Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Extension set

The CamuS system is currently in the form of a laboratory prototype and is undergoing a series of validation tests using an extensive set of test-pieces covering a range of geometries and classes of defect which has been manufactured for the purpose. [Pg.772]

The editor provides two modes for drawing the structure and the draw mode. This distinction is important for differentiating chemical information from conventional drawings. Both modes are switchable and provide an extensive set of features in the menu bar to create chemical structures and reactions, or just drawings. The number of options can be quite confusing for beginners however, one becomes accustomed to them after a short period of vocational adjustment. [Pg.141]

The first example of enantioselective catalysis of a Diels-Alder reaction was reported in 1979 . Since then, an extensive set of successful chiral Lewis-acid catalysts has been prepared. Some selected examples will be presented here together with their mechanistic interpretation. For a more complete... [Pg.77]

A micelle-bound substrate will experience a reaction environment different from bulk water, leading to a kinetic medium effect. Hence, micelles are able to catalyse or inhibit organic reactions. Research on micellar catalysis has focused on the kinetics of the organic reactions involved. An overview of the multitude of transformations that have been studied in micellar media is beyond the scope of this chapter. Instead, the reader is referred to an extensive set of review articles and monographs" ... [Pg.129]

Table 7.8 contains values of p,/p for the common target elements employed in X-ray work. A more extensive set of mass absorption coefficients for K, L, and M emission lines within the wavelength range from 0.7 to 12 A is contained in Heinrich s paper in T. D. McKinley, K. F. J. Heinrich, and D. B. Wittry (eds.). The Electron Microprobe, Wiley, New York, 1966, pp. 351-377. This article should be consulted to ascertain the probable accuracy of the values and for a compilation of coefficients and exponents employed in the computations. [Pg.704]

At the time of a computer mn of a simulation, it is desirable to store only the parameters for those particular components involved in the simulation, and so this set of basic data is normally copied over from the permanent system parameters data bank into mn-time data locations. In typical flow-sheeting problems this involves the collection of particular parameters for 5 to 20 components from a data bank with extensive sets of data for up to several thousand components. [Pg.76]

Another example of a divalent metal of this group, but which in fact is probably entirely analogous to the dihydiides, is LaL. However, the most extensive set of examples of these metals in low formal oxidation states is provided by the binary and ternary halides produced by... [Pg.949]

From the experimental point of view, two important features need emphasis. First, the diet can be split into as many components as are appropriate to the problem, provided the list is complete. Secondly, the molecular level at which the components are categorized, either for the diet or for the body parts, is entirely open to choice, within the bounds set by the experimental data. Ideally, an extensive set of DIFFs could be set up at the molecular level (on individual amino acids, for example), from which the behavior at the level of proteins could be derived. However, the data to do this are simply... [Pg.216]

Data of Nomura and Funita (12). The predictive capabilities of EPM for copolymerizations are shown in Figures 8-9. Nomura has published a very extensive set of seeded experimental data for the system styrene-MMA. Figures 8 and 9 summarize the EPM calculations for two of these runs which were carried out in a batch reactor at 50 °C at an initiator concentration of 1.25 g dm 3 water. The concentration of the seeded particles was 6x10 dm 3 and the total mass of monomer was 200 g dm 3. The ratio of the mass of MMA to the total monomer was 0.5 and 0.1 in Figures 8 and 9 respectively. The agreement between the measured and predicted values of the total monomer conversion, the copolymer composition, and the concentration of the two monomers in the latex particles is excellent. The transition from Interval II to Interval III is predicted satisfactorily. In accordance with the experimental observations, EPM predicted no new particle formation under the conditions of this run. [Pg.376]

Broad and comprehensive, this book provides a cohesive treatment of the subject. It contains an extensive set of literature references and numerous illustrative figures. The authors use a mechanistic approach with emphasis on the pathways, and the principles that emerge provide a guide not only for specific compounds but also for those having a more remote structural resemblance. [Pg.711]

Spark sources are especially important for metal analysis. To date, medium-voltage sparks (0.5-1 kV) often at high frequencies (1 kHz and more), are used under an argon atmosphere. Spark analyses can be performed in less than 30 s. For accurate analyses, extensive sets of calibration samples must be used, and mathematical procedures may be helpful so as to perform corrections for matrix interferences. In arc and spark emission spectrometry, the spectral lines used are situated in the UV (180-380nm), VIS (380-550nm) and VUV (<180 nm) regions. Atomic emission spectrometry with spark excitation is a standard method for production and product control in the metal industry. [Pg.615]

The oxoanions of these elements represent an extensive set of potential ligands, characterized by a dominant, but not exclusive, tendency towards O bonding. Practically every known oxoanion has been introduced into the Co coordination sphere during the last century. [Pg.47]

Early scientific software packages focused on compilers, individual applications, and specific aspects of computer support such as statistics. More recently, software packages provide a broad, integrated, easy to use, and extensible set of capabilities to support research data management. RS/1 (TM) is described as an example of modern scientific software. [Pg.23]

Both equilibrium and kinetic data have been obtained. The most extensive set of equilibrium constants was determined for pyridines, RC5H4N. Values of K24 lie in the range 2xl0-2 (R = 2-Me) to > 5xl04 (R = 4-Me2N) according to a Hammett correlation, p-—7.5 (35). The... [Pg.177]

Complex 24 catalyzes this reaction, although the process occurs much more slowly than does Eq. (38). An extensive set of kinetic data lead to the mechanism presented in Scheme 15. It features two sequential sulfoxide reactions, one to form dioxorhenium(VII), the next to reconvert it to 24. [Pg.190]

Different tests arise from requiring power against specific elements or subsets of this rather extensive set of alternatives. [Pg.892]

First-order phase transition from a nucleonic matter to the strange quark state with a transition parameter A > 3/2 that occurs in superdense nuclear matter generally gives rise to a toothlike kink on the stable branch of the dependence of stellar mass on central pressure. Based on the extensive set of calculated realistic equations of state of superdense matter, we revealed a new stable branch of superdense configurations. The new branch emerges for some of our models with the transition parameter A > 3/2 and a small quark core (.Mcore 0.004 A- 0.03M ) on the M(PC) curve, with Mmax 0.08M and A 0.82M for different equations of state. Stable equilibrium layered... [Pg.339]

The second part, comprising four chapters, centers on an extensive set of data regarding the different environmental levels of all analyzed surfactants and their major degradation products in various countries. The aerobic biodegradation of surfactants is treated extensively, with emphasis on metabolic routes and novel and persistent metabolites formed. In addition, anaerobic degradation and sorption is also covered. [Pg.27]

An extensive set of experimental data on regioselectivity, face selectivity [106-109] and kinetics [110] of allylic alcohol epoxidation by the MTO system is available. On the basis of these results experimentalists have suggested a variety of transition structures (Figure 10) [28, 108, 110]. [Pg.306]


See other pages where Extension set is mentioned: [Pg.82]    [Pg.88]    [Pg.4]    [Pg.330]    [Pg.827]    [Pg.409]    [Pg.110]    [Pg.332]    [Pg.197]    [Pg.309]    [Pg.350]    [Pg.287]    [Pg.354]    [Pg.73]    [Pg.187]    [Pg.198]    [Pg.334]    [Pg.505]    [Pg.505]    [Pg.223]    [Pg.2]    [Pg.639]    [Pg.331]    [Pg.332]    [Pg.332]    [Pg.369]    [Pg.114]    [Pg.196]    [Pg.196]    [Pg.42]   
See also in sourсe #XX -- [ Pg.60 ]




SEARCH



Basis set extension

Basis set extension correction

Basis set extension, effect

Error-Balanced Segmented Contracted Gaussian Basis Sets A Concept and Its Extension to the Lanthanides

© 2024 chempedia.info