Fuel incomplete combustion

Carbon monoxide Motor vehicle emissions Burning fossil fuels Incomplete combustion Combines with hemoglobin to form carboxyhemoglobin, poisonous Asphyxia and death... 

Whatever the process of external combustion, it has been shown that the amount of harmfid emission can be minimized by carefid control of the fuel mixtures and the burning conditions (e.g. the combustion temperature). Flames near the sooting limit (i.e. those from fuel-rich mixtures whose conditions just define the onset of the release elemental carbon aerosol) exhibit a large number of intermediate species, such as H2 and CO, rather than H2O and CO2. Furthermore, depending on the fuel, incomplete combustion will lead to the likely production of a variety of hydrocarbons or aromatic compounds. 

Carbon monoxide is also produced during the incomplete combustion of organic fuels. Incomplete combustion of methane occurs when the supply of oxygen is limited. 

The diesel engine operates, inherently by its concept, at variable fuel-air ratio. One easily sees that it is not possible to attain the stoichiometric ratio because the fuel never diffuses in an ideal manner into the air for an average equivalence ratio of 1.00, the combustion chamber will contain zones that are too rich leading to incomplete combustion accompanied by smoke and soot formation. Finally, at full load, the overall equivalence ratio... 

Combustion. The burning of soHd, Hquid, and gaseous fuels as a source of energy is very common. Using sufficient and reHable combustion controls, this process seldom causes serious problems. However, some combustion processes are deHberately carried out with an inadequate oxygen supply in order to obtain products of incomplete combustion. Explosive mixtures sometimes occur, and then flashback is a serious problem. 

Unburnt hydrocarbon (UHC) and carbon monoxide (CO) are only produced in incomplete combustion typical of idle conditions. It appears probable that idling efficiency can be improved by detailed design to provide better atomization and higher local temperatures. CO2 production is a direct function of the fuel burnt (3.14 times the fuel burnt) it is not possible to control the production of CO2 in fossil fuel combustion, the best control is the increasing of the turbine efficiency, thus requiring less fuel to be burnt for the same power produced. 

Carbon monoxide is a colourless, odourless gas and - without chemical analysis - its presence is undetectable. It is produced by steam reforming or incomplete combustion of carbonaceous fuels typical carbon monoxide concentrations in common gases are given in Table 5.30. 

Combustion processes are the most important source of air pollutants. Normal products of complete combustion of fossil fuel, e.g. coal, oil or natural gas, are carbon dioxide, water vapour and nitrogen. However, traces of sulphur and incomplete combustion result in emissions of carbon monoxide, sulphur oxides, oxides of nitrogen, unburned hydrocarbons and particulates. These are primary pollutants . Some may take part in reactions in the atmosphere producing secondary pollutants , e.g. photochemical smogs and acid mists. Escaping gas, or vapour, may... 

Measures such as improved process design, operation, maintenance, housekeeping, and other management practices can reduce emissions. By improving combustion efficiency, the amount of products of incomplete combustion (PlCs), a component of particulate matter, can be significantly reduced. Proper fuel-firing practices and... 

The characterization of PIC (products of incomplete combustion) from the combustion of wood treated with pentachlorophenol (penta) is more widely documented in the open literature than creosote alone. However, both products are similar in chemical composition and likely result in comparable forms and concentrations of PIC. Literature reported studies on the combustion of these chemicals and wood treated by them, and the PIC generated are based upon optimal conditions. Optimal conditions are defined as those in which the fuel burns at the designed heat release rate with nominally 160% excess air and a low level (< 100 ppm) of carbon monoxide (CO) emissions in combustion (flue) gases. 

Combustion is the rapid exothermic oxidation of combustible elements in fuel. Incineration is complete combustion. Classical pyrolysis is the destructive distillation, reduction, or thermal cracking and condensation of organic matter under heat and/or pressure in the absence of oxygen. Partial pyrolysis, or starved-air combustion, is incomplete combustion and occurs when insufficient oxygen is provided to satisfy the combustion requirements. The basic elements of each process are shown on Figure 27. Combustion of wastewater solids, a two-step process, involves drying followed by burning. 

Odor and pollution problems are often experienced due to incomplete combustion when concentrated HjS is flared. When such considerations are expected to be critical, flare system designs should include a fuel gas connection and equipment sizing sufficient to handle an equal volume of fuel gas when flaring H2S at design rate. Where flaring of HjS is intermittent and the fuel gas diluent is continuous then steam injection at the base of the flare may be needed to reduce smoking. 

Smoke Aerosols formed from minute solid or liquid particles, most less than 1 xm in diameter, generated by the incomplete combustion of a fuel or by sublimation. 

Soot The aggregates leaving a combustion chamber due to incomplete combustion of a carbonaceous fuel. 

Carbon monoxide, or CO, is a highly toxic chemical that chemically binds to hemoglobin, rendering it incapable of carrying oxygen to the tissues of the body. CO is produced by the incomplete combustion of fossil fuels. Carbon monoxide levels across the United States fell, on average, by 39 percent between 1989 and 1998. 

According to r] = l-Rf the efficiency of the ideal Otto cycle increases indefinitely with increasing compression ratio. Actual engine experiments, which inherently include the real effects of incomplete combustion, heat loss, and finite combustion time neglected in fuel-air cycle analysis, indicate an efficiency that IS less than that given by r =l-R when a = 0.28. Furthermore, measured experimental efficiency reached a maximum at a compression ratio of about 17 in large-displacement automotive cylinders but at a somewhat lower compression ratio in smaller cylinders. 

If the engine is fed a mixture containing more fuel than the stoichiometric anioiint, the mixture is said to be rich, and carbon monoxide (CO) and hydrogen are added to the combustion products. Because these two gases are fuels themselves, their presence in the exhaust signifies incomplete combustion and wasted energy. 

Figure 19.1 indicates the flue losses to be expected for different temperatures and excess air. It is seen that considerable savings can be made, particularly at higher temperatures, by reducing excess air levels to a practical minimum. It is also evident that a reduction in air/gas ratio to below stoichiometric will cause a rapid deterioration in efficiency caused by the energy remaining in the incomplete combustion of fuel. 

An important principle is that the coal becomes ignited from the fuel which is on top of it and further down the grate. This reduces carry-over of smalTunburned particles, as the burning coal on top filters them out. Volatiles released from the fresh coal are also ignited and consumed in the burning layer. This minimizes smoke formation which is caused by incomplete combustion of the volatiles. 

Exhaust system The engine operating mode controls the tailpipe emissions of hydrocarbons (HC) and carbon monoxide (CO). Over 80% of HC and CO emissions are generated during cold-start and warm-up due to incomplete combustion. Fuel vaporization and fuel/ air mixing are important factors in achieving thorough combustion of the hydrocarbons. 

Carbon monoxide (CO) Is one of the most widely distributed air pollutants. It Is formed by natural biological and oxidation processes, the Incomplete combustion of carbon-containing fuels and various Industrial processes. However, the largest Individual source of man-made emissions Is motor vehicle exhausts which account for virtually all CO emitted In some urban environments. It has been estimated that global man-made emissions range from 300-1600 million tons per year, which Is approximately 60% of the total global CO emissions (22-23). 

Mere destruction of the original hazardous material is not, however, an adequate measure of the performance of an incinerator. Products of incomplete combustion can be as toxic as, or even more toxic than, the materials from which they evolve. Indeed, highly mutagenic PAHs are readily generated along with soot in fuel-rich regions of most hydrocarbon flames. Formation of dioxins in the combustion of chlorinated hydrocarbons has also been reported. We need to understand the entire sequence of reactions involved in incineration in order to assess the effectiveness and risks of hazardous waste incineration. 

The recommended method of trichloroethylene disposal is incineration after mixing with a combustible fuel (Sittig 1985). Care should be taken to carry out combustion to completion in order to prevent the formation of phosgene (Sjoberg 1952). Other toxic byproducts of incomplete combustion include polycyclic aromatic hydrocarbons and perchloroaromatics (Blankenship et al. 1994 Mulholland et al. 1992). An acid scrubber also must be used to remove the haloacids produced. 

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