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Hydrazines nitro amines

Semi-carbazid.—When guanidine is nitrated, by means of a mixture of nitric and sulphuric acids, a nitro guanidine is obtained, which, on reduction, yields amino guanidine, and this, on boiling with dilute acids or alkalies, yields a compound known as semi-carbazid. This in turn breaks down into ammonia, hydrazine (di-amine) and water. [Pg.441]

This type of ring closure is achieved mostly either by reaction between a hydroxylamino and a nitroso group or between a hydrazine or amine derivative and a nitro or nitroso group. [Pg.680]

The nitrofurans are derivatives of S-nitro-2-furaldchydc. formed on reaction with the appropriate hydrazine or amine derivative. Antimicrobial activity is present only when the nitro group is in the 5 position. [Pg.252]

The various techniques of dispoal of wastes contaminated with chemical carcinogens are then discussed and some validated chemical degradation methods presented for the treatment of wastes and spillage containing aflatoxins, N-nitrosamines, N-nitros-amides, polycyclic aromatic hydrocarbons, hydrazines, aromatic amines, haloethers and some antineo-plastic agents. [Pg.101]

Depending on the reaction conditions and the reagents used, the reduction of N-nitroso compounds gives either substituted hydrazines or amines. However, reduction to hydrazine is not quite unambiguous and generally takes place in small yields. In addition, substituted hydrazines are not described to such an extent that they can be used for identification. Therefore, the reduction to the corresponding amine (which can be converted to a suitable derivative) is more useful. The reduction is carried out with zinc in hydrochloric acid as was described for the reduction of nitro compounds. [Pg.363]

This method cannot be applied to polynitro amines, since these are so weakly basic that they can be diazotised only under special conditions in strongly acidic solutions. In such cases use may, however, be made of the mobility oonfared upon halogen atoms by the presence of nitro groups in the orlko and para positions. Thus the valuable reagent 2 4-dinitrophenylhydrazine is readily prepared by the condensation of 2 4-dinitrochlorobenzene with hydrazine ... [Pg.635]

Nitroso compounds and hydroxylamines can be reduced to amines by the same reagents that reduce nitro compounds (19-41). One example reduces a hydro-xylamine to the amine with CS2 in acetonitrile. N-Nitroso compounds are similarly reduced to hydrazines ... [Pg.1554]

Weak donor acceptor Alcohol, organic acid, phenol, primary and secondary amines, oxime, nitro and nitrile compounds having hydrogen at a-position, hydrazine, HF, and HCN... [Pg.86]

Abstract Starting with tetracyanodibenzo(l,4,7,10-tetrathia-(12-crown-4)) (1) and 4-nitro-l,2-dicyanobenzene (2), nitro-substituted dimeric phthalocyanine (3) was synthesized. In the second step, using hydrazine hydrate as a reductant, amine-substituted dimeric phthalocyanine (4) was synthesized from nitro-substituted dimeric phthalocyanine. Stractmres of all synthesized compounds were determined by elemental analyses, UV/vis, H-NMR and IR spectroscopy. [Pg.361]

Peripheral nitro substituents on the Pc offer a number of possibilities to obtain reactive binding sites, such as reduction to an amine. For this purpose, hydrazine hydrate is used as the reductant. [Pg.364]

Class 2 Molecules with active H-atoms and electronegative atoms with pairs of free electrons (0, N, F) Alcohols, acids, phenols, prim, and sek. amines, oximes, nitro compoimds and nitriles with a-H-atoms like hydrazine, NH3, HF, HCN, etc. [Pg.47]

Types of compounds are arranged according to the following system hydrocarbons and basic heterocycles hydroxy compounds and their ethers mercapto compounds, sulfides, disulfides, sulfoxides and sulfones, sulfenic, sulfinic and sulfonic acids and their derivatives amines, hydroxylamines, hydrazines, hydrazo and azo compounds carbonyl compounds and their functional derivatives carboxylic acids and their functional derivatives and organometallics. In each chapter, halogen, nitroso, nitro, diazo and azido compounds follow the parent compounds as their substitution derivatives. More detail is indicated in the table of contents. In polyfunctional derivatives reduction of a particular function is mentioned in the place of the highest functionality. Reduction of acrylic acid, for example, is described in the chapter on acids rather than functionalized ethylene, and reduction of ethyl acetoacetate is discussed in the chapter on esters rather than in the chapter on ketones. [Pg.321]

Reduction of nitro compound 31 with hydrazine hydrate/Raney nickel affords an amine, which produces pyrrolo-benzazepine 32 under intramolecular amide bond coupling (Equation (5) (1996BCF251). [Pg.7]

Laboratory studies have indicated an increasing number of further processes for which iron oxides may be used as catalysts. A sodium promoted iron oxide on a support of Si02 catalyses the gas phase oxidation (377-427 °C) by nitrous oxide, of pro-pene to propene oxide (Duma and Honicke, 2000). Ferrihydrite or akaganeite can be used to catalyse the reduction (at 55-75 °C) by hydrazine, of aromatic nitro compounds to aromatic amines (which are the starting materials for a huge range of chemicals) these Fe oxides have the potential to provide a safe and economical pathway to the production of these important organics (Lauwiner et al., 1998). [Pg.520]

Reduction of several classes of organics may be achieved using hydrazine and appropriate catalysts. It reduces nitro compounds to corresponding amines e.g., nitrobenzene to aniline ... [Pg.346]

Nitro compounds in presence of carbonyl group are selectively reduced to amines in the presence of Raney nickel catalyst. Hydrazine reduces nitrdes yielding hydrazones. Under controlled reaction conditions other functional groups, including nitroso and oxime, may be reduced. Many partially hydrogenated derivatives, such as azo-, hydrazo-, and azoxy compounds may be obtained by partial reduction with hydrazine. Reaction with chlorobenzene yields benzene. [Pg.347]

The reduction of carbazole nitro groups to the primary amines is straightforward stannous chloride, tin-hydrochloric acid, iron-hydrochloric acid" hydrogen-palladium/charcoal," hydrogen-nickel,hydrazine-palladium,and hydrazine-nickeP have all been employed. 3,6-Dichloro-l,8-dinitrocarbazole was partially reduced with sodium hydrogen sulfide to give l-amino-8-nitro-3,6-dichloro-carbazole. ... [Pg.154]

Sulfonsaure-alkylester konnen auch mittels Gabriel-Synthese in primare Amine iiber-gefuhrt werden. So lassen sich z, B. fluorierte Alkylamine wie 2-Amino-l,1,1-trifluor-ethan, 3-Amino-1,1,2,2-tetrafluor-propan und hohere Homologe durch Reaktion der entsprechen-den 2-Nitro-benzolsulfonsaure-fluoralkylester mit Kalium-phthalimid und anschliefiende Spaltung mit Hydrazin in guten Ausbeuten herstellen1. [Pg.741]

The keto-acid function is then converted to a pyridazinone by treatment with hydrazine (35-4). Catalytic hydrogenation then converts the nitro group to an amine (35-5) cyclization of the resulting ortho amino amide by means of a strong acid leads to the formation of the corresponding benzimidazole. There is thus obtained pimobendan (35-6) [37]. [Pg.344]

The synthesis of a triptan with a chiral side chain begins by reduction of the carboxylic acid in chiral 4-nitrophenylalanine (15-1). The two-step procedure involves conversion of the acid to its ester by the acid chloride by successive reaction with thionyl chloride and then methanol. Treatment of the ester with sodium borohy-dride then afford the alanilol (15-2). Reaction of this last intermediate with phosgene closes the ring to afford the oxazolidone (15-3) the nitro group is then reduced to the aniline (15-4). The newly obtained amine is then converted to the hydrazine (15-5). Reaction of this product with the acetal from 3-chloropropionaldehyde followed by treatment of the hydrazone with acid affords the indole (15-6). The terminal halogen on the side chain is then replaced by an amine by successive displacement by means of sodium azide followed by catalytic reduction of the azide. The newly formed amine is then methylated by reductive alkylation with formaldehyde in the presence of sodium cyanoborohydride to afford zolmitriptan (15-7) [15]. [Pg.392]


See other pages where Hydrazines nitro amines is mentioned: [Pg.479]    [Pg.214]    [Pg.32]    [Pg.559]    [Pg.404]    [Pg.277]    [Pg.370]    [Pg.233]    [Pg.150]    [Pg.99]    [Pg.193]    [Pg.113]    [Pg.339]    [Pg.534]    [Pg.952]    [Pg.1171]    [Pg.158]    [Pg.73]    [Pg.1282]    [Pg.135]    [Pg.280]    [Pg.550]    [Pg.209]    [Pg.598]    [Pg.610]   
See also in sourсe #XX -- [ Pg.94 , Pg.188 ]




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