Decor papers, additives

In the present contribution, the synthesis and characterization of partially substituted kraft lignin phenol-formaldehyde (KLPF) impregnation resins containing different additives for use in decorative paper laminate manufacturing are discussed based on dynamic DSC experiments. 

Urea-formaldehyde (UF) resins are mainly used as adhesives for wood. Laminated sheets (tables and counter tops) are a major application for melamine resins, which stay in the outer decorative surface. Molding compounds, their first big application, is still a major market, taking advantage of their extreme hardness and heat resistance. Coatings, textile finishing, paper additives, leather tanning and foundry binders, for which methanol- or butanol-etherified resins are usually employed, are important markets discussed in Ref 203. 

Urea—formaldehyde resins are also used as mol ding compounds and as wet strength additives for paper products. Melamine—formaldehyde resins find use in decorative laminates, thermoset surface coatings, and mol ding compounds such as dinnerware. 

Paper may also be colored by surface appHcation of dyestuff solutions after the paper has been formed and dried or partially dried by utilizing size-press addition, calendar staining, or coating operations on the paper machine. In addition, paper may be colored in off-machine processes by dip dyeings or absorption of dyestuff solution and subsequent drying, such as for decorative crepe papers. 

Two classes of resol are generally distinguished, water-soluble resins prepared using caustic soda as catalyst, and spirit-soluble resins which are catalysed by addition of ammonia. The water-soluble resins are usually only partially dehydrated during manufacture to give an aqueous resin solution with a solids content of about 70%. The solution viscosity can critically affect the success in a given application. Water-soluble resols are used mainly for mechanical grade paper and cloth laminates and in decorative laminates. 

Detail on printing and decoration as applied to planar surfaces such as paper and board can be found in many textbooks. However, the decoration and printing of packs, packaging materials and packaging components, many of which are non-planar surfaces, involves processes additional to the conventional ones. This chapter therefore briefly discusses these many processes, which continue to increase (comparatively recent additions include inkjet, laser and thermal printing). 

Chem. Descrip. Polyester resin without amine addition Uses Plasticizer for water-thinnable, acid-curing, oven-cured coatings, impregnations or lacquers for paper and wood decoration foils Features High reactive... 

Non-compatibilized blends of PS with either PEST or PEST and PMMA have been used for decorative applications or as the so-called plastic paper (Kamata et al. 1980). Similarly, PAr blends with either SAN (Brandstetter et al. 1983a, b, c) or high-performance blends of LCP with thermoplastic polymers (e.g., PP, PS, PC, PI) (Haghighat et al. 1992) showed adequate performance for the envisaged applications. However, most PS blends with engineering resins require compatibi-lization. Thus, for example, PS with PA-6 was compatibilized by addition of either methylmethacrylate-styrene copolymer (SMM) (Fayt et al. 1986b) or SMA (e.g., used in PARA/PS blends) (Lee and Char 1994). POM was blended with a small amount of either PS poly(a-methyl styrene) (MPS) or SAN and with particulate fillers (Tajima et al. 1991). PAr/PS blends were compatibilized with PAr-PS segmented copolymer (Unitika Ltd. 1983). 

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