important role in stabilizing alkyl complexes of the actinides, and there is a great deal of organometallic chemistry associated with these complexes. [Pg.46]


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See also in sourсe #XX -- [ Pg.31 , Pg.32 , Pg.33 , Pg.34 ]




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