Heat output

Pyrotechnic mixtures may also contain additional components that are added to modify the bum rate, enhance the pyrotechnic effect, or serve as a binder to maintain the homogeneity of the blended mixture and provide mechanical strength when the composition is pressed or consoHdated into a tube or other container. These additional components may also function as oxidizers or fuels in the composition, and it can be anticipated that the heat output, bum rate, and ignition sensitivity may all be affected by the addition of another component to a pyrotechnic composition. An example of an additional component is the use of a catalyst, such as iron oxide, to enhance the decomposition rate of ammonium perchlorate. Diatomaceous earth or coarse sawdust may be used to slow up the bum rate of a composition, or magnesium carbonate (an acid neutralizer) may be added to help stabilize mixtures that contain an acid-sensitive component such as potassium chlorate. Binders include such materials as dextrin (partially hydrolyzed starch), various gums, and assorted polymers such as poly(vinyl alcohol), epoxies, and polyesters. Polybutadiene mbber binders are widely used as fuels and binders in the soHd propellant industry. The production of colored flames is enhanced by the presence of chlorine atoms in the pyrotechnic flame, so chlorine donors such as poly(vinyl chloride) or chlorinated mbber are often added to color-producing compositions, where they also serve as fuels. 

The first large-scale commercial oxychlorination process for vinyl chloride was put on-stream in 1958 by The Dow Chemical Company. This plant, employing a fixed-tube reactor containing a catalyst of cupric chloride on an active carrier, produced 1,2-dichloroethane from ethylene. The high temperatures involved in the reaction were moderated by a suitable diluent. The average heat output from the reaction is 116 kJ/mol (50,000 Btu/lb mol). 

Fig. 11. Effect of coal rank on furnace sizing (constant heat output) (82), where W = width, D = depth, and h and H are the heights indicated. A represents medium volatile bituminous B, high volatile bituminous or subbituminous C, low sodium lignite D, medium sodium lignite and E, high...

Cold fusion has been reported to result from electrolyzing heavy water using palladium [7440-05-3] Pd, cathodes (59,60). Experimental verification of the significant excess heat output and various nuclear products are stiU under active investigation (61,62) (see Eusion energy). 

High or low fuel gas pressure ean have a dramatic effect on the operation of a firetube heater. Burners are typically rated as heat output at a specified fuel pressure. A significantly lower pressure means inadequate heat release. Significantly higher pressure causes overfiring and over heating. The most common causes of a fuel gas pressure problem are the failure of a pressure regulator or an unacceptably low supply pressure. 

In an operating plant, the air rate can be adjusted at fixed heat output (constant steam rate for a boiler) until minimum fuel rate is achieved. This is the optimum so long as the warnings below ai e heeded. 

The cycle consists of two phases. In the first, suppose pumping to be anticlockwise, and initially that bed 1 is cold (maximum adsorbent concentration) and bed 2 is hot (minimum adsorbent concentration). The oil recovers heat from bed 2, has a further heat addition from the gas heat exchanger and then proceeds to heat bed 1 via the special heat exchanger within it. Bed 1 desorbs refrigerant which passes to the condenser (giving a useful heat output in the case of a heat pump) and bed 2 adsorbs gas from the evaporator which... 

Figure 6.11 shows a famous example of the application of isothermal calorimetry. Gordon (1955) deformed high-purity copper and annealed samples in his precision calorimeter and measured heat output as a function of time. In this metal, the heat output is strictly proportional to the fraction of metal recrystallised. 

Impurities or the delayed addition of a catalyst causes inhibition or delayed initiation resulting in accumulation in the reactors. The major hazard from accumulation of the reactants is due to a potentially rapid reaction and consequent high heat output that occurs when the reaction finally starts. If the heat output is greater than the cooling capacity of the plant, the reaction will run away. The reaction might commence if an agitator is restarted after it has stopped, a catalyst is added suddenly, or because the desired reaction is slow to start. 

A point source has a convective heat output of 100 W (see Fig. 7, >2). Determine the airflow rate 1 m above the source. 

Heat output The useful heat output from a heat generator or a heat exchanger. 

Plate-type design (space heaters) Type of heat exchanger characterized by a substantial proportion of its heat output being by way of radiant energy. 

For a gas turbine operating as a combined heat and power plant, the energy utilisation factor (EUF) is a better criterion of performance than the thermal efficiency. It is defined as the ratio of work output (W) plus useful heat output (Qu) to the fuel energy supplied (F),... 

Electrical power output Heat output (normal load) (with supplementary firing) Gas fuel energy supply Thermal efficiency... 

The higher heat of formation and less oxygen in the HTPB molecule implies a higher heat output with greater oxidizer loading capacity. However, more oxygen in the... 

The metabolic rate is increased by several hormones including thyi oid hormone, adrenalin and male sex hormones. The increase in metabolic rate caused by male sex hormones explains why males have slightly higher average metabolic rates than females of the same size and age. Living in a cold climate increases the metabolic rate because the cold stimulates thyroid hormone production and this hormone increases heat output of the body, while living in a warm climate causes the metabolic rate to decrease. 

The metabolic rate can be measured in several ways. When no external work is being performed, the metabolic rate equals the heat output of the body. This heat output can be measured by a process called direct calorimetry. In this process, the subject IS placed m an insulated chamber that is surrounded by a water jacket. Water flows through the jacket at constant input temperature. The heat from the subject s body warms the air of the chamber and is then removed by the water flowing through the jacketing. By measuring the difference between the inflow and outflow water temperatures and the volume of the water heated, it is possible to calculate the subject s heat output, and thus the metabolic rate, in calories. 

Some new features of furnaces available today include variable speed blowers, which deliver warm air more slowly and more quietly when less heat is needed, and variable heat output from the burner, which when combined with the variable speed blower allows for more continuous heating than the typical fixed firing rate. Distribution system features can be sophisticated with zoned heating which employs a number of thermostats, a sophisticated central controller, and a series of valves or dampers that direct airflow or water to different parts of the home only when needed in those areas. 

As with the electrical load profile, it is also necessary to analyze the heat load over the daily and annual cycles. Ideally, the heat load will match the available heat from the electrical generator (however, this is rarely the case). There will be periods when supplementary output will be necessary which can be achieved by, say, supplementary firing the waste heat gases of a gas turbine, or heat output reduction is necessary by the introduction of bypass stacks. For a steam turbine installation bypass pressure-reducing valves will be necessary to supplement steam output, while a dump condenser may be needed at low-process steam demands. The nature of the electrical and heat load will obviously have significant influence in the development of the scheme and scope of equipment. 

This is the ratio of heat input to the useful heat output of the boiler, taking account of heat losses in the flue gases, blowdown and radiation. It is covered in BS 845 Part 1, which fully details the concise or losses method of determining the efficiency of a boiler. 

For low-temperature heating systems using natural convective or radiant appliances the normal design water flow temperature to the system is 83°C (see also Table 27.8). Boost temperatures may be used on modulated-temperature systems because of the changes in heat output characteristics with varying temperatures. Additionally, comfort aspects must be borne in mind, as forced convective emitters operating on modulated temperature systems can deliver air streams at unacceptably low temperatures. 

Design arrangements for reduced-temperature secondary systems (sometimes referred to as injection circuits) include fixed provisions for minimum dilution rates. Conventional system-balancing devices with three-port automatic modulating valves to regulate mixed water temperatures and, hence, heat output are used. Automatic safety controls must prevent excessive temperatures occurring in the coil circuits, as floor fabrics or finishes could be damaged very rapidly. 

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