Glycoside sulfates

Roubal et al. (8) applied TLC to the separation and identification of metabolites of l c-iabeled naphthalene administered to coho salmon fingerlings via intraperitoneal injection. 1-Naphthol, a dihydrodiol, mercapturic acid, 1-naphthyl glucuronic acid and a glycoside/sulfate fraction were identified in brain, liver, gall bladder, and muscle 1-naphthol, a dihydrodiol, and 1-naphthyl glucuronic acid were the only metabolites found in heart. 

Table I lists the sugar sulfates and glycoside sulfates that have been...

Not enough monomeric glycoside sulfates have been examined to permit more than a few preliminary observations to be made. Methyl /3-D-galacto-pyranoside 6-sulfate (11) rapidly consumes 2 moles of periodate per mole, liberating 1 mole of formic acid, and is not oxidized further, as is to be ... 

Several steroidal saponin sulfates have been reported from starfish (Hostettmann, 1985). Sea cucumbers secrete water-soluble glycosides, holothurins, that possess greater hemolytic ability than saponins of plant origin. These compounds are mixtures of glycoside sulfates (Agarwal and Ras-togi, 1974). 

Riccio, R., O. Squillace-Greco, L. Minale, J. Pusset, and J.L. Menou Starfish Saponins, Part 18. Steroidal Glycoside Sulfates from the Starfish Linckia laevigata. J. Nat. Prod. 48, 97 (1985). 

Penares Triterpenic glycosides, sulfated cyclic depsipeptides, polyamines, azetidine derivatives... 

D Auria, M.V., lorizzi, M., Minale, L., Ricdo, R., and Uriarte, E. (1990b) Starfish saponins. Part 41. Structure of two new steroidal glycoside sulfates (miniatosides A and B) and two new polyhydroxylated sterols from the starfish Patiria miniata. J. Nat. Prod., 53, 94-101. 

Maier, M.S., Roccatagliata, A., and Seldes, A.M. (1993) Two novel steroidal glycosides sulfates from the starfish Cosmasterias lurida. J. Nat. Prod., 56,939-942. 

Miyamoto, T., Togawa, K., Higushi, R., Komori, T., and Sasaki, T. (1990b) Constituents of Holothuroidea. II. Six newly identified biologically active triterpenoid glycoside sulfates from the sea cucumber Cucumaria echinata. Liebigs Ann. Chem., 453 60. 

Riccio, R., Pizza, C., Squillace-Greco, O., and Minale, L. (1985e) Starfish saponins. Part 17. Steroidal glycoside sulfates from the starfish Ophidiaster ophidianus (Lamarck) and Hacelia attenuata (Gray)./. Chem. Soc. Perkin Trans. I, 655-660. 

Riccio, R., Zollo, F., Finamore, E., Minale, L., Laurent, D., Bargibant, G., and Pusset, J. (1985g) Starfish saponins. 19. A novel steroidal glycoside sulfate from the starfishes Protoreaster nodosus and Pentareaster alveolatus.. Nat. Prod., 48, Ibb-ni. 

Riccio, R., D Auria, M.V., and Minale, L. (1986a) Two new steroidal glycoside sulfates, longicauside-A and -B from the Mediterranean ophiuroid Ophioderma longicaudum. J. Org. Chem., 51, 533-536. 

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