Upper Explosion Limit

Flash points and autoignition temperatures are given in Table 11. The vapor can travel along the ground to an ignition source. In the event of fire, foam, carbon dioxide, and dry chemical are preferred extinguishers. The lower and upper explosion limits are 1% and 7%. 

Flammability Acrolein is very flammable its flash point is <0° C, but a toxic vapor cloud will develop before a flammable one. The flammable limits in air are 2.8% and 31.0% lower and upper explosive limits, respectively by volume. Acrolein is only partly soluble in water and will cause a floating fire, so alcohol type foam should be used in firefighting. The vapors are heavier than air and can travel along the ground and flash back from an ignition source. 

The relatively low flash points of some acrylates create a fire hazard. Also, the ease of polymerization must be home in mind in ah. operations. The lower and upper explosive limits for methyl acrylate are 2.8 and 25 vol %, respectively. Corresponding limits for ethyl acrylate are 1.8 vol % and saturation, respectively. All possible sources of ignition of monomers must be eliininated. 

Health and Safety Factors, Toxicology. Because low molecular weight phosphines generally are spontaneously flammable, they must be stored and handled in an inert atmosphere. The upper explosion limit is 1.6% and the upper limit is near 100% (93). The higher and less volatile homologues are more slowly oxidized by air and present less of a problem. 

Flammable or Explosive Limits — the upper and lower vapor eoneentrations at whieh a mixture will bum or explode. The lower explosive limit of p-xylene is 1.1 pereent by volume in air, whereas the upper explosive limit is 7.0 percent in air. A mixture of p-xylene vapor and air having a coneentration of <1.1 pereent in air is too lean in p-xylene vapor to bum. Conversely, a mixture containing more than 7.0 percent is too rieh in p-xylene to bum. By subtraetion (7.0 - 1.1), p-.xylene is said to have a flammable range of 5.9. Materials having low explosive limits and wide flammable ranges are extremely dangerous. 

Flammable Limits in Air - This is a concentration expressed as percent by volume of the chemical in air, whereby spontaneous combustion will be supported. The lowest concentration where combustion will be supported is known as the lower flammability limit (LFL) or lower explosion limit (LEL). LEL and LFL are considered interchangeable. The upper concentration limit is the UFL (Upper Flammability Limit) or UEL (Upper Explosion Limit). 

Upper Explosive Limit (UEL) or Upper Flammable Limit (UFL) ... 

UEL/UEL Upper Explosive Limit/Upper Elammable Limit... 

Among common areas where explosion can occur are coal mines, petrochemical plants, chemical plants, paint shops, grain handling industry, etc. Explosive limits for gases and vapors are expressed as percentages (% ), and may be defined as minimum and maximum concentrations of a flammable gas or vapor between which ignition occur. Concentrations below the lower explosive limit (LEL) are too lean to burn, while those above the upper explosive limit (UEL) are too rich. Table 7.8 lists explosive limits for some common gases. 

Lower and upper explosive limits (LEL, UEL) must be considered in order TO avoid dangerous operation in the incinerators. Thermal incinerators are normally designed to operate with concentrations below 2.5% of the LEI, lypically, the LEL ranges from 2500 to 10 000 ppmv. ... 

Lower explosive limit (LEL) The owe.st concentration of a substance m air at ambient temperature that will explode if ignited, expressed as a percentage of the substance in the room air by volume. See also Upper explosive limit (IJELj. 

UEL = upper explosive limit LEL = lower explosive limit... 

The vapor-air mixture in the drum is close to the optimum for an explosion. This usually occurs about midway between the lower and upper explosive limits. 

Upper Flammable Limit (UFL) That concentration of a combustible material in air above which ignition will not occur. It is often, interchangeably, called Upper Explosive Limit (UEL). Mixtures above this limit are said to be too rich. ... 

Flanumbility limits (or explosion limits) for a flammable gas define tlie concentration range of a gas-air ini. ture witliin wliich an ignition source can start a self-propagating reaction. Tlie minimmn and maximmn fuel concentrations in air tliat will produce a self-sustaining reaction mider given conditions are called tlie lower Jlammability limit (LFL) and tlie upper Jlammability limit (UFL). (The abbreviations LEL and UEL, for lower and upper explosivity limits, are sometimes used.) The flanunability limits are functions of... 

The composition of the gas mixture, which is introduced into the tube bundle reactor (tubes of 6-12 m length and 20-50 mm diameter, filled with the Ag catalyst) consists of 15-50 vol % ethylene, 5-9% oxygen, as much as 60% methane as dilution gas, and 10-15% carbon dioxide. The reaction therefore proceeds above the upper explosion limit. The ethylene conversion runs up to 10% per cycle through the reactor. The ethylene oxide selectivity amounts to 75-83 % maximum. The formed ethylene oxide is recovered by scrubbing with water and the newly formed carbon dioxide is separated from the cycle gas, e.g., by hot potash washing process. 

Mixtures become inflammable when the vapour concentration lies between two limits called the lower explosive limit (LEL) and the upper explosive limit (UEL). These limits depend on numerous factors, especially temperature and pressure. 

The effects of the presence of 44 gaseous or volatile materials upon the upper explosion limits of hydrogen-air mixtures have been tabulated. 

UEL Upper explosive limit in air, expressed as a percentage by volume. 

Lower explosion limit (LEL) and upper explosion limit (UEL) are used interchangeably with LFL and UFL. 

Explosions from vapors occur due to the rapid transfer of heat from one molecule to the next molecule. Additionally, vapors can only ignite when present in certain concentration ranges - known as their lower and upper explosive limits. Also, vapors disperse due to diffusion and convection therefore, if a vapor cloud is released and is not ignited, the hazard is soon gone. 

Dust presents a different type of hazard, because while it has a lower explosive limit, it does not have an upper explosive limit. This can result in a primary explosion, followed by secondary explosions as new air is provided. Secondly, dust does not diffuse away from its point of release, but settles out of the air and accumulates into layers. Unlike vapor, the dust explosion is caused by the radiant heat from one particle igniting the next. Because of this, the lower explosive limits for dusts are greatly higher than for vapors. Also, the size and shape of the dust particles are important factors in effecting its lower explosive limit. 

---