Sulfite pulping cooking chemicals

MARATHON-HOWARD PROCESS. A treatment of waste sulfite liquor from sulfite pulp manufacture In recover chemicals and reduce steam pollution. The waste sulfite is treated with line and precipitates. (I) calcium sulfite for use in preparing fresh cooking acid for the sulfite pulp process, and 121 a basic calcium salt tif ligmn sulfonic acid (lignin sullYmalesi that can be pressed and used as a fuel of used as raw- material for vanillin, lignin plasties, and other chemicals. The remaining liquor with its BOD reduced X() ( is the effluent. 

The soda, kraft, and sulfite pulping processes are used to prepare full chemical pulps. The soda process, which uses sodium hydroxide as the cooking chemical for delignification purposes, has hugely been superseded by the kraft process, which is characterized by its use of sodium hydroxide and sodium sulfide as active delignification agenls in the chip-cooking phase of the process. 

The basis of the sulfite pulping process is the discovery by Tilghman in 1866 that white cellulose fibers are obtained by cooking wood under pressure in an aqueous solution of calcium bisulfite Ca(HS03)2. In chemical terms, the process is founded on the fact that lignin, the solid binder of wood, reacts with sulfite to form water-soluble sulfonic acids. In this fash-... 

The two main procedures are the Kraft process and the sulfite process. Kraft cooking (alkaline) is the parent chemical pulping method globally. Sulfite process (acidic) makes the lignin water-soluble. Chemical pulp fibers are more flexible than mechanical pulp fibers. Chemical pulps give paper good strength qualities. 

High-yield chemical pulps can be produced by the soda, kraft, or sulfite processes, in which chemical use and digestion time and/or temperature are suitably reduced to effect a milder cook than used for full chemical pulps. Mechanical defibrators are used to complete the separation of wood fibers not accomplished by the chemical action... 

There are several modifications of the sulfite method which are designated according to the pH of the cooking liquor (Table 7-1). For the production of chemical pulps, delignification is allowed to proceed until most of the lignin in the middle lamella is removed after which the fibers can be readily separated from each other. Semichemical pulps are often produced by the neutral sodium sulfite method followed by mechanical fiberization of the partially delignified wood. 

Sulfite Process. The sulfite process uses a cooking liquor of sulfurous acid and a salt of the acid. Although calcium was the most widely used base at one time, it has been supplanted by sodium, magnesium, and ammonia. Lignin will react with the bisulfite ion (HSO3") under acidic conditions to form lignosulfonates that are soluble in water. For many years this was the preferred process because it produced pulps of light color that could easily be bleached, it used cheap chemicals in fairly limited amounts so that no recovery was necessary, and it was a relatively simple process to operate. 

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