Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Detection unit

Fig. 7. Fluorescence polarization (FP). (a) The formation of the large FITC—protein A—IgG complex which leads to a net increase in plane polarized light transmitted from the solution. Molecular weights of the protein A-FITC, IgG, and complex are ca 43,000, 150,000, and 343,000, respectively, (b) Detection of IgG by fluorescence polarization immunoassay using A, a laboratory fluorimeter where (O) represents AP = change in polarization, and B, a portable detection unit where (D) is —fiV = change in voltage (27). The field detector proved to be more sensitive than the fluorimeter. Fig. 7. Fluorescence polarization (FP). (a) The formation of the large FITC—protein A—IgG complex which leads to a net increase in plane polarized light transmitted from the solution. Molecular weights of the protein A-FITC, IgG, and complex are ca 43,000, 150,000, and 343,000, respectively, (b) Detection of IgG by fluorescence polarization immunoassay using A, a laboratory fluorimeter where (O) represents AP = change in polarization, and B, a portable detection unit where (D) is —fiV = change in voltage (27). The field detector proved to be more sensitive than the fluorimeter.
A disadvantage of the first-generation device was that reaction and detection units were separated by HPLC tubing, which caused delay in analysis ]72-74],... [Pg.416]

A laser-based detection system for NO2 gas (which is an industrial hazard and common environmental pollutant) was developed by Koybayashi et al.4. This was achieved by splitting light, from an Ar-ion multi-line laser, into two paths, one passing through a measurement gas, and the other being transmitted directly to the measurement unit as a reference signal. The detection unit contained two filters to separate the two chosen laser lines, and these were then detected on separate optical receivers. One of these chosen laser lines coincided with a strong absorption line in the NO2... [Pg.460]

Identification and quantification of natural dyes need high performance analytical techniques, appropriate for the analysis of materials of complicated matrices containing a small amount of coloured substances. This requirement perfectly fits coupling of modern separation modules (usually high performance liquid chromatography in reversed phase mode, RPLC, but also capillary electrophoresis, CE) with selective detection units (mainly mass spectrometer). [Pg.365]

Ion-selective electrodes are now well understood in terms of the underlying theory, and this has made it possible for new sensing principles to emerge that make use of the thousands of chemical receptors originally developed for ion-selective electrodes. One is the field of optical sensors, which has not been discussed here because it is outside the focus of this chapter. Such so-called bulk optodes do not require electrical connectivity between the sensing and detection unit and are therefore more easily brought into various shapes and sizes, including particle formats, which suit the need of modem chemical analysis. [Pg.131]

This method was developed as a second independent method to complement the usual colorimetric procedure in the determination of a certified concentration of dissolved silica in a seawater reference material. Ion exclusion affords a separation of the dissolved silica not only from major seawater cations but also from potentially interfering anions. The detection unit limit, conservatively estimated at 2.3 ng/g Si (0.08. im), is superior to that achievable by direct analysis using inductively coupled plasma emission spectrometry. [Pg.104]

The camera/detection unit contains, in a small enclosure approved for a Class 1, Div. 1 hazardous area, the camera and computing facilities to determine whether or not the unit is "seeing" a fire. The device is programmed with... [Pg.192]

The application of HPLC in routine environments, like pharmaceutical, food, or environmental analysis and particularly quality assurance, makes not only great demands on the robnstness of HPLC hardware, comprising pumps, column thermostats, and detection units, bnt in addition to the column reproducibility. Column reproducibility can be investigated at different levels of complexity Run-to-run reproducibility compares consecutive chromatographic runs, whereas long-term stability describes the column variance over several hundreds of injections. Column-to-column (batch-to-batch) reproducibility finally explores the match of independently fabricated chromatographic columns. Column characteristics that are routinely consulted for the determination of the robustness are retention, selectivity, column efficiency, and peak symmetry. [Pg.29]

In a most versatile and flexible scheme, all processes are therefore carried out in the same experimental setup what is needed is a broadband laser sonrce, the capability to deliver the femtosecond pulses in situ in the microscope with highest possible intensity, the ability to control the phase to select the desired process, and a multichannel detection unit. In a schematic way, this is shown in Fignre 7.3. [Pg.170]

A step forward in simplification of multi-column systems involves the use of anion exchange and cation exchange columns connected in series. Such systems can be readily organized inside a standard isocratic ion chromatograph. In this approach a single eluent is used for separation of anions and cations and ideally the eluted analytes are detected with a single detection unit. In this way Takeuchi et al. [31 separated a mixture of Na+,... [Pg.1213]

As stated above, small volume of the sample and reagent are representative of most miniaturised systems. This characteristic has clear advantages associated with cost and analytical throughput, but also has disadvantages, such as the suitability of detection techniques. Consequently, much research effort has focused on developing miniaturised and sensitive detection units [6], and detection improvements are still one of the most important focuses of research. [Pg.828]

The feasibility of constructing a miniaturised system including reaction, separation and detection units integrated directly onto the EC-CE microchip device has also been shown and approximates the concept of total analysis system . Furthermore, the low cost of the EC detection in connection with new polymer material can bring a real disposable device. [Pg.860]

The activities are at present related to two major topics, namely chemical production and mass screening [3, 8, 25]. While miniaturization in the first field focuses on new process regimes due to enhanced heat and mass transfer, the second field of application results in an increase of reaction and detection units per reactor volume. Thus, miniaturization - the reduction of characteristic dimensions - directly influences the process performance in the first case, while in the last case this is only indirect by an increase in flexibility and multiplicity. [Pg.246]

Fig. 7.3 Experimental setup for the nanosecond laser Flash Photolysis with a white light continuum. A Brilland-Quantel Nd YAG laser delivers the fundamental pulses (355 and 532 nm). A pulsed XBO lamp is used as white light source. The laser signal is split in order to trigger the digital storage oscilloscope (DSO) utilizing a second photodiode (PD). Two separate detection units in different geometries—photomultiplier (PMT) in front face and a PD in side face—detect the signal in the UV/vis and NIR region, respectively. The monochromator is operated by a standard PC... Fig. 7.3 Experimental setup for the nanosecond laser Flash Photolysis with a white light continuum. A Brilland-Quantel Nd YAG laser delivers the fundamental pulses (355 and 532 nm). A pulsed XBO lamp is used as white light source. The laser signal is split in order to trigger the digital storage oscilloscope (DSO) utilizing a second photodiode (PD). Two separate detection units in different geometries—photomultiplier (PMT) in front face and a PD in side face—detect the signal in the UV/vis and NIR region, respectively. The monochromator is operated by a standard PC...
A Perkin-Elmer MPF-2A Fluorescence Spectrophotometer was used to determine the excitation and emission wavelengths required for achieving maximum fluorescence intensity for the pesticides studied. The MPF-2A contained a 150 watt xenon arc and an excitation monochromator with a grating blazed at 300 nm as the excitation unit a Hamamatsu R 777 photomultiplier tube (sensitivity range 185 - 850 nm) and an emission monochromator grating blazed at 300 nm as the emission detection unit. A DuPont Model 848 Liquid Chromatograph was used for HPLC (Figure 2). The accessory injection device included a Rheodyne Model 70-10 six-port sample injection valve fitted with a 20 y liter sample loop. A Whatman HPLC column 4.6 mm x 25 cm that contained Partisil PXS 1025 PAC (a bonded cyano-amino polar phase unspecified by the manufacturer) was used with various mobile phases at ambient temperature and a flowrate of 1.25 ml/minute. [Pg.105]

General Electric 4 watt germicidal lamp and a Corion Corporation 2537 interference filter (15% transmission at 2537). The Fluoromonitor s emission detection unit consisted of a RCA 931B (S-4 spectral response) photomultiplier tube and a Corning 7-51 glass filter that transmits light of wavelengths between 310 and 410 nm. [Pg.107]

Basically, the equipment is a standard Wicke-Kallenbach cell, except that provision is made for introducing a pulse of the trace component on one face of the porous sample, i.e. z=0. However the design does have to take into consideration the need to calibrate the detection unit for lags in the system.This does not seem to have been carried out in other work reported which used this technique. Failure to make this correction can lead to significant errors in the values of the diffusion coefficient which are extracted from the experimental data e.g. see Fig.l. [Pg.476]

Joint Service Lightweight Standoff Chemical Agent Detector (JSLSCAD). The JSLSCAD is a passive, IR detection unit employing FTIR Spectrometry. The device is designed to detect nerve and blister vapor clouds at a distance of up to 5 km. [Pg.77]

Flow cytometry is a very versatile technique [223] which allows the analysis of more than 104 cells per second [369,370]. This high number results in statistically significant data and distributions of cell properties. Therefore, flow cytometry is a key technique to segregate biomass (into distinct cell classes) and to study microbial populations and their dynamics, specifically the cell cycle [76, 87, 116, 200, 214, 221, 295, 329, 330, 409, 418]. Individual cells are aligned by means of controlled hydrodynamic flow patterns and pass the measuring cell one by one. One or more light sources, typically laser(s), are focused onto the stream of cells and a detection unit(s) measure(s) the scattered and/or fluorescent light (Fig. 24). Properties of whole cells such as size and shape can be... [Pg.38]

Karube and Yokoyama presented an overview on the developments in the biosensor technology [60]. The overview describes the use of micromachining fabrication techniques for the construction of detection units for FIA, electrochemical flow cells and chemiluminescence detectors. Acetylcholine microsensors using carbon fiber electrodes and glutamate microsensors for neuroscience were discussed. [Pg.75]

There are excellent HPLC systems available on the market today, yet there is one area of concern with this instrumentation, and this rests with the detection units. Certainly the most widely used detector system employs a low dead-volume micro-ultraviolet detector. This latter unit operates near 200 nm and detects mainly unsaturated linkages in phospholipids (or lipid) samples. Some contribution by carbonyl functions can be expected. This approach is an advantage when the sample under study contains olefinic groups, but will not detect those with saturated side (hydrocarbon) chains. An alternative detector is the refractive index monitor which is often called a universal detector, since it is based on the concept that the refractive index of the solvent changes when a solute is present. The drawback of the latter unit lies in its sensitivity, which is approximately 15- to 20-fold less than that of the ultraviolet monitor. [Pg.57]

The fluorescence detection unit is mounted towards the base of the prism, rotating together with the prism (sample) at 6, while the photo-diode detecting the reflected light rotates at 26. The fluorescence emission from the sample... [Pg.61]

X-ray detection unit with convertor into visible light and camera. [Pg.149]

Usually for the observation of dHvA oscillations in organic metals temperatures below a few K down to the mK range are necessary. Therefore, the detection unit is inserted into a He cryostat or a He/ He dilution refrigerator. Often the sample is directly immersed in the liquid and can be rotated in situ around one or even two axes. Thus, the FS can be mapped out more easily without remounting of the sample. [Pg.67]

Figure 3-6. A refrigerated scintillation spectrometer. The large bottom cabinet is a deepfreeze unit that contains the sample holders and photomultiplier detection units. The typewriter is used for data print out. (Courtesy of Packard Instrument Company, Inc.)... Figure 3-6. A refrigerated scintillation spectrometer. The large bottom cabinet is a deepfreeze unit that contains the sample holders and photomultiplier detection units. The typewriter is used for data print out. (Courtesy of Packard Instrument Company, Inc.)...

See other pages where Detection unit is mentioned: [Pg.599]    [Pg.295]    [Pg.416]    [Pg.52]    [Pg.349]    [Pg.240]    [Pg.227]    [Pg.386]    [Pg.24]    [Pg.123]    [Pg.23]    [Pg.493]    [Pg.35]    [Pg.15]    [Pg.111]    [Pg.383]    [Pg.143]    [Pg.190]    [Pg.354]    [Pg.331]    [Pg.291]    [Pg.818]    [Pg.331]    [Pg.538]   
See also in sourсe #XX -- [ Pg.298 ]




SEARCH



Photoacoustic detection unit

Radiation Units and Detection

Resonance units detection

© 2024 chempedia.info