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Etherification process

Isomerization. Isomerization is a catalytic process which converts normal paraffins to isoparaffins. The feed is usually light virgin naphtha and the catalyst platinum on an alumina or zeoflte base. Octanes may be increased by over 30 numbers when normal pentane and normal hexane are isomerized. Another beneficial reaction that occurs is that any benzene in the feed is converted to cyclohexane. Although isomerization produces high quahty blendstocks, it is also used to produce feeds for alkylation and etherification processes. Normal butane, which is generally in excess in the refinery slate because of RVP concerns, can be isomerized and then converted to alkylate or to methyl tert-huty ether (MTBE) with a small increase in octane and a large decrease in RVP. [Pg.185]

There are etherification processes, such as MTBE and TAME, aimed at producing ethers from C, Cg, and tertiary olefins. [Pg.322]

The ether linkage is a major structural motif found in a broad range of natural and unnatural structures. Due to the biomedical and industrial importance of these molecules, the efficient and selective construction of ether bonds has been a topic of long-standing interest. While numerous etherification processes have been developed ever since the discovery of the Williamson ether synthesis,1 an increasingly large number of examples have employed transition... [Pg.649]

Another Rh-catalyzed protocol that has potentially broad utility has come from the reactions of Cu(i) alkoxides with allylic carbonates.190,191 Under the action of Wilkinson s catalyst modified by P(OMe)3, a variety of primary, secondary, and even tertiary aliphatic alcohols undergo an allylic etherification process with a high degree of retention of regio- and stereochemistry, thus providing expeditious access to a and/or ct -stereogenic ether linkages (Scheme 5).192... [Pg.662]

In addition to alkoxides, carbonyl oxygens have occasionally been recruited to function as nucleophiles in allylic etherification processes. The cyclization reactions of ketones containing internal allylic systems occur through O-allylation under Pd catalysis to give rise to vinyl dihydrofurans203 or vinyl dihydropyrans (Equation (51))204,205 in good yields. [Pg.663]

Since nucleophilic addition to a metal-coordinated alkene generates a cr-metal species bonded to an -hybridized carbon, facile 3-H elimination may then ensue. An important example of pertinence to this mechanism is the Wacker reaction, in which alkenes are converted into carbonyl compounds by the oxidative addition of water (Equation (108)), typically in the presence of a Pd(n) catalyst and a stoichiometric reoxidant.399 When an alcohol is employed as the nucleophile instead, the reaction produces a vinyl or allylic ether as the product, thus accomplishing an etherification process. [Pg.679]

Diethyl ether (Et20) can be prepared by heating ethanol with sulphuric acid at about 140 °C, and adding more alcohol as the ether distils out of the reaction medium. A similar continuous etherification process is used industrially. A more general procedure for the preparation of symmetrical ethers from primary alcohols (e.g. dibutyl ether, Expt 5.70) is to arrange for the water formed in the reaction to be removed azeotropically. [Pg.581]

Originally it was believed that etherification with sulfuric acid proceeded through the intermediate formation of alkyl sulfuric acids (R0S03H), since these products sometimes could be isolated from the reaction mixture. It now seems clear, however, that alkyl sulfuric acids are formed only as by-products in the reaction and are not actually intermediates in the etherification process. Thus, ethyl ter -butyl ether was prepared in yields of 95 per cent by heating a mixture of tert-butyl and ethyl alcohols containing 15 per cent sulfuric acid at 70°, yet titration of the cooled reaction mixture showed no evidence of the formation of an alkyl sulfuric acid.4 Furthermore, the yield of diethyl ether was 95 per cent when ethanol was passed through concentrated sulfuric acid heated to 140°, but when the reaction was carried out with ethyl sulfuric acid at the same temperature, much sulfur dioxide was evolved and the yield dropped to 70 per cent.4 8 We can, therefore, conclude that the... [Pg.214]

A large number of papers have been published on the process modeling and optimization of the etherification process. More details could be found in a handbook. The most important aspect of process improvement is catalyst improvement because the Amberlyst ion-exchange resin used in the MTBE synthesis has an upper thermal stability limit of less than 100°C and there is a need to develop other acidic catalysts with higher thermal stability. Some of the recent papers have described the use of zeolites. [Pg.2602]

In the same process during the up-stream conversion of say, p-cresol to PCME during etherification process, sodium sulfate is invariably produced as a liquid by-product and that needs careful processing of liquid PCME and separation of the inorganic layer from the organic mass. A proper system for recovery of sodium sulfate from the mass is no doubt one of the preconditions for a GMP and production of p-anisic aldehyde with a proper eco-system. [Pg.175]

Similar dehydration-etherification processes accompanied the use of C2-C10 alcohols as alkylating agents in the presence of rare earth-X (REX) and -Y (REY) and HY catalysts 43). [Pg.306]

Alternative approaches were developed by Rose and his colleagues at involving polyetherification reactions, in principle very similar to the poly-etherification processes that they had developed earlier for the manufacture of polysulphones Table 21.3), either by self-condensation of products such as IV or reaction between intermediates V and VI Figure 21.8). [Pg.603]

Typical etherification process conditions are (i) liquid phase (p<18bar), (ii) temperature <100°C and (iii) use of a strong cation-exchange resins as catalysts. It is an exothermic reactions with thermodynamic limitations. [Pg.143]

Figure 3.35 shows a process flow diagram of Phillips MTBE/ETBE/TAME process. This process is often called the Phillips Etherification Process. The reaction section (1,2) which receives methanol and isobutene concentrate, contains an ion exchange resin. The isobutene concentrate may be mixed olefins from a Fluid Catalytic Cracking Unit (FCCU) or steam cracker or from the on-purpose dehydration of isobutene (Phillips STAR process). High purity MTBE (99 wt%) is removed as a bottoms product from the MTBE fractionator (3). AH of the unreacted methanol is taken overhead, sent to a methanol... [Pg.170]

Ueno (ref. 5) draws attention to the fact that the production of water can also be due to a parasite etherification process (eqns. 17, 18). [Pg.124]

It is a marked characteristic of catalytic development that the empirical art has always been in advance of the science. Fermentation processes for wine and vinegar, the making of soap, and the etherification process all preceded the first formulations of catalytic action, and so it has remained down to the present time. The theory of catalysis has normally succeeded those practical applications that the ingenuity of the research scientist provided. In mitigation of this inferior position that the student of catalytic science has always experienced, it can at least be said that, out of his basic studies, an ever more rapid technical development has become possible. The theoretical study of basic principles has been the catalyst for an increasing tempo of technical development. The swiftness with which cata-... [Pg.1]

OH. These results suggest that some of the intramolecular hydrogen bonds between the 3-OH groups and 0-5 in the adjacent anhydro-glucose residues, known to occur in native celluloses, are retained even in swollen alkali cellulose, and thus have an effect on the etherification process. [Pg.295]

The reactions are catalyzed by strong acid ion-exchange resins and are usually carried out in the presence of inert components. For MTBE synthesis the iso-olefin is isobutylene and for TAME synthesis the iso-olefins are 2-methyl-l-butene and 2-methyl-2-butene. Further details on the chemistry of etherification processes are given in Chapter 5. [Pg.257]

First simulation results on steady state multiplicity of etherification processes were obtained for the MTBE process by Jacobs and Krishna [45] and Nijhuis et al. [78]. These findings attracted considerable interest and triggered further research by others (e. g., [36, 80, 93]). In these papers, a column pressure of 11 bar has been considered, where the process is close to chemical equilibrium. Further, transport processes between vapor, liquid, and catalyst phase as well as transport processes inside the porous catalyst were neglected in a first step. Consequently, the multiplicity is caused by the special properties of the simultaneous phase and reaction equilibrium in such a system and can therefore be explained by means of reactive residue curve maps using oo/< -analysis [34, 35]. A similar type of multiplicity can occur in non-reactive azeotropic distillation [8]. [Pg.257]

The second is autocatalysis by the products. In the open literature only little is known about the application of RD technology to autocatalytic systems. Although there seems to be some potential in such applications [84]. In contrast to this, selfinhibition of the reactants is frequently observed in heterogeneously catalyzed RD. Typical examples are the etherification processes that were treated above. Other examples are hydration processes for the production of tert-alcohols [31, 32, 84]. [Pg.263]

So far, only little work on RD column control is available in the open literature. Most of this work is concerned with case studies for esterification and etherification processes. Furthermore, the ethylene glycol process has received some attention because of its interesting dynamic behavior, which was summarized and illustrated above. A recent review on control case studies is available in [2]. Only very few general guidelines are available for RD column control including the work of Sneesby et al. [97] and Alarfaj and Luyben [2]. [Pg.271]

Because input multiplicity depends on the choice of the output variables, it can be avoided by selecting a suitable control configuration. In the present case, this problem is easily solved by taking a third temperature measurement into account as proposed in [90] and illustrated in Fig. 10.28. The difference between the two temperature measurements in the reaction zone is an indirect measure for the conversion of the chemical reaction and therefore leads to a unique steady state with good control characteristics. Similar control schemes, with direct and indirect inference of conversion were proposed in [99, 100, 105] for etherification processes. [Pg.273]

Etherification process of ethanol by caproic or lactic acids has been studied by these authors. The reaction of acetal formation was studied ... [Pg.553]

In a bromo-etherification process, amino alcohols 147, derived from the chiral pool, cyclized in a 1-endo manner to give rise to a range of chiral polysubstituted 1,4-oxazepanes 148 in good yields with moderate-to-excellent regio- and diastereoselectivities. The regioselectivity observed was... [Pg.544]

Keto-alcohols 149 participated in a stereoselective intramolecular reductive etherification process to afford differentially substituted 1,4-oxazepanes 150 in mosdy good yields with excellent diastereoselectivities. In a single example, the use of a carbon nucleophile allowed access to trisubstituted 1,4-oxazepane derivatives (13EJO2076). [Pg.545]

Since FCC olefins contain significant amounts of contaminants, including sulfur, nitrogen as well as diolefms, feed pretreatment is necessary to improve downstream alkylation or etherification processes. In addition, methanol and dimethyl ether significantly increase acid consumption. Thus, if an MTBE or TAME unit precedes an alkylation unit, the MTBE or TAME effluent must be treated to remove the trace methanol and oxygenates. [Pg.168]

In order to be competitive, these plants will have to be highly heat integrated between the isomerization, dehydrogenation and etherification processes. Minimal recycle is needed with cost effective use of low level heat. [Pg.173]


See other pages where Etherification process is mentioned: [Pg.185]    [Pg.208]    [Pg.686]    [Pg.106]    [Pg.185]    [Pg.388]    [Pg.2602]    [Pg.2609]    [Pg.172]    [Pg.242]    [Pg.262]    [Pg.308]    [Pg.544]   
See also in sourсe #XX -- [ Pg.17 , Pg.201 ]

See also in sourсe #XX -- [ Pg.142 , Pg.143 , Pg.469 , Pg.472 ]




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