Chemiluminescence nitrogen oxides

MODELLING OF THE SIGNAL INTENSITY IN THE VARIOUS REACTION CHAMBERS OF THE N0-03 CHEMILUMINESCENCE NITROGEN OXIDES MONITOR TO OBTAIN HIGHER SENSITIVITY... 

Today, we often use the NO-O3 chemiluminescence nitrogen oxides (NO ) analyzer for determining NO concentration in the atmosphere. In the atmosphere, especially at rural sites, NO dominates the formation of O3 known as a toxic substance. " It is important that we understand atmospheric chemistry including O3 formation and the changes in atmospheric NO concentration. High sensitivity and quick response are required on the NO-O3 chemiluminescence NO analyzer for that purpose. However, commercial NO < analyzers generally have insufficient sensitivity for the measurement of NO concentration at the low levels, which are often observed in remote region such as rural sites. 

There may be many types of chemical species of interest for a given test. The most common types of analyzers associated with combustion equipment are contained in a rack or cabinet as seen in Figure 33.4. The typical analyzers found in one of these cabinets are a paramagnetic oxygen analyzer, infrared absorpfion carbon monoxide analyzer, UBH analyzer, and a chemiluminescent nitrogen oxide analyzer. Commercial sulfur dioxide analyzers based on infrared or ultraviolet absorption are also readily available to fit into one of these racks. The... 

The NO analyzer is based on the principles of chemiluminescence to determine continuously the NO concentration in the sample gas stream. The analyzer should contain a NOg-to-NO converter, which converts the nitrogen dioxide (NO9) in the sample gas to nitrogen oxide (NO). An NOg-to-NO converter is not necessary if data are presented to demonstrate that the NO9 portion of the exhaust gas is less than 5 percent of the total NO9 concentration. 

An instrument for measuring nitrogen oxides based on chemiluminescence is shown in Fig. 13.49. The ozone required for the reaction is produced in the ozone generator, which is part of rhe device. One of the reaction chamber walls is an optical filter through which a red-sensitive photomultiplier tube measures the chemiluminescence radiation intensity and converts it into a current signal. 

The device for nitrogen oxides based on chemiluminescence measures the nitrogen monoxide concentration. The same equipment can be used to measure the concentration of nitrogen dioxide. Nitrogen dioxide is reduced to nitrogen monoxide in a converter by a molybdenum catalyst. In order to... 

Chemiluminescent techniques have been used to determine nanomolar quantities of nitrate and nitrite in seawater [124,125]. This method depends on the selective reduction of these species to nitric oxide, which is then determined by its chemiluminescent reaction with ozone, using a commercial nitrogen oxides analyser. The necessary equipment is compact and sufficiently sturdy to allow shipboard use. A precision of 2nmol/l is claimed, and an analytical range of 2nmol/l with analysis rates of 10-12 samples hourly. 

The technol( for the routine measurement of the nitrogen oxides (nitrogen dioxide and nitric oxide) is fairly well advanced. The epa is on the verge of officially proposing that chemiluminescence produced by the reaction of nitric oxide with ozone be the reference method for nitrogen dioxide.This method is even more suitable for nitric oxide. Because no national air quality standard has been promulgated for nitric oxide, no reference method will be specified. However, its measurement in the atmosphere is crucial for establishing the relation of its emission to the formation of atmospheric ozone and other photochemical oxidants. 

In the chemiluminescent detection of nitrogen oxides, a constant source of ozone reacts with a metered air sample containing nitric oxide. Fontijn et al. suggested that this method could also be used for ozone detection by using a constant nitric oxide source for reaction with ozone in the air sample. The ozone-nitric oxide reaction is carried out at reduced pressure, to avoid quenching the chemiluminescent reaction. Detection of the emission in the spectral r on involved (600-3,000 nm) requires using a near-infrared-sensitive photomultiplier tube. The noise of such a photomultiplier tube is reduced by cooling it to about - 20 C. ... 

The calibration of a chemiluminescent analyzer using these standards is verified when both the nitrogen dioxide and nitric oxide channels respond similarly to charges from the (ylinder of diluted nitric oxide. Agreement with the response of the nitric oxide channel should also be obtained when the standard nitric oxide mixture is titrated with a previously established source of ozone. Chemiluminescent instruments have simplified monitoring of nitrogen oxides, but accurate calibration requires well-trained personnel. 

Automobile accidents, oxidant concentration and, 427 Automotive exhaust aerosol formation from, 60 chemiluminescence associated with. 48 diolefins in, 101 hydrocarbons in, 1,95-%, 97 nitrogen oxides in. 1... 

This reaction can be utilized for determining the nitrogen oxides content in gas mixtures. The NO concentration can be measured separately using the chemiluminescence of the NO + ozone reaction. 

Difficulties are encountered in determining NO2 using the ozone-chemiluminescence technique due to the non-specific conversion of several nitrogen oxides/oxyacids on the Mo catalyst. Use of FeS04 f°r N02-to-N0 conversion has been described, but humidity-dependent sorption/desorption effects have been reported, e.g., PAN (11). Alternatively, a commercial NO2 analyzer based on surface chemiluminescence of NO2 in the presence of a luminol solution, has been introduced which exhibits the requisite sensitively and selectivity. 

Total Nitrogen (TN) consists of the estimation of the sum of the different mineral (nitrates, nitrites, ammonium, gaseous ammonia) and organic forms of nitrogen in water. For this analysis all the various forms are mineralized by combustion into nitrogen oxides which are detected and quantified by chemiluminescence (NF EN... 

Continuous analysis instruments equipped with flame ionization, chemiluminescence, and infrared detectors were used to measure the concentrations of total hydrocarbons, nitrogen oxides and carbon monoxide, respectively. The concentration of total hydrocarbons was measured by a JUM FID 3-300 hydrocarbon analyzer with a flame ionization detector. NO, NO2 and NOx was measured by an ECO Physics CLD 700 EL-ht chemiluminescence detector. CO was measured with either a Beckman Industrial Model 880 non-dispersive infrared instrument or an NDIR instrument from Maihak (UNOR 6N). 

Fig. 3-7. Vertical distribution of nitrogen oxides and nitric acid in the stratosphere. Left Nitric oxide in the sunlit atmosphere the fields enclose data obtained with the chemiluminescence technique (Horvath and Mason, 1978 Roy et at, 1980 Ridley and Schiff, 1981 Ridley and Hastie, 1981) horizontal lines represent measurements by infrared optical techniques (Drummond and Jarnot, 1978 Roscoe etal., 1981 Loewenstein etal., 1978a,b). Center Nitrogen dioxide as observed by optical measurement techniques, day (d) and night (n) points indicate data from Murcray et al. (1974), Goldman et al. (1978), Blatherwick et at (1980) horizontal bars are from Drummond and Jarnot (1978) and Roscoe et al. (1981). The N205 profile was obtained by Toon et al. (1986) at sunrise. Right Nitric acid observed by in situ filter sampling (open points) (Lazrus and Gandrud, 1974) and by infrared spectroscopy and mass spectroscopy (solid points) (Fontanella et at, 1975 Harries et al., 1976 Evans et al., 1978 Arnold et al., 1980 Murcray et al. as quoted by Hudson, 1982 Fischer et at, 1985). The envelope gives the error range.

Joseph, D. W., and C. W. Spicer (1978). Chemiluminescence method for atmospheric monitoring of nitric acid and nitrogen oxides. Anal. Chem. 50, 1400-1403. 

Among other methods is that based on the chemiluminescent reaction of nitrogen oxide with ozone ... 

Reports on sensors for nitrogen oxides (NOj ) are scarce, although there are various observations as to the quenching of the fluorescence of polycyclic aromatic hydrocarbons by NO. This may be utilized for sensing purposes. The chemiluminescence produced in the reaction between NO and ozone is another attractive possibility that might be exploited for this purpose. 

---