Corrosive steam

If CO is not vented off from valve B, then it will begin to dissolve in the condensate to form H CO (carbonic acid). This acid causes tube failures due to acidic corrosion. Venting gas below the pass partition baffle will stop this corrosion, according to the Shell expert. I don t have any personal experience in stopping CO corrosion with such venting. But it seems to make good engineering sense to me. 

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Almost all larger FT and HP boiler plants employ some form of external capital equipment for MU water and FW treatment. The rationale for installing capital equipment is to eliminate (or at least minimize) the level of mineral impurities, process contaminants, and noncondensable gases entering the boiler via the FW system to reduce the potential for the development of waterside deposition, corrosion, steam contamination, and other waterside problems. 

Contaminants AS WELL AS feedwater. Water treatment fault. Fouling of boiler. Corrosive steam. 

A manway should be provided at the top of the kettle to provide access so that the kettle can be hosed down at the end of the reclaiming cycle. To minimize corrosion, steam spargers... 

Speidel M O, Denk J and Scarlin B 1991 Stress Corrosion Craoking and Corrosion Fatigue of Steam-Turbine Rotor and Blade Materials (Luxembourg Commission of the European Communities)... 

Benzylatnine. Warm an alcoholic suspension of 118-5 g. of finely-powdered benzyl phthalimide with 25 g. of 100 per cent, hydrazine hydrate (CAUTION corrosive liquid) a white, gelatinous precipitate is produced rapidly. Decompose the latter (when its formation appears complete) by heating with excess of hydrochloric acid on a steam bath. Collect the phthalyl hydrazide which separates by suction filtration, and wash it with a little water. Concentrate the filtrate by distillation to remove alcohol, cool, filter from the small amount of precipitated phthalyl hydrazide, render alkaline with excess of sodium hydroxide solution, and extract the liberated benzylamine with ether. Dry the ethereal solution with potassium hydroxide pellets, remove the solvent (compare Fig. //, 13, 4) on a water bath and finally distil the residue. Collect the benzylamine at 185-187° the 3ueld is 50 g. 

Recovery of Ammonia. The filter Hquor contains unreacted sodium chloride and substantially all the ammonia with which the brine was originally saturated. The ammonia may be fixed or free. Fixed ammonia (ammonium chloride [12125-02-97]) corresponds stoichiometrically to the precipitated sodium bicarbonate. Free ammonia includes salts such as ammonium hydroxide, bicarbonate, and carbonate, and the several possible carbon—ammonia compounds that decompose at moderate temperatures. A sulfide solution may be added to the filter Hquor for corrosion protection. The sulfide is distilled for eventual absorption by the brine in the absorber. As the filter Hquor enters the distiller, it is preheated by indirect contact with departing gases. The warmed Hquor enters the main coke, tile, or bubble cap-fiUed sections of the distiller where heat decomposes the free ammonium compounds and steam strips the ammonia and carbon dioxide from the solution. 

A.m blent Environment. The environment around the flow conduit must be considered in meter selection. Such factors as the ambient temperature and humidity, the pipe shock and vibration levels, the avadabiHty of electric power, and the corrosive and explosive characteristics of the environment may all influence flow meter selection. Special factors such as possible accidental flooding, the need for hosedown or steam cleaning, and the possibiHty of lightning or power transients may also need to be evaluated. 

In this pyrolysis, sub atmospheric partial pressures are achieved by employing a diluent such as steam. Because of the corrosive nature of the acids (HE and HCl) formed, the reactor design should include a platinum-lined tubular reactor made of nickel to allow atmospheric pressure reactions to be mn in the presence of a diluent. Because the pyrolysate contains numerous by-products that adversely affect polymerization, the TFE must be purified. Refinement of TFE is an extremely complex process, which contributes to the high cost of the monomer. Inhibitors are added to the purified monomer to avoid polymerization during storage terpenes such as t7-limonene and terpene B are effective (10). 

Chromium is the most effective addition to improve the resistance of steels to corrosion and oxidation at elevated temperatures, and the chromium—molybdenum steels are an important class of alloys for use in steam (qv) power plants, petroleum (qv) refineries, and chemical-process equipment. The chromium content in these steels varies from 0.5 to 10%. As a group, the low carbon chromium—molybdenum steels have similar creep—mpture strengths, regardless of the chromium content, but corrosion and oxidation resistance increase progressively with chromium content. 

Cobalt aHoys may find appHcation ia a fluidized-bed process for the direct combustion of coal (qv). CoCrAlY-coated Haynes 188 has proven to be one of the most resistant materials to a fireside corrosion process encountered ia tubes coimected the fluidized-bed combustor to a steam turbiae. 

Allowing DRI to become wet does not necessatily cause it to overheat. When large pdes of DRI are wetted with rain, the corrosion reactions are limited to the outer surface area of the pde and the resultant heat from the corrosion reactions is dissipated into the atmosphere. However, if water penetrates into the pde from the bottom, or if wet DRI is covered with dry DRI, the heat from corrosion reactions can budd up inside the pde to the point where rapid reoxidation begins. Corrosion occurs significantly faster with salt water than with fresh water. DRI saturated with water can cause steam explosions if it is batch charged into an electric arc furnace. 

Maleic Anhydride. The ACGIH threshold limit value in air for maleic anhydride is 0.25 ppm and the OSHA permissible exposure level (PEL) is also 0.25 ppm (181). Maleic anhydride is a corrosive irritant to eyes, skin, and mucous membranes. Pulmonary edema (collection of fluid in the lungs) can result from airborne exposure. Skin contact should be avoided by the use of mbber gloves. Dust respirators should be used when maleic anhydride dust is present. Maleic anhydride is combustible when exposed to heat or flame and can react vigorously on contact with oxidizers. The material reacts exothermically with water or steam. Violent decompositions of maleic anhydride can be catalyzed at high temperature by strong bases (sodium hydroxide, potassium hydroxide, calcium hydroxide, alkaU metals, and amines). Precaution should be taken during the manufacture and use of maleic anhydride to minimize the presence of basic materials. 

Steam treatment imparts increased corrosion resistance for ferrous P/M parts. The parts are heated to 400—600°C and then exposed to superheated steam. After cooling, the parts are usually oil dipped to further increase corrosion and wear resistance, and to enhance appearance (see Corrosion and CORROSION control). Heat treated parts are seldom steam treated because annealing reduces hardness and tensile strength. 

Boron, in the form of boric acid, is used in the PWR primary system water to compensate for fuel consumption and to control reactor power (3). The concentration is varied over the fuel cycle. Small amounts of the isotope lithium-7 are added in the form of lithium hydroxide to increase pH and to reduce corrosion rates of primary system materials (4). Primary-side corrosion problems are much less than those encountered on the secondary side of the steam generators. 

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