Gas firing

The high point, before the introduction of modem electrical and oil- or gas-fired kilns, was the development in China of the dragon kiln, a tunnel kiln built against a hillside, with a draft which resulted in the temperatures needed for the firing of porcelain ware. 

Year Petroleum Gas-fired Internal combustion andgas turbine Total... 

FIOR Process. In the FIOR process, shown in Figure 5, sized iron ore fines (0.04—12 mm) are dried in a gas-fired rotary dryer. A skip hoist dehvers the dry fines to lock hoppers for pressurizing. The fines pass through four fluidized-bed reactors in series. Reactor 1 preheats the ore to 760°C in a nonreducing atmosphere. Reactors 2, 3, and 4 reduce the ore at 690—780°C. At higher (ca 810°C) temperatures there is a tendency for the beds to defluidize as a result of sticking or hogging of the reduced material. 

Many kilns that formerly were direct coal-fired or producer-gas verticals were retrofitted to natural gas firing with center-burners and after World War II, dramatically improving lime quaUty, kiln capacity, and fuel efficiency. By the 1960s, this improved vertical kiln had lost favor to rotary and other special kilns because of the supply and cost problems of oil and gas in the United States and the spectacular improvement in rotary kiln performance. Many natural gas-fired center burners were permanently closed and dismanded because they could not be converted to coal. However, the reverse occurred in Europe where the extensive oil and gas discoveries heightened interest in the new, advanced vertical kilns. 

Air preheat temperature requirements of 2250—2300 K are anticipated for natural gas-fired systems, and about 2000 K for oil or coal-fired systems (11). Use of 32—40% oxygen enrichment lowers the preheat temperature requirement to a moderate 900—1000 K, which can be attained with conventional metal-type tubular heat exchangers. Depending on the cost of oxygen, this is a viable alternative to the use of separately fired high temperature preheaters. 

For gas-fired systems the state-of-the-art is represented by the preheater described in Reference 69. A pebble bed instead of a cored brick matrix is used. The pebbles are made of alumina spheres, 20 mm in diameter. Heat-transfer coefficients 3—4 times greater than for checkerwork matrices are achieved. A prototype device 400 m in volume has been operated for three years at an industrial blast furnace, achieving preheat temperatures of 1670 to 1770 K. 

Italy Industrial MHD Geneva MDA 1 1.4 gas-fired test facihty... 

Russia Institute of High Temp Moscow U-25G 25 3.5 integrated facihty originally gas-fired, now coal-fired... 

Refined calcined alumina is commonly used in combination with high purity limestone [1317-65-3] to produce high purity calcium aluminate cement (CAC). The manufacture, properties, and appHcations of CAC from bauxite limestone, as weU as high purity CAC, has been described (104). High purity CAC sinters readily in gas-fired rotary kiln calcinations at 1600 —1700 K. CAC reactions are considered practically complete when content of free CaO is less than 0.15% andloss on ignition is less than 0.5% at 1373 K. 

Gas turbine-based power plants, particularly natural gas-fired cogeneration and combined-cycle faciUties, have proven to be highly rehable, efficient, and environmentally attractive. Advances in machine design, more efficient plant integration, and optimistic forecasts for the availabiUty of affordable natural gas worldwide have boosted the appeal of these systems for both base-load and peaking service. 

At least two manufacturers have developed and installed machines rated to produce more than 210 MW of electricity in the simple-cycle mode. In both cases, the machines were designed and manufactured through cooperative ventures between two or more international gas turbine developers. One 50-Hz unit, first installed as a peaking power faciUty in France, is rated for a gross output of 212 MW and a net simple-cycle efficiency of 34.2% for natural-gas firing. When integrated into an enhanced three-pressure, combined-cycle with reheat, net plant efficiencies in excess of 54% reportedly can be achieved. 

Most gas-fired, heavy-duty gas turbines installed as of 1996 operate at gas pressures between 1.2 and 1.7 MPa (180—250 psig). However, aero derivative gas turbines and newer heavy-duty units can have such high air-inlet compression ratios as to require booster compressors to raise gas inlet pressures, in some cases as high as 5.2 MPa (750 psig). 

Motor-driven, multistage reciprocating compressors have reportedly been the most popular choice for aeroderivatives. Motor-driven, oil-fiooded screw compressors are also used in some cases. High horsepower, multistage centrifugal compressors, similar to those used at many pipeline compressor stations, may be required for the newer heavy-duty units if the distribution pipeline pressure is insufficient (see Pipelines). Gas turbines have more stringent fuel-gas specifications in terms of cleanliness than do gas-fired boilers. Thus oil- and water-knockout systems, coalescing filters, and fine-mesh filters are used. 

AH gas-fired power plants require oxygen analy2ers to ensure that air has not been drawn into the piping system. Oxygen intake can lead to the presence of an explosive mixture in the pipeline before the fuel reaches the burner or combustor 2one. When gas-fired units are located in an enclosed area, multiple ultraviolet flame detectors are used to shut down equipment and flood the area with CO2 or a chemical fire suppressant whenever a spark or flame is detected. 

Artificial surfaces must be resistant to cigarette bums, vandaUsm, and other harm. Fire resistance is most critically evaluated by the NBS flooring radiant panel test (10). In this test, a gas-fired panel maintains a heat flux, impinging on the sample to be tested, between 1.1 W/cm at one end and 0.1 W/cm at the other. The result of the bum is reported as the flux needed to sustain flame propagation in the sample. Higher values denote greater resistance to burning results depend on material and surface constmction. Polypropylene turf materials are characterized by critical radiant flux indexes which are considerably lower than those for nylon and acryflc polymers (qv) (11). 

Vitreous silica is used for gas-heated or electrically heated devices ia various shapes, eg, as a tube or muffle because of its electrical resistivity, impermeabihty, and low expansion. In its simplest form, an electric-resistance furnace consists of a vitreous siUca tube or pipe on which the resistance element is wound (see Furnaces, ELECTRIC). Because of its iadifference to temperature gradients, a tubular furnace of vitreous siUca maybe made to operate at different temperatures at various portions of the tube, either by arrangement of the heating elements or by cooling sections of the tube with water. Vitreous siUca pipes may be employed ia vacuum-iaduction and gas-fired furnaces (see Vacuum technology) (221). 

A further enhancement to the HRS process whereby the exhaust from a gas fired turbine is used to superheat steam from the HRS process is also possible (129). The superheated steam is then fed through a turbogenerator to produce additional electricity. This increases the efficiency of heat recovery of the turbine exhaust gas. With this arrangement, electric power generation of over 13.6 kW for 1 t/d (15 kW/STPD) is possible. Good general discussions on the sources of heat and the energy balance within a sulfuric acid plant are available (130,131). 

Fig. 2. Gas-fired denitration pots for denitration of U02(N02)2 6H20. (a) The large pot (1.68 M ID, 0.81 m height) is heated by three concentric rings of small radiant gas burners, (b) The small pot (76 cm ID, 46 cm height) is heated by four gas burners iaside a ceramic furnace (40).

Metafile arsenic can be obtained by the direct smelting of the minerals arsenopyrite or loeUingite. The arsenic vapor is sublimed when these minerals are heated to about 650—700°C in the absence of air. The metal can also be prepared commercially by the reduction of arsenic trioxide with charcoal. The oxide and charcoal are mixed and placed into a horizontal steel retort jacketed with fire-brick which is then gas-fired. The reduced arsenic vapor is collected in a water-cooled condenser (5). In a process used by Bofiden Aktiebolag (6), the steel retort, heated to 700—800°C in an electric furnace, is equipped with a demountable air-cooled condenser. The off-gases are cleaned in a sembber system. The yield of metallic arsenic from the reduction of arsenic trioxide with carbon and carbon monoxide has been studied (7) and a process has been patented describing the gaseous reduction of arsenic trioxide to metal (8). 

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