Frequency definition

While for some purposes it may be necessary to have accurate frequency definition, for others good time discrimination is useful. These are opposite requirements. Because of the Fourier relationship between frequency and time, the more precisely the time of a signal is known, the greater bandwidth of frequencies is necessary (there is a close analogy here with Heisenberg s uncertainty principle). Approximately, the time resolution t is the reciprocal of the bandwidth Bw, so that their product Bwr 1. 

The single-frequency linewidth of the color center laser is truly exceptional in its purity. In single-mode cw operation, linewidths below 4 KHz have been achieved. This performance is attributable to the solid-state nature of the gain media there are no moving parts in the laser cavity to perturb the phase of the laser. Such precise frequency definition, coupled with broad tunability, has made the color center laser a powerful tool for spectroscopy and metrology. 

It is straightforward to operate a color center laser in a narrowline single mode that can be tuned to any wavelength within the tuning range of the crystal. Such capability has proven useful for molecular spectroscopists, where the excellent frequency definition and tunability of the color center laser have allowed detailed studies of many important molecular species. 

Rotating Wave Approximation with the Instantaneous Frequency Definition of the Photoassociation... 

In general, it seems more reasonable to suppose that in chemisorption specific sites are involved and that therefore definite potential barriers to lateral motion should be present. The adsorption should therefore obey the statistical thermodynamics of a localized state. On the other hand, the kinetics of adsorption and of catalytic processes will depend greatly on the frequency and nature of such surface jumps as do occur. A film can be fairly mobile in this kinetic sense and yet not be expected to show any significant deviation from the configurational entropy of a localized state. 

The two exponential tenns are complex conjugates of one another, so that all structure amplitudes must be real and their phases can therefore be only zero or n. (Nearly 40% of all known structures belong to monoclinic space group Pl c. The systematic absences of (OlcO) reflections when A is odd and of (liOl) reflections when / is odd identify this space group and show tiiat it is centrosyimnetric.) Even in the absence of a definitive set of systematic absences it is still possible to infer the (probable) presence of a centre of synnnetry. A J C Wilson [21] first observed that the probability distribution of the magnitudes of the structure amplitudes would be different if the amplitudes were constrained to be real from that if they could be complex. Wilson and co-workers established a procedure by which the frequencies of suitably scaled values of F could be compared with the tlieoretical distributions for centrosymmetric and noncentrosymmetric structures. (Note that Wilson named the statistical distributions centric and acentric. These were not intended to be synonyms for centrosyimnetric and noncentrosynnnetric, but they have come to be used that way.)... 

The sinc fiinction describes the best possible case, with often a much stronger frequency dependence of power output delivered at the probe-head. (It should be noted here that other excitation schemes are possible such as adiabatic passage [9] and stochastic excitation [fO] but these are only infrequently applied.) The excitation/recording of the NMR signal is further complicated as the pulse is then fed into the probe circuit which itself has a frequency response. As a result, a broad line will not only experience non-unifonn irradiation but also the intensity detected per spin at different frequency offsets will depend on this probe response, which depends on the quality factor (0. The quality factor is a measure of the sharpness of the resonance of the probe circuit and one definition is the resonance frequency/haltwidth of the resonance response of the circuit (also = a L/R where L is the inductance and R is the probe resistance). Flence, the width of the frequency response decreases as Q increases so that, typically, for a 2 of 100, the haltwidth of the frequency response at 100 MFIz is about 1 MFIz. Flence, direct FT-piilse observation of broad spectral lines becomes impractical with pulse teclmiques for linewidths greater than 200 kFIz. For a great majority of... 

Fault Tree Analysis. Fault trees represent a deductive approach to determining the causes contributing to a designated failure. The approach begins with the definition of a top or undesired event, and branches backward through intermediate events until the top event is defined in terms of basic events. A basic event is an event for which further development would not be useful for the purpose at hand. For example, for a quantitative fault tree, if a frequency or probabiUty for a failure can be deterrnined without further development of the failure logic, then there is no point to further development, and the event is regarded as basic. 

PR = perpendicular recording LR = longitudinal recording HFRH = high frequency recording heads RH/HDTV = recording heads for high definition television and Pa = perpendicular perpendicular anisotropy. 

Ideally a standard cell is constmcted simply and is characterized by a high constancy of emf, a low temperature coefficient of emf, and an emf close to one volt. The Weston cell, which uses a standard cadmium sulfate electrolyte and electrodes of cadmium amalgam and a paste of mercury and mercurous sulfate, essentially meets these conditions. The voltage of the cell is 1.0183 V at 20°C. The a-c Josephson effect, which relates the frequency of a superconducting oscillator to the potential difference between two superconducting components, is used by NIST to maintain the unit of emf. The definition of the volt, however, remains as the Q/A derivation described. 

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