Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Diffusion interpretation

As pointed out in the review by C )erly and Alder ( 31) the diffusion interpretation of the Schroedinger equation has an extensive history. The diffusion analogy becomes apparent if one writes the time-dependent Schroedinger Equation (one electron for simplicity) in terms of imaginary time, t. [Pg.311]

More general models for the porous structure have also been developed by Johnson and Stewart [60] and by Feng and Stewart [43], called the parallel cross-linked pore model. Here, Eqs. 3.5.b-4 to 6 or Eq. 3.5.b-7 are considered to apply to a single pore of radius r in the solid, and the diffusivities interpreted as fte actual values rather than effective diffusivities corrected for porosity and tortuosity. A pore size and orientation distribution function /(r, Q), similar to Eq. 3.4-2, is defined. Then /(r, Q)dri is the fraction open area of pores with radius r and a direction that forms an angle Q with the pdlet axis. The total porosity is then... [Pg.172]

FIdthmann H, Beck C, Schinke R, Woywod C and Domcke W 1997 Photodissociation of ozone in the Chappuis band. II. Time-dependent wave packet calculations and interpretation of diffuse vibrational... [Pg.1090]

Proposed flux models for porous media invariably contain adjustable parameters whose values must be determined from suitably designed flow or diffusion measurements, and further measurements may be made to test the relative success of different models. This may involve extensive programs of experimentation, and the planning and interpretation of such work forms the topic of Chapter 10, However, there is in addition a relatively small number of experiments of historic importance which establish certain general features of flow and diffusion in porous media. These provide criteria which must be satisfied by any proposed flux model and are therefore of central importance in Che subject. They may be grouped into three classes. [Pg.50]

In general, tests have tended to concentrate attention on the ability of a flux model to interpolate through the intermediate pressure range between Knudsen diffusion control and bulk diffusion control. What is also important, but seldom known at present, is whether a model predicts a composition dependence consistent with experiment for the matrix elements in equation (10.2). In multicomponent mixtures an enormous amount of experimental work would be needed to investigate this thoroughly, but it should be possible to supplement a systematic investigation of a flux model applied to binary systems with some limited experiments on particular multicomponent mixtures, as in the work of Hesse and Koder, and Remick and Geankoplia. Interpretation of such tests would be simplest and most direct if they were to be carried out with only small differences in composition between the two sides of the porous medium. Diffusion would then occur in a system of essentially uniform composition, so that flux measurements would provide values for the matrix elements in (10.2) at well-defined compositions. [Pg.101]

The size of the error which can be introduced by imprecise interpretation of the data in terms of an "effective diffusion coefficient" can easily be estimated. Denoting by flux of substance 1 in the... [Pg.104]

It appears that a loose interpretation of this type may be the origin of a discrenancy found by Otanl and Smith [59] in attempting to apply effective diffusivities from Wakao and Smith s [32] isobaric diffusion data to measurements on a chemically reacting system. This was pointed out by Steisel and Butt [60], and further pursued to the point of detailed computer modeling of a particular pore network by Wakao and Nardse [61]. [Pg.104]

In contrast to the cell experiments of Gibilaro et al., it is now seen from equation (10.45) that measurement of the delay time gives no information about diffusion within the pellets this can be obtained only through equation (10.46) from measurements of the second moment. As in the case of the cell experiment, the results can also be Interpreted in terms of an "effective diffusion coefficient" associated with a Fick equation for the... [Pg.107]

In the earlier versions of the streamline upwinding scheme the modified weight function was only applied to the convection tenns (i.e. first-order derivatives in the hyperbolic equations) while all other terms were weighted in the usual manner. This is called selective or inconsistent upwinding. Selective upwinding can be interpreted as the introduction of an artificial diffusion in addition to the physical diffusion to the weighted residual statement of the differential equation. This improves the stability of the scheme but the accuracy of the solution declines. [Pg.54]

To increase the number of theoretical plates without increasing the length of the column, it is necessary to decrease one or more of the terms in equation 12.27 or equation 12.28. The easiest way to accomplish this is by adjusting the velocity of the mobile phase. At a low mobile-phase velocity, column efficiency is limited by longitudinal diffusion, whereas at higher velocities efficiency is limited by the two mass transfer terms. As shown in Figure 12.15 (which is interpreted in terms of equation 12.28), the optimum mobile-phase velocity corresponds to a minimum in a plot of H as a function of u. [Pg.562]

These effects of differential vapor pressures on isotope ratios are important for gases and liquids at near-ambient temperatures. As temperature rises, the differences for volatile materials become less and less. However, diffusion processes are also important, and these increase in importance as temperature rises, particularly in rocks and similar natural materials. Minerals can exchange oxygen with the atmosphere, or rocks can affect each other by diffusion of ions from one type into another and vice versa. Such changes can be used to interpret the temperatures to which rocks have been subjected during or after their formation. [Pg.365]

A final interpretation of the regrouped expression given in item (2) is that 2D equals the diffusion velocity for a particle undergoing unit displacement, X = 1 m in the SI system. [Pg.121]

At first glance, the contents of Chap. 9 read like a catchall for unrelated topics. In it we examine the intrinsic viscosity of polymer solutions, the diffusion coefficient, the sedimentation coefficient, sedimentation equilibrium, and gel permeation chromatography. While all of these techniques can be related in one way or another to the molecular weight of the polymer, the more fundamental unifying principle which connects these topics is their common dependence on the spatial extension of the molecules. The radius of gyration is the parameter of interest in this context, and the intrinsic viscosity in particular can be interpreted to give a value for this important quantity. The experimental techniques discussed in Chap. 9 have been used extensively in the study of biopolymers. [Pg.496]

We can imagine measuring experimental curves equivalent to those in Fig. 9.11 by, say, scanning the length of the diffusion apparatus by some optical method for analysis after a known diffusion time. Such results are then interpreted by rewriting Eq. (9.85) in the form of the normal distribution function, P(z) dz. This is accomplished by defining a parameter z such that... [Pg.631]

In other work, the impact of thermal processing on linewidth variation was examined and interpreted in terms of how the resist s varying viscoelastic properties influence acid diffusion (105). The authors observed two distinct behaviors, above and below the resist film s glass transition. For example, a plot of the rate of deprotection as a function of post-exposure processing temperature show a change in slope very close to the T of the resist. Process latitude was improved and linewidth variation was naininiized when the temperature of post-exposure processing was below the film s T. [Pg.131]

The previous definitions can be interpreted in terms of ionic-species diffusivities and conductivities. The latter are easily measured and depend on temperature and composition. For example, the equivalent conductance A is commonly tabulated in chemistry handbooks as the limiting (infinite dilution) conductance and at standard concentrations, typically at 25°C. A = 1000 K/C = ) + ) = +... [Pg.599]

Numerical values for solid diffusivities D,j in adsorbents are sparse and disperse. Moreover, they may be strongly dependent on the adsorbed phase concentration of solute. Hence, locally conducted experiments and interpretation must be used to a great extent. Summaries of available data for surface diffusivities in activated carbon and other adsorbent materials and for micropore diffusivities in zeolites are given in Ruthven, Yang, Suzuki, and Karger and Ruthven (gen. refs.). [Pg.1511]

At high temperatures there is experimental evidence tlrat the Anhenius plot for some metals is curved, indicating an increased rate of diffusion over tlrat obtained by linear exU apolation of tire lower temperature data. This effect is interpreted to indicate enhanced diffusion via divacancies, rather tlrair single vacaircy-atom exchange. The diffusion coefficient must now be represented by an Anheirius equation in the form... [Pg.174]

The comparison with experiment can be made at several levels. The first, and most common, is in the comparison of derived quantities that are not directly measurable, for example, a set of average crystal coordinates or a diffusion constant. A comparison at this level is convenient in that the quantities involved describe directly the structure and dynamics of the system. However, the obtainment of these quantities, from experiment and/or simulation, may require approximation and model-dependent data analysis. For example, to obtain experimentally a set of average crystallographic coordinates, a physical model to interpret an electron density map must be imposed. To avoid these problems the comparison can be made at the level of the measured quantities themselves, such as diffraction intensities or dynamic structure factors. A comparison at this level still involves some approximation. For example, background corrections have to made in the experimental data reduction. However, fewer approximations are necessary for the structure and dynamics of the sample itself, and comparison with experiment is normally more direct. This approach requires a little more work on the part of the computer simulation team, because methods for calculating experimental intensities from simulation configurations must be developed. The comparisons made here are of experimentally measurable quantities. [Pg.238]

A dynamic transition in the internal motions of proteins is seen with increasing temperamre [22]. The basic elements of this transition are reproduced by MD simulation [23]. As the temperature is increased, a transition from harmonic to anharmonic motion is seen, evidenced by a rapid increase in the atomic mean-square displacements. Comparison of simulation with quasielastic neutron scattering experiment has led to an interpretation of the dynamics involved in terms of rigid-body motions of the side chain atoms, in a way analogous to that shown above for the X-ray diffuse scattering [24]. [Pg.248]

In an isolated two-spin system, the NOE (or, more accurately, the slope of its buildup) depends simply on where d is the distance between two protons. The difficulties in the interpretation of the NOE originate in deviations from this simple distance dependence of the NOE buildup (due to spin diffusion caused by other nearby protons, and internal dynamics) and from possible ambiguities in its assignment to a specific proton pair. Mofec-ufar modeling methods to deaf with these difficulties are discussed further below. [Pg.255]

Specification of. S SkCG, CO) requires models for the diffusive motions. Neutron scattering experiments on lipid bilayers and other disordered, condensed phase systems are often interpreted in terms of diffusive motions that give rise to an elastic line with a Q-dependent amplitude and a series of Lorentzian quasielastic lines with Q-dependent amplitudes and widths, i.e.. [Pg.479]

Graphical interpretation of the factors influencing the critical distance from air supply to the linear obstacle with a height for air supply through a slot diffuser with height Ioq and for air supply through a round nozzle with outlet diameter are presented in Fig. 7.43. Nonisothermal flow has an influence on... [Pg.483]

The inverse of the time eonstant tmicro (mieromixing) ean be interpreted as a transfer eoeffieient for mass transfer by diffusion. [Pg.50]

Fig. 7 gives an example of such a comparison between a number of different polymer simulations and an experiment. The data contain a variety of Monte Carlo simulations employing different models, molecular dynamics simulations, as well as experimental results for polyethylene. Within the error bars this universal analysis of the diffusion constant is independent of the chemical species, be they simple computer models or real chemical materials. Thus, on this level, the simplified models are the most suitable models for investigating polymer materials. (For polymers with side branches or more complicated monomers, the situation is not that clear cut.) It also shows that the so-called entanglement length or entanglement molecular mass Mg is the universal scaling variable which allows one to compare different polymeric melts in order to interpret their viscoelastic behavior. [Pg.496]


See other pages where Diffusion interpretation is mentioned: [Pg.610]    [Pg.203]    [Pg.73]    [Pg.610]    [Pg.203]    [Pg.73]    [Pg.542]    [Pg.1769]    [Pg.1933]    [Pg.366]    [Pg.51]    [Pg.102]    [Pg.108]    [Pg.186]    [Pg.144]    [Pg.260]    [Pg.507]    [Pg.228]    [Pg.291]    [Pg.476]    [Pg.477]    [Pg.480]    [Pg.115]    [Pg.247]    [Pg.29]    [Pg.51]    [Pg.218]    [Pg.526]   
See also in sourсe #XX -- [ Pg.311 ]




SEARCH



© 2024 chempedia.info