Hardness filler

Mineral fillers used are calcium carbonate (CaCOj), China Clay (Al/0H [Si.,0 J), miea especially muscovite (KAyOHjFlJAlSijOj J), silica flour (SiO ), talc (Mg, (OH)j[Si Oj J), and wollastonite (CaSiOj). Parameters that need to be considered during inorganic filler selection are basicity, filler impurities that may influence the resin euring proeess, and filler hardness that eauses abrasion of the mold [1]. Mica filled phenolics are used in electrical parts because mica adds outstanding dielectric properties, high thermal and chemical resistance and low water absorption [1]. 

China clay is a widely used white filler in the rubber industry. Depending on particle size, it can be used as a semi-reinforcing filler (hard clay) or a non-reinforcing filler (soft clay) in such applications as chemical liners, bicycle tyres, conveyor belts, shoe soles, gaskets and flooring. Its use in plastics is much more limited. In thermoplastics it is used for speciality antiblocking, in thermosets it is used in urea-, phenol- and melamine formaldehyde, in unsaturated polyesters, and in epoxy resins. 

The mechanical properties of individual filler particles - as opposed to those of filled plastics - can be quite difficult to determine, and often the data are not readily available. Hardness is an exception, being one of the more frequently quoted mechanical properties of fillers, and the materials are sometimes divided loosely into hard and soft fillers. Hardness values, together vith density and refractive index, are listed for several fillers in Table 2. The density can be expressed either as true... 

It is known that in segmented polyurethanes, the main reinforcement mechanism comes from the aggregation of the hard s ments into hard phase nemo-domains. Thus, our polymer in effect becomes a nanocomposite, with glassy fillers (hard phase) in a rubbery matrix (soft phase). However, unlike most nanocomposites, fillers are chemically bonded to the matrix. 

Gier D R, O Neill R E, Adams M R, Priester, Jr. R D, Lidy W A, Barnes C G, Rightor E G and Davis B L (1998) Fillers, Hard Phases and Copolymer Polyols -Their Different Mechanism to Reinforce Flexible Polyurethane Foams, in Polyurethanes Expo 98, SPI Polyurethanes Division, Dallas, pp. 227-229. 

There is hardly a metal that cannot, or has not, been joined by some welding process. From a practical standpoint, however, the range of alloy systems that may be welded is more restricted. The term weldability specifies the capacity of a metal, or combination of metals, to be welded under fabrication conditions into a suitable stmcture that provides satisfactory service. It is not a precisely defined concept, but encompasses a range of conditions, eg, base- and filler-metal combinations, type of process, procedures, surface conditions, and joint geometries of the base metals (12). A number of tests have been developed to measure weldabiHty. These tests generally are intended to determine the susceptibiHty of welds to cracking. 

Phenol—formaldehyde (PF) was the first of the synthetic adhesives developed. By combining phenol with formaldehyde, which has exceptional cross-linking abiHties with many chemicals and materials, and a small amount of sodium hydroxide, a resin was obtained. The first resins soHdified as they cooled, and it was discovered that if it was ground to a powder with a small amount of additional formaldehyde and the appHcation of more heat, the mixture would Hquify and then convert to a permanently hard material. Upon combination of the powdered resin mixture with a filler material such as wood flour, the result then being placed in a mold and pressed under heat and pressure, a hard, durable, black plastic material was found to result. For many years these resulting products were called BakeHte, the trade name of the inventor. BakeHte products are still produced today, but this use accounts for only a small portion of the PF resins used. 

The cured polymers are hard, clear, and glassy thermoplastic resins with high tensile strengths. The polymers, because of their highly polar stmcture, exhibit excellent adhesion to a wide variety of substrate combinations. They tend to be somewhat britde and have only low to moderate impact and peel strengths. The addition of fillers such as poly (methyl methacrylate) (PMMA) reduces the brittleness somewhat. Newer formulations are now available that contain dissolved elastomeric materials of various types. These mbber-modifted products have been found to offer adhesive bonds of considerably improved toughness (3,4). 

Hardness. The hardness (qv), or related property abrasiveness, is an important filler property. Hardness is determined by comparison to materials of known hardness on the Mohs scale. On this nonlinear scale, diamond is rated 10, quartz 7, calcite 3, and talc 1. The abrasiveness of a filler is also dependent on psd and the presence of impurities, eg, ka olin clay (Mohs hardness of 3) can be quite abrasive because of the presence of quartz impurities. 

Hardness. The resistance of a fabricated mbber article to indentation, ie, hardness, is influenced by the amount and shape of its fillers. High loadings increase hardness. Fillers in the form of platelets or flakes, such as clays or mica, impart greater hardness to elastomers than other particle shapes at equivalent loadings. 

Filler loading Volume, parts Mooney viscosity Optimum cure (at 141°C), min Modulus (at 300%), MPa Tensde strength, MPa Elongation, % Hardness, Shore A NBS abrasion (ASTMD1630) Rebound, %... 

Other uses for coal-tar pitch include production as a binder for foundry cores, as a sealant for dry batteries, and in the manufacture of clay pigeons. PeUeted pitch used as the binder in foundry cores is a hard pitch suppHed as spherical granules which are formed by a spray-cooling process. Clay pigeons consist of disks molded from a mixture of hard pitch and a mineral filler such as clay or limestone dust. 

This resin, usually a viscous Hquid, is mixed with fillers, pigments, and a curing agent. The mix is then appHed to the substrate, and cure is obtained in a few hours. The product is strong, tough, and resistant to chemicals and abrasion. It is used for industrial and other doors subject to hard water. The use of epoxy resins for this purpose is only a small fraction of its total use. 

The modem interest in composite materials can be traced to the development of BakeHte, or phenoHc resin, in 1906. BakeHte was a hard, brittle material that had few if any mechanical appHcations on its own. However, the addition of a filler— the eadiest appHcations used short cellulose fibers (2)—yielded BakeHte mol ding compounds that were strong and tough and found eady appHcations in mass-produced automobile components. The wood dour additive improved BakeHte s processibiHty and physical, chemical, and electrical properties, as weU as reducing its cost (3,4). 

To optimize the lesin system foi a given process and part, consideration should be given to fillers that can gready affect the cost and performance of the composite. Because of their low viscosity, fillers can often be added to polyesters. Fillers are often much cheaper than the resin they displace, and they can improve the heat resistance, stiffness, and hardness of the composite. Certain fillers, such as fumed siUca, impart thixotropy to the resin, increasing its resistance to drainage. 

Mechanical properties depend considerably on the stmctural characteristics of the EPM/EPDM and the type and amount of fillers in the compound. A wide range of hardnesses can be obtained with EPM/EPDM vulcanisates. The elastic properties are by far superior to those of many other synthetic mbber vulcanizates, particularly of butyl mbber, but they do not reach the level obtained with NR or SBR vulcanizates. The resistance to compression set is surprisingly good, in particular for EPDM with a high ENB content. 

Cyclohexene oxide [286-20-4] M 98.2, b 131-133 /atm, dj 0.971, n 1.452. Fractionated through an efficient column. The main impurity is probably H2O. Dry over MgS04, filler and distil several limes (b 129-134 /aim). The residue is sometimes hard to remove from the distilling flask. To avoid this difficulty, add a small amount of a mixture of ground NaCl and Celite (1 1) to help break the residue particularly if H2O is added. [Org Synth Coll Vol I 185 7945.]... 

Particulate fillers are divided into two types, inert fillers and reinforcing fillers. The term inert filler is something of a misnomer as many properties may be affected by incorporation of such a filler. For example, in a plasticised PVC compound the addition of an inert filler will reduce die swell on extrusion, increase modulus and hardness, may provide a white base for colouring, improve electrical insulation properties and reduce tackiness. Inert fillers will also usually substantially reduce the cost of the compound. Amongst the fillers used are calcium carbonates, china clay, talc, and barium sulphate. For normal uses such fillers should be quite insoluble in any liquids with which the polymer compound is liable to come into contact. 

When employed in elastomeric systems it is commonly observed that the finer the particle size the higher the values of such properties as tensile strength, modulus and hardness. Coarser particles will tend to give compounds less strong than compounds with the filler absent, but if the particle size is sufficiently fine there is an enhancement in the above-mentioned properties (at least up to an optimum loading of filler) and the phenomenon is known as reinforcement. The particle shape also has an influence for example, the somewhat plate-like china... 

Fillers are commonly employed in opaque PVC compounds in order to reduce cost. They may also be employed for technical reasons such as to increase the hardness of a flooring compound, to reduce tackiness of highly plasticised... 

Soon after World War II the hard thermoplastic floor tile was developed. These tiles use coumarone resins as a binder for the other ingredients, which may contain fibrous fillers such as asbestos, inert fillers such as china clay and softeners such as paraffin wax. 

The choice of filler depends on the end use. Metal fillers will improve machineability, hardness and thermal conductivity but may in some cases inhibit cure. 

---