Insecticides surface treatments

Today one the most common insecticidal surface treatments is the pyrethroid insecticide cyfluthrin (Tempo). It is available as an emulsifiable concentrate (EC) or as a wettable powder (WP), but the WP is much more... 

Perfluoroalkyl compounds have been manufactured since the 1950s.The total production of fluorinated surfactants (anionic, cationic and neutral) was 2001 in 1979, whereas in 2000 the total production of PFOS (perfluorooctane sulfonate) alone was nearly 3000t (Shoeib et al., 2004). Together with PFOA (perfluoroocta-noic acid), PFOS is used in refrigerants, surfactants, fire retardants, stain-resistant coatings for fabrics, carpets and paper and insecticides. Surface treatments, such as protection of clothing and carpets constitute the largest volume of PFOS production (Moriwaki, Takata and Arakawa, 2003). PFOA as well is present in several... 

Uses. /-Butyl hypochlorite has been found useful in upgrading vegetable oils (273) and in the preparation of a-substituted acryflc acid esters (274) and esters of isoprene halohydrins (275). Numerous patents describe its use in cross-linking of polymers (qv) (276), in surface treatment of mbber (qv) (277), and in odor control of polymer latexes (278). It is used in the preparation of propylene oxide (qv) in high yield with Httle or no by-products (269,279). Fluoroalkyl hypochlorites are useful as insecticides, initiators for polymerizations, and bleaching and chlorinating agents (280). 

Human dose comparisons utilizing biomonitoring and passive monitoring of an exposure environment following surface treatment with an insecticide... 

Currently there are few insecticides registered as surface treatments to control stored-product insects. For years the organophosphate insecticide malathion was used as a surface treatment for structural facilities, but stored-product insects throughout the world have developed extensive resistance to malathion (Subramanyam and Hagstrum, 1996). Most of the resistance reports were generated from studies with bulk grains, but in the United States, resistance has been documented for field populations of the red flour beetle, T. castaneum (Herbst), and the confused flour beetle, T. confusum (DuVal), collected from flour mills (Arthur and Zettler, 1991, 1992 Zettler, 1991). Populations of the Indianmeal moth, the almond moth, and the red flour beetle collected from bulk peanuts and empty warehouses were also highly resistant to malathion (Arthur et al., 1988 Halliday et al., 1988). 

Alkylphenol ethoxylates are chemically stable and highly versatile surfactants that find application in a large variety of industrial products including acid and alkaline metal cleaning formulations, hospital cleaners, herbicides (qv) and insecticides, oil-well drilling fluids, synthetic latices, and many others (see Disinfectants and antiseptics Elastomers, synthetic Insect control technology Metal surface treatments Pesticides Petroleum, drilling fluids). 

OTHER COMMENTS used as a solvent for casein, albumin, shellac, and sulfur used in the manufacture of surfactants, emulsifying agents, wetting agents, dispersants, corrosion inhibitors, detergents, and textile surface treatments used in preparation of dyes, synthetic waxes, resins, insecticides, and asphalt wetting agents also used as an inhibitor in antifreeze solutions has been used as a pharmaceutical aid. 

Dusts are the simplest means of insecticide dispersal and are appHed by introducing the finely divided carrier, with particles of 0.5 ndash 3.0 p.m in diameter, into a moving air stream. In comparison with sprays, dusts adhere poody to surfaces and cause serious drift problems away from the treatment area. 

The most important application for singlet oxygen generators (SOGs), namely the anti-cancer treatment known as photodynamic therapy (PDT), is described elsewhere in this series (see Chapter 9.22). However, SOGs are also being evaluated in other areas, such as hard surface disinfectants, soaps and washing powders,73 and insecticides.74,75... 

Eroschenko VP. 1982. Surface changes in oviduct, uterus and vaginal cells of neonatal mice after estradiol-17 and the insecticide chlordecone (Kepone) treatment A scanning electron microscopic study. Biol Reprod 26 707-720. 

Irreversible anticholinesterases include the organophosphorus inhibitors and ambenonium, which irreversibly phosphorylate the esteratic site. Such drugs have few clinical uses but have been developed as insecticides and nerve gases. Besides blocking the muscarinic receptors with atropine sulphate in an attempt to reduce the toxic effects that result from an accumulation of acetylcholine, the only specific treatment for organopho-sphate poisoning would appear to be the administration of 2-pyridine aldoxime methiodide, which increases the rate of dissociation of the organophosphate from the esteratic site on the enzyme surface. 

Insecticides derived from natural sources include nicotine, rotenone, and pyrethrum. Nicotine is obtained from the dried leaves of Nicotiana tabacum and Nicotiana rustica. It is rapidly absorbed from mucosal surfaces the free alkaloid, but not the salt, is readily absorbed from the skin. Nicotine reacts with the acetylcholine receptor of the postsynaptic membrane (sympathetic and parasympathetic ganglia, neuromuscular junction), resulting in depolarization of the membrane. Toxic doses cause stimulation rapidly followed by blockade of transmission. These actions are described in Chapter 7 Cholinoceptor-Activating Cholinesterase-Inhibiting Drugs. Treatment is directed toward maintenance of vital signs and suppression of convulsions. 

Aquatic Invertebrates. The initial impact of insecticides on most benthic invertebrates in streams is the inability to maintain their position on the streambed resulting in increased numbers being carried downstream in what is termed drift. Invertebrate drift in treated streams is easily sampled by holding a net in the current. Post-spray catches can be compared to both pre-spray diurnal patterns and catches at an untreated upstream station or in an untreated control stream. This method also can be used to document knockdown of streamside foliage-dwelling or arboreal insects if the net is set so as to sample the stream s surface. Impacts on stream invertebrates can also be determined by caging studies and by pre- and post-spray bottom fauna population assessments which either sample the numbers within a given area of natural streambed (e.g., Surber sampler) or on artificial substrates intentionally set in the stream before treatment to be colonized by resident populations. 

Evidence was obtained recently that pesticide vapors may enter the air by still another mechanism, involving plant circulation and water loss (57). Rice plants were found to efficiently transport root-zone applied systemic carbamate insecticides via xylem flow to the leaves, eventually to the leaf surface by the processes of guttation and/or stomatal transpiration, and finally to the air by surface volatilization. Results from a model chamber showed that 4.2, 5.8, and 5.7% of the residues of carbaryl, carbofuran, and aldicarb, respectively, present in rice plants after root soaking vaporized within 10 days after treatment. The major process was evaporation of surface residues deposited by guttation fluid. 

Measureable air concentrations of parent carbofuran were present from both systemic treatments (Figure 10). The root soak treatment gave a maximum vapor concentration 1 day after treatment (i. e., transplanting), and then a slow decrease thereafter. This is because the root soaking is essentially a one-shot treatment and evaporation from the leaf surface is apparently the slow step in the distribution/loss process. By contrast, the gelatin capsule treatment boosted air concentrations continually over the period of sampling. This arises through an apparently continual supply of insecticide to the... 

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