Kellogg Advanced

The design sketched above is an elaborate version of the so-called Kellogg Advanced Ammonia Process (KAAP) in which iron-based catalysts are used in the first bed, and ruthenium-based catalysts, which bind nitrogen more weakly, are used in the second, third and fourth beds [T.A. Czuppon, S.A. Knez, R.W. Schneider and G. Woroberts, Ammonia Plant Safety Relat. Pacil. 34 (1994) 236]. 

Alkali-promoted Ru-based catalysts are expected to become the second generation NHs synthesis catalysts [1]. In 1992 the 600 ton/day Ocelot Ammonia Plant started to produce NH3 with promoted Ru catalysts supported on carbon based on the Kellogg Advanced Ammonia Process (KAAP) [2]. The Ru-based catalysts permit milder operating conditions compared with the magnetite-based systems, such as low synthesis pressure (70 -105 bars compared with 150 - 300 bars) and lower synthesis temperatures, while maintaining higher conversion than a conventional system [3]. 

KAAP [Kellogg advanced ammonia process] The first high-pressure process developed for synthesizing ammonia from its elements which does not use an iron-containing catalyst. The reformer gas for this process is provided by the KRES process. The catalyst was developed by BP it contains ruthenium supported on carbon. Developed by MW Kellogg Company in 1990 and first installed by the Ocelot Ammonia Company (now Pacific Ammonia) at Kitimat, British Columbia, from 1991 to 1992. Another plant was installed at Ampro Fertilizers in Donaldsonville, LA, in 1996. 

Kellogg Advanced Ammonia Process (KAAP), 19 621 Kelly leaf filter, 11 365 Kelp, 14 360... 

M. W. Kellogg has developed a new technology in the synthesis of ammonia. They employ a ruthenium on graphite as the catalyst on Kellogg Advanced Ammonia Process (KAAP). The process is the first to employ a non-iron based catalyst and was co-developed with British Petroleum Ventures. The KAAP has been commercialized since 1994, and has been used in an increasing number of projects. 

The KRES (Kellogg Reforming Exchanger System) is a reforming process that provides syngas to the KAAP process. The KAAP (Kellogg Advanced... 

The KAAP (Kellogg Advanced Ammonia process) process is the first high-pressure ammonia synthesis process that makes ammonia from nitrogen and hydrogen without the aid of an iron-containing catalyst.1 It is described in References 22-25. 

Figure 95. Kellogg advanced ammonia process (KAAP) a) Compressor b) PGRU c) Refrigeralion...

Perry s Chemical Engineering Handbook, 6th Ed. McGraw-Hill New York, 1984 11-31 and 11-40. Winthrop, A.H. et al. (M.W. Kellogg), Advances in solvent deasphalting technology. National Petroleum Refining Association Annual Meeting, San Antonio, Texas, March 17-19, 1996, paper AM-96-55. 

Alternatively, KBR offer the KAAP (Kellogg Advanced Ammonia Process) synthesis concept, where the synthesis gas is converted to ammonia in a low pressure synthesis loop (8-9 MPa) featuring a four bed synthesis converter loaded with conventional iron based catalyst in the first bed and Ru-based catalyst in the lower beds. This technology has so far only had limited use due to the high cost of Ru. 

Figure 6.14. The Kellogg Advanced Ammonia Process (KAAI Synthesis Loop.

Czuppon, T. A., et. al. 1993. The Kellogg Advanced Ammonia Process First Commerlcal Application at Ocelot Ammonia Company, Ammonia Safety Symposium. 

Since ruthenium catalyst is expensive, highly active and readily inhibited by H2, the process for the ammonia synthesis must be modified to fit these features. In 1980, BP and Kellogg Corporation cooperated to develop a novel ammonia synthesis system, in which BP was to develop a new ammonia synthesis catalyst with high activity at low temperatures and low pressures, while Kellogg was responsible for the development of the matching technology for the process of ammonia synthesis. After a joint effort for 10 years, a process called Kellogg Advanced Ammonia Process (KAAP) was developed successfully (Fig. 1.26). 

The principal advance ia technology for SASOL I relative to the German Fischer-Tropsch plants was the development of a fluidized-bed reactor/regenerator system designed by M. W. Kellogg for the synthesis reaction. The reactor consists of an entrained-flow reactor ia series with a fluidized-bed regenerator (Fig. 14). Each fluidized-bed reactor processes 80,000 m /h of feed at a temperature of 320 to 330°C and 2.2 MPa (22 atm), and produces approximately 300 m (2000 barrels) per day of Hquid hydrocarbon product with a catalyst circulation rate of over 6000 t/h (49). 

Figure 7. Kellogg s new ruthenium-catalyst based advanced ammonia process combined with the reforming exchange system. (Used with permission of Chemical Engineering.)...

Kellogg Brown Root Advanced Ammonia Process - Plus (KAAP)... 

After C02 removal, final purification includes methanation (8) gas diying (9) and ciyogenic purification (10). The resulting pure synthesis gas is compressed in a single-case compressor and mixed with a recycle stream (11). The gas mixture is passed to the ammonia converter (12), which is based on the Kellogg Brown Root Advanced Ammonia Process (KAAP). It uses a precious metal-based, high-activity ammonia synthesis catalyst to allow for high conversion at the relatively low pressure of 90 bar. 

Kellogg Brown Root Ammonia, advanced Hydrocarbons/natural gas naphtha Catalytic-steam reforming process uses pressure-based Kellogg Reforming Exchange System (KRES) NA NA... 

Schematic representation of the transformation of sulfur compounds in the atmosphere according to Kellogg et al. (1972). (Copyright 6.2.1979 by the American Association for the Advancement of Science...

Propylene, Advanced Catlytic Olefins - Kellogg Brown Root LLC... 

Kellogg Brown Root LLC Propylene, Advanced Catalytic Olefins Light and full-range naphthas Catalytic conversion of naphtha feed to produce higher ultimate yields of light olefins and at higher P/E production ratio relative to steam cracking, typically about 1 1 1 2010... 

Kellogg Brown Root, Inc. Ammonia, KAAPp/us Hydrocarbons To produce ammonia from hydrocarbon feedstocks using a high-pressure heat exchange-based steam reforming process integrated with a low-pressure advanced ammonia synthesis process 200 2010... 

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