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Estimation measurement

Plutonium (Pu) is an artificial element of atomic number 94 that has its main radioactive isotopes at 2 °Pu and Pu. The major sources of this element arise from the manufacture and detonation of nuclear weapons and from nuclear reactors. The fallout from detonations and discharges of nuclear waste are the major sources of plutonium contamination of the environment, where it is trapped in soils and plant or animal life. Since the contamination levels are generally very low, a sensitive technique is needed to estimate its concentration. However, not only the total amount can be estimated. Measurement of the isotope ratio provides information about its likely... [Pg.369]

Note that some organizations may not use the terminology used in this book and may not distinguish between SOPs and WIs. Standard Operating Procedures provide details of how a series of operations are carried out. An example of a SOP would be the detailed instruction for carrying out a particular analytical method. Work Instructions give details of how a specific operation is carried out. What might be classed as a WI is how to operate a particular instrument, how to estimate measurement uncertainty or how to calibrate a piece of equipment. [Pg.203]

The conceptual model uses the Source -Pathway - Receptor Paradigm. The paradigm requires that each of the parameters within the model are documented, estimated, measured or recorded. The model identifies the source of any contamination identifies who or what is affected (the receptor) and identifies how the source may reach the receptor (pathway). The collection of field data, observations and estimates confirms whether a linkage exists between the source and receptor. [Pg.549]

Standard hydrocarbon estimation. Measurement of the low-pressure radiative association rate constant is sufficient for assignment of if k and k are independently known, from the relation, ... [Pg.103]

A lot of guidance on how to estimate measurement uncertainties is available. All guides are freely available from the internet. [Pg.271]

Measurement uncertainty Since 2004 there has been considerable development in approaches to estimation of uncertainty and this chapter has been considerable revised and expanded in order to take into account new guidelines. Main difference is that several ways of estimating measurement uncertainty are know full acceptable and the analyst is free to choose approach dependent on scope and data availability. [Pg.337]

Any inferences about the difference between the effects of the two treatments that may be made upon such data are the observed rates, or proportions of deteriorations by the intrathecal route. In this example, amongst those treated by the intrathecal route 22/58 = 0.379 of patients deteriorated, and the corresponding control rate is 37/60 = 0.617. The observed rates are estimates of the population incidence rates, jtt for the test treatment and Jtc for the controls. Any representation of differences between the treatments will be based upon these population rates and the estimated measure of the treatment effect will be reported with an associated 95% confidence interval and/or p-value. [Pg.292]

In summary, economic analysis of medical technology or medical care evaluates a medical service by comparing its monetary cost with its monetary benefit (cost-benefit), by measuring its monetary cost in relation to its outcomes (cost-effectiveness), or simply by tabulating the costs involved (cost-identification). Direct costs are generated as services are provided. In addition, productivity costs should be considered, especially in determining the benefit of a service that decreases morbidity or mortality. Finally, the perspective of the study determines the costs and benefits that will be quantified in the analysis, and sensitivity analyses test the effects of changes in variable specifications for estimated measures on the results of the study. [Pg.41]

Elemental mass distribution - The aerosol sampled by the LPI for elemental analysis was impacted on coated mylar films affixed to 25 mm glass discs. The mylar had been coated with Apiezon L vacuum grease to prevent particle bound. The LPI samples were sent to Crocker Nuclear Laboratory for elemental analysis by PIXE using a focused alpha particle beam of 3 to 4 mm diameter. Nanogram sensitivities for most elements were achieved with the focused beam. A detailed description of the PIXE focused beam technique applied to LPI samples can be found in Ouimette (13). Based upon repeated measurements of field samples, the estimated measurement error was about 15-20% or twice the minimum detection limit, whichever was larger. [Pg.130]

Armishaw, P. (2003), Estimating measurement uncertainty in an afternoon. A case study in the practical application of measurement uncertainty, Accred. Qual. Assur., 8, 218-242. [Pg.786]

As I have shown, the response given by the model equation (3.5) has an error term that includes the lack of fit of the model and dispersion due to the measurement (repeatability). For the three-factor example discussed above, there are four estimates of each effect, and in general the number of estimates are equal to half the number of runs. The variance of these estimated effects gives some indication of how well the model and the measurement bear up when experiments are actually done, if this value can be compared with an expected variance due to measurement alone. There are two ways to estimate measurement repeatability. First, if there are repeated measurements, then the standard deviation of these replicates (s) is an estimate of the repeatability. For N/2 estimates of the factor effect, the standard deviation of the effect is... [Pg.88]

Samples distributed for analysis should have known quantity values with estimated measurement uncertainties, although, of course, these are not released to the participants until after the tests. The value of the measurand ( assigned) can be assigned by... [Pg.149]

The late William Horwitz, who is the leading exponent of top down measurement uncertainty, offers the following four approaches to estimate measurement uncertainty (Horwitz 2003) ... [Pg.169]

As reproducibility standard deviation from interlaboratory method validation studies has been suggested as a basis for the estimation of measurement uncertainty if it is known sR can be compared with a GUM estimate. It may be that with good bias correction, the estimate may be less than the reproducibility, which tends to average out all systematic effects including ones not relevant to the present measurement. Another touchstone is the Horwitz relation discussed in section 6.5.4. A rule of thumb is that the reproducibility of a method (and therefore the estimated measurement uncertainty) should fall well within a factor of two of the Horwitz value. [Pg.198]

Prepare any working calibrators and estimate measurement uncertainty of the quantity value of the calibrator. [Pg.223]

An important aspect of a full method validation is estimating bias components attributable to the method itself and to the laboratory carrying out the analysis. This step is required to estimate measurement uncertainty with a reasonable range that covers results that would be obtained in another laboratory of similar experience and standing. In chapter 5 I discussed these approaches at length. ISO (1994b) has a procedure for such interlaboratory... [Pg.230]

When estimating measurement results, the important thing is not only to know its accuracy but also the measurement confidence. The degree of measurement the confidence is estimated from confidence interval as defined by the level of significance. Let X denote the actual measurement value and AX the error in measuring... [Pg.192]

Inputs to the models describe the aircraft, nozzle, evaporation fate, meteorology, and biological environment. Obtaining sufficiently accurate model inputs is as difficult and challenging as developing the models themselves. The inputs are estimated, measured, calculated, or selected. [Pg.85]

By one convention, illustrated in Fig. 3, the validation of a measurement method, as replicated in the field, succeeds if the certified value of an appropriate RM falls within the estimated measurement uncertainty when the RM is measured using the method. That definition of validation does not require a mutual conformance condition in which the two values (that deter-... [Pg.17]

Although the advice is given mainly for the description of risk assessment results, it holds completely for exposure assessment, since the quantitative input for risk assessment is exposure assessment and uncertainty analysis. Since any description of the resulting exposure distribution(s) in terms such as very low , low , fair , moderate , high or extreme includes an evaluation, it must be defined and justified (EnHealth Council, 2004). Those communicating the results of an exposure assessment frequently use comparative reporting schemes, such as the 50%/majority/. .. /95% of data/measurements/individuals show exposure values/estimates/measurements lower than the tolerable daily intake... [Pg.75]

The chapters in the first half of the book describe the basic fundamental knowledge about plastics, processing aids and additives as well as the physical-chemical and mathematical background of the mass transport in these systems. The second half of the book applies the information contained in the first half to the estimation, measurement and evaluation of polymer/food interactions. Foods are considered to be the model substances here but these findings can be applied to many other products and systems as well. [Pg.639]

An essential caveat must be observed, however the molecular weight estimation measures the size of the detergent-protein complex, and different proteins bind different amounts of detergent. All empirical methods, accordingly, are fraught with possible error, and the results reported or reviewed now should be looked upon as preliminary and indicative, rather than definitive. [Pg.123]

While R22 is highly temperature dependent, the data are too limited to make an accurate determination of the activation energy, and 7 kcal should be considered an estimate. Measurements over the complete range of tropospheric temperatures are in progress [Johnston (119)]. The important loss reactions,... [Pg.434]

Quality of Analytical Results Classifiying Errors and Estimating Measurement Uncertainty... [Pg.17]


See other pages where Estimation measurement is mentioned: [Pg.130]    [Pg.25]    [Pg.36]    [Pg.165]    [Pg.125]    [Pg.125]    [Pg.109]    [Pg.173]    [Pg.105]    [Pg.33]    [Pg.147]    [Pg.163]    [Pg.169]    [Pg.223]    [Pg.260]    [Pg.124]    [Pg.68]    [Pg.325]    [Pg.245]    [Pg.94]    [Pg.25]    [Pg.75]    [Pg.111]    [Pg.386]    [Pg.216]    [Pg.2300]   


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