Chemicals sulfite

Treatment chemicals Sulfites, hydrazine, amines, chelants Incorrect application results in thermal breakdown, sludges and corrosion deposits. 

Chemically, sulfites and bisulfites are moderate reducing agents ... 

Asthma can be induced by chemicals that are ingested or dermally applied as well as inhaled chemicals. Sulfites in wine, salads, other foods, and some medications are known to induce asthma when ingested, I41-43 ... 

The subglacial lake is sealed off from the air, so the oxygen must come from a solid or liquid source. These bacteria eat sulfate, pulling one of the four oxygens off it and producing the three-oxygen chemical sulfite. These bacteria reduce sulfate because this process takes oxygen away from it, the opposite of oxidation. Sulfate... 

Asthma can be induced by chemicals that are ingested or dermally applied as well as inhaled chemicals. Sulfites in wine, salads, other foods, and some medications are known to induce asthma when ingested [7, 45 7] and many chemicals, including isocyanates and anhydrides, have been shown to induce asthma following dermal exposure [48, 49]. The discussion in this section, however, will be limited to inhaled chemical mixtures as causative agents for asthma. 

At the anode, a chemical oxidation reaction is bound to take place. In normal fixers, sulfite (SOj ) is oxidized and acid (H ) is released as a consequence of this oxidation. Due to the decrease of the sulfite concentration and the decrease in the pH, the fixing solution becomes unstable and sulfur precipitation starts to occur when the pH of the fixer decreases below 4.0. In the case of hardening fixers, there is also an upper limit to the pH, since aluminum-hydroxides starts to precipitate when the pH exceeds 5.0. 

Residual monomers in the latex are avoided either by effectively reacting the monomers to polymer or by physical or chemical removal. The use of tert-huty peroxypivalate as a second initiator toward the end of the polymeri2ation or the use of mixed initiator systems of K2S20g and tert-huty peroxyben2oate (56) effectively increases final conversion and decreases residual monomer levels. Spray devolatili2ation of hot latex under reduced pressure has been claimed to be effective (56). Residual acrylonitrile also can be reduced by postreaction with a number of agents such as monoamines (57) and dialkylamines (58), ammonium—alkali metal sulfites (59), unsaturated fatty acids or their glycerides (60,61), their aldehydes, esters of olefinic alcohols, cyanuric acid (62,63), andmyrcene (64). 

Sulfites and related compounds have been the subject of much controversy. It has been shown that these chemicals may cause serious allergic reactions in sensitive individuals. In the United States, sulfite-containing foods must be labeled as such, and sulfites ate prohibited in areas such as salad bats where labeling is inappropriate. 

Certain chemical treatments can be employed during the TMP process to achieve improved strength. Sodium sulfite and hydrogen peroxide have been used either for chip pre- or post-treatment of the TMP pulp such pulp is called chemithermomechanical pulp (CTMP). The strength improvements, which may be 50%, are obtained at some sacrifice to yield and opacity. The yields of mechanical pulps are 90—95% the lower yields are associated with chemical treatment. No principal commercial pulps are produced in the next lower yield range, ie, 80—90%. 

Includes hydrogen, sulfur, batteries, chemicals, and spent sulfite Hquor. 

Further Modifications. There have been attempts to improve the pulp strength and decrease the energy requirement of the groundwood process by the addition of chemicals, eg, sodium carbonate or sodium sulfite. Although some benefits can be obtained, the additional costs and chemical disposal problems have not been justified. Presteaming of wood is practiced in Europe to add moisture and to soften the lignin, which is especially advantageous for certain hardwoods. 

Delignification Chemistty. The chemical mechanism of sulfite delignification is not fully understood. However, the chemistry of model compounds has been studied extensively, and attempts have been made to correlate the results with observations on the rates and conditions of delignification (61). The initial reaction is sulfonation of the aUphatic side chain, which occurs almost exclusively at the a-carbon by a nucleophilic substitution. The substitution displaces either a hydroxy or alkoxy group ... 

Chemical recovery ia sodium-based sulfite pulpiag is more complicated, and a large number of processes have been proposed. The most common process iavolves liquor iaciaeration under reduciag conditions to give a smelt, which is dissolved to produce a kraft-type green liquor. Sulfide is stripped from the liquor as H2S after the pH is lowered by CO2. The H2S is oxidized to sulfur ia a separate stream by reaction with SO2, and the sulfur is subsequendy burned to reform SO2. Alternatively, ia a pyrolysis process such as SCA-Bidemd, the H2S gas is burned direcdy to SO2. A rather novel approach is the Sonoco process, ia which alumina is added to the spent liquors which are then burned ia a kiln to form sodium aluminate. In anther method, used particulady ia neutral sulfite semichemical processes, fluidized-bed combustion is employed to give a mixture of sodium carbonate and sodium sulfate, which can be sold to kraft mills as makeup chemical. 

In lower pressure boilers a variety of additional treatments may be appropriate, particularly if the steam is used in chemical process or other nonturbine appHcation. Chelants and sludge conditioners are employed to condition scale and enable the use of less pure feedwater. When the dmm pressure is less than 7 MPa (1015 psia), sodium sulfite may be added direcdy to the boiler water as an oxygen scavenger. It has minimal effect on the oxygen concentration in the system before the boiler. 

Benzenedisulfonic acid [831-59-4] (disodium salt), produced by the neutralization of the disulfonic acid with sodium sulfite [7757-83-7] is used in the manufacture of resorcinol [108-46-3] (1,3-benzenediol) (2), a chemical component found in mbber products and wood adhesives (72). The disodium salt is fused with sodium hydroxide, dissolved in water, and acidified to produce resorcinol, which is isolated via extraction (73). 

Chemical Properties. Anhydrous sodium sulfite is stable in dry air at ambient temperatures or at 100°C, but in moist air it undergoes rapid oxidation to sodium sulfate [7757-82-6]. On heating to 600°C, sodium sulfite disproportionates to sodium sulfate and sodium sulfide [1313-82-2]. Above 900°C, the decomposition products are sodium oxide and sulfur dioxide. At 600°C, it forms sodium sulfide upon reduction with carbon (332). 

Chemical Properties. The chemistry of sodium metabisulfite is essentially that of the sulfite—bisulfite—metabisulfite—sulfurous acid system. The relative proportions of each species depend on the pH. The pH of a sodium bisulfite solution obtained by dissolving 10 wt % sodium metabisulfite in water at 20°C is 4.9 at 30 wt %, the pH is 4.4. 

Economic Aspects. U.S. production of sodium metabisulfite is estimated to be well ia excess of 45,000 t, but statistics are confused by some commingling with sodium sulfite. The principal U.S. producers are Rhc ne-Poulenc and General Chemical. The price ia mid-1995 was 0.63/kg for anhydrous sodium bisulfite. 

Sodium Sulfite Solution 25-9 in Oxygen Scavenging, Technical Information Bulletin TlR-13, Rhtjane-Poulenc Basic Chemicals Co., Shelton, Conn., 1991. R. L. Miron, Mater. Peform., 45 (June 1981). 

Gmelins Handbuch derAnorganischen Chemie, 8th ed.. System No. 9, Part B2, Vedag Chemie, Weinheim/Bergstrasse, Germany, 1960, pp. 373—613. Sodium Sulfite, product brochure. General Chemical Co., Claymont, Del., 1993. 

Sodium Sulfite, Commercial Anhydrous, data sheet, Indspec Chemical Corp., Pittsburgh, Pa., 1992. 

The manufacture of vanillin shows the progress made in the chemistry and chemical engineering of the substance. Most commercial vanillin is synthesized from guaiacol the remainder is obtained by processing waste sulfite Hquors. Preparation by oxidation of isoeugenol is of historical interest only. 

Because of the time and expense involved, biological assays are used primarily for research purposes. The first chemical method for assaying L-ascorbic acid was the titration with 2,6-dichlorophenolindophenol solution (76). This method is not appHcable in the presence of a variety of interfering substances, eg, reduced metal ions, sulfites, tannins, or colored dyes. This 2,6-dichlorophenolindophenol method and other chemical and physiochemical methods are based on the reducing character of L-ascorbic acid (77). Colorimetric reactions with metal ions as weU as other redox systems, eg, potassium hexacyanoferrate(III), methylene blue, chloramine, etc, have been used for the assay, but they are unspecific because of interferences from a large number of reducing substances contained in foods and natural products (78). These methods have been used extensively in fish research (79). A specific photometric method for the assay of vitamin C in biological samples is based on the oxidation of ascorbic acid to dehydroascorbic acid with 2,4-dinitrophenylhydrazine (80). In the microfluorometric method, ascorbic acid is oxidized to dehydroascorbic acid in the presence of charcoal. The oxidized form is reacted with o-phenylenediamine to produce a fluorescent compound that is detected with an excitation maximum of ca 350 nm and an emission maximum of ca 430 nm (81). 

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