In Material Safety Data Sheets

Human and environmental welfare for lubricants and their use is addressed in Material Safety Data Sheets (MSDS). These MSDS address toxicology and health concerns based on the components in the lubricant as well as indicating the proper response in case of a spik. Environmental ha2ards of the lubricant are covered on European and Japanese MSDS as shown in Table 5. 

Neady every significant class of dyes and pigments has some members that function as sensitizers. Toxicological data are often included in surveys of dyes (84), reviews of toxic substance identification programs (85), and in material safety data sheets provided by manufacturers of dyes. More specific data about toxicological properties of sensitizing dyes are contained in the Engchpedia under the specific dye classes (see Cyanine dyes Polymethine dyes Xanthene dyes). 

Personal Protective Equipment — The items are those recommended by (a) manufacturers, either in technical bulletins or in Material Safety Data Sheets, (b) the Manufacturing Chemists Association, or (c) the National Safety Council, for use by personnel while responding to fire or accidental discharge of the chemical. They are intended to protect the lungs, eyes, and skin. 

Current TLV/TWA values are provided in Material Safety Data Sheets provided by manufacturers on request. 

When using ERPG data, keep in mind that human responses vary widely and that particular responses cannot be attributed to exact levels of exposure. Other sources of hazards data in some case can be found in Material Safety Data Sheets (MSDS) issued by the manufacturer of the material or in the National Institute of Occupation Safety and Health (NIOSH) publication NIOSH Pocket Guide to Chemical Hazards (DHHS, 1990). 

USACHPPM s TG 218. Detailed and General Facts About Chemical Agents. The facts sheets contained in this Technical Guide are intended to provide summary information on 24 chemical warfare materials related to Chemical Stockpile and Non-Stockpile activities. In essence, they are a brief abstract of data contained in Material Safety Data Sheets and other technical references relevant to these substances. 

For TSCA Inventory purposes, the EPA distinguishes silica gel (CASRN 63231-67-4), and silica fumes, (CASRN 69012-64-2), as unique chemical substances. The EPA takes the position that manufacturers are free to describe these types of substances in promotional literature and in Material Safety Data Sheets (MSDS) in any way they wish. For example, the substance silica, crystalline, has no CASRN assigned to it and does not appear on the TSCA Inventory, but it has been listed by California under Proposition 65 as a carcinogen. The list of various forms of silica in Table 4.1 does not contain forms that are specifically described as being crystalline, but two of them (CASRN 112945-52-5 and 112926-00-8) clearly state that they are not crystalline (crystalline-free). Some suppliers may use these CAS numbers on their MSDS to assure California customers that their products are not subject to a Proposition-65 warning, even though the correct CASRN for TSCA purposes is 76310-86-9. 

FIGURE 8.10 (a) Lower explosive limits for selected organic solvents, (b) Upper explosive limits for selected organic solvents. (Note Data derived from explosive limit information documented in Material Safety Data Sheets and other sources and other sources.)... 

Information to do with the effect of a chemical on human beings is provided in Material Safety Data Sheets (MSDSs) as discussed in Chapter 5. The EPA RMP Lookup Tables provide further guidance. Other sources of information include the following ... 

As discussed in Chapter 3, the selection of raw materials and chemical reactions is often suggested by chemists, biologists, biochemists, or other persons knowledgeable about the chemical conversions involved. In recent years, with the tremendous increase in awareness of the need to avoid handling hazardous and toxic chemicals, in connection with environmental and safety regulations (as discussed in Sections 1.3 and 1.4), raw materials and chemical reactions are often selected to protect the environment and avoid the safety problems that are evident in Material Safety Data Sheets (MSDSs). For example, recall that when the vinyl chloride... 

The items are those recommended by (a) manufacturers, either in technical bulletins or in Material Safety Data Sheets, (b) the Manufacturing Chemists Association, or (c) the National Safety Coxmcil, for use by personnel while responding to fire or accidental discharge of the chemical. They are intended to protect the lungs, eyes, and skin. There are many plastics and rubber compounding ingredients, as well as the monomers themselves, which are toxic and pose fire and explosion hazards. The user must consult a Material Safety Data Sheet (MSDS) for the specific properties and safety hazards associated with the chemicals handled. An MSDS will provide specific recommendations on the required personal protective equipment that should be used when handling a certain chemical. 

Table 13.3 Acronyms of Legal Acts Common in Material Safety Data Sheets...

The exact composition of products with which the patient has come into contact at the workplace is not known, or is not known before patch testing. In general, all ingredients occurring in the industrial chemicals are not listed in material safety data sheets... 

Henriks-Eckerman M-L, Kanerva L (1997) Product analysis of acrylic resins compared to information given in material safety data sheets. Contact Dermatitis 36 164-165 Henriks-Eckerman M-L, Laijoki T (1986a) Aliphatic polyamines and epoxy oligomers in cold cured epoxy products (in Finnish with English summary). Tyoterveyslaitoksen tut-kimuksia 4 37-40 (summary p 69)... 

Henriks-Eckerman ML, Kanerva L (1997) Product analysis of acrylic resins compared to information given in material safety data sheets. Contact Dermatitis 36 164-165... 

The poly(alkylene oxide)s are an unusual family of polymeric materials because of the extremely diverse and critical functions they perform in commercial use. To most consumers, these materials are often hidden in the fine print that describes compositions on labels, in material safety data sheets, and in handling documents. To scientists, the poly(alkylene oxide)s are known as distinct materials that are available in a wide range of molecular weights, from dimer to polymers of tens of millions, and yet remain well-characterized species of controlled molecular-weight distribution and known structure and configuration. These polymers can form ionic or molecular complexes and can provide mixtures with wide ranges of compatibilities, solubilities. 

Information to do with the properties of hazardous chemicals is provided in Material Safety Data Sheets (MSDS), also known as Safety Data Sheets (SDS). They provide comprehensive information about the chemical that allows employers and workers to obtain concise, relevant, and accurate information that can be put in perspective with regard to the hazards, uses, and risk management of the chemical product in the workplace. The SDS should contain 16 sections. While there were some differences in existing industry recommendations, and requirements of countries, there was widespread agreement on a 16-section SDS that includes the following headings in the order specified ... 

Figure 37.1 below shows what typically can be found on labels and in material safety data sheets and what will change in the near future. 

Compare flammabdity and health safety risks that hydrogen, methanol, gasoline, and ethanol pose. You can find this information in material safety data sheets available online from various manufacturers. Is there a safe fuel ... 

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