Emissions sulfur compounds

In the manufacture of varnish, heat is necessary for formulation and purificahon. The same may be true of operations preparing paints, shellac, inks, and other protective or decorative coahngs. The compounds emitted to the atmosphere are gases, some with extremely low odor thresholds. Acrolein, with an odor threshold of about 4000 /xg/m, and reduced sulfur compounds, with odor thresholds of 2 are bofh possible emissions... 

The most widely used pulping process is the kraft process, as shown in Fig. 6-11, which results in recovery and regeneration of the chemicals. This occurs in the recovery furnace, which operates with both oxidizing and reducing zones. Emissions from such recovery furnaces include particulate matter, very odorous reduced sulfur compounds, and oxides of sulfur. If extensive and expensive control is not exercised over the kraft pulp process, the odors and aerosol emissions will affect a wide area. Odor complaints have been reported over 100 km away from these plants. A properly controlled and operated kraft plant will handle huge amounts of material and produce millions of kilograms of finished products per day, with little or no complaint regarding odor or particulate emissions. 

The presence of asphaltenes, originating in the fuel, acts as a trap for vanadium, nickel, and sodium (which promote slagging and sulfur corrosion)-, these asphalthenes often contain sulfur compounds, which simply add to the contaminant load. Additionally, asphaltenes act as precursors to spherical stack solids (cenospheres), which are exhausted with the flue gases as stack emissions. 

Similarly, SO2 and SO3 (SOJ compounds are produced in combustion by the oxidation of sulfur compounds within the fuel source. SO , emitted into the atmosphere can be incorporated into aerosol particles and wet-deposited as corrosive sulfuric acid. Both NO , and SO , emissions contribute to acid rain content from wet deposition, due to their participation in the formation of nitric and sulfuric acid, respectively. 

During hot metal desulfurization, used to remove or alter sulfur compounds in the hot metal, the exhaust gases are found to bear particulate matter. Emissions may also result from slag handling. Sulfur dioxide is formed when the sulfur in the slag is exposed to air. The presence of moisture can... 

Power boilers at pulp and paper mills are sources of particulate emissions, S02, and NOx. Pollutants emitted from chemical recovery boilers include S02 and total reduced sulfur compounds (TRS). 

Many sophisticated analytical techniques have been used to deal with these complex mixtures.5,45,46 A detailed description is not possible here, but it can be noted that GLC, often coupled with mass spectrometry (MS), is a major workhorse. Several other GLC detectors are available for use with sulfur compounds including flame photometer detector (FPD), sulfur chemiluminescence detector (SCD), and atomic emission detector (AED).47 Multidimensional GLC (MDGC) with SCD detection has been used48 as has HPLC.49 In some cases, sniffer ports are provided for the human nose on GLC equipment. 

The reactions of H and F with CH3S are exothermic by 259 and 393 kJ mol-1, respectively, and either could be responsible for formation of CH2S(A3S) [7], Methylated sulfur compounds produce intense emission from HCF, while the corresponding ethyl-substituted compounds produce only trace or no HCF [6]. Emission from HFf was much stronger for the ethyl-substituted than for the methyl-substituted sulfides [6], This suggests that methyl radicals, formed perhaps in Reaction (34), lead to the formation of HCF. Emission of HCF has been identified in F2/CH4 flames [70] where it is attributed to the association reaction... 

The chemiluminescent reaction with chlorine dioxide provides a highly sensitive and highly selective method for only two sulfur compounds, hydrogen sulfide and methane thiol [81]. As in the flame photometric detector (FPD), discussed below, atomic sulfur emission, S2(B3S -> ) is monitored in the wave-... 

Hydrosulfreen A process for removing sulfur compounds from the tail gas from the Claus process. It combines the Sulfreen process with an upstream hydrolysis/oxidation stage, which improves efficiency and optimizes the emission control. Developed jointly by Lurgi and Societe National Elf Aquitaine, and installed in 1990 in the Mazovian Refining and Petrochemical Works, near Warsaw, Poland. See also Oxysulfreen. 

However, it is well known that various pollutants including sulfur compounds can be transported by air from country to country in the whole Asian domain and especially in North East Asia. Thus, model calculations have shown that in 1991— 1994 about 35% of oxidized sulfur species deposited in South Korea was transported from other locations, mainly from China (Sofiev, 1999). Accordingly, in spite of a national reduction in SO2 emission, the sulfur depositions are still very significant. 

FCC feed, sulfur compounds in, 11 716 FCC unit emissions, 11 714 controlling, 11 689-694 FCC unit regenerators, 11 713 air distribution systems in, 11 726 catalyst emissions from, 11 714—715 CO2 emissions from, 11 720—721 configuration and mechanical hardware in, 11 722-731 cyclones in, 11 726-728 design of, 11 722-723 flue gas handling in, 11 729 fluidization in, 11 723-725 nitrogen oxide emissions from,... 

The presence of sulfur compounds in the combustion process can affect the nitrogen oxides, as well. Thus, it is important to study sulfur compound oxidation not only to find alternative or new means of controlling the emission of objectionable sulfur oxides, but also to understand their effect on the formation and concentration of other pollutants, especially NO,. ... 

Little snlfnr is re-emitted from wetlands into the atmosphere. Table 8.7 gives estimates of global emissions of volatile sulfur compounds from different sources. Total emissions are in the range 98 to 120 Tg (S) year 75 % is anthropogenic, mainly from fossil fnel combustion in the northern hemisphere. The main natural sources are the oceans and volcanoes. Wetlands and soils contribnte less than 3 % of the total emission. 

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