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Disulfonic acids

Diazo coupling involves the N exocyclic atom of the diazonium salt, which acts as an electrophilic center. The diazonium salts of thiazoles couple with a-naphthol (605). 2-nitroresorcinol (606), pyrocatechol (607-609), 2.6-dihydroxy 4-methyl-5-cyanopyridine (610). and other heteroaromatic compounds (404. 611) (Scheme 188). The rates of coupling between 2-diazothicizolium salts and 2-naphthol-3.6-disulfonic acid were measured spectrophotometrically and found to be slower than that of 2-diazopyridinium salts but faster than that of benzene diazonium salts (561 i. The bis-diazonium salt of bis(2-amino-4-methylthiazole) couples with /3-naphthol to give 333 (Scheme 189) (612). The products obtained from the diazo coupling are usuallv highly colored (234. 338. 339. 613-616). [Pg.112]

Naphthol-6,8-disulfonic acid 7.5 to 9.1 Blue to light blue 4... [Pg.948]

Indigo-5,5 -disulfonic acid (Na salt) 0.291 -0.125 <9 Colorless to blue... [Pg.950]

Chromotropic acid (1,8-dihydroxy naphthalene- 3,6-disulfonic acid)[148-25-4... [Pg.212]

A series of water-soluble fiber-reactive xanthene dyes has been prepared from the reaction of ben2oxanthenedicatboxylic acid anhydride disulfonic acid with, for example, 3-aminophenyl-P-hydtoxyethyl sulfone to yield dyes, with high brilliance and good fastness properties for dyeing of or printing on leather, wool, sHk, or ceUulosic fibers (53). [Pg.406]

Stilbene Derivatives. Most commercial brighteneis aie bistria2inyl derivatives (1) of 4,4 -diarmnostilbene-2,2 -disulfonic acid (Table 1). The usual compounds are symmetric preparation begias with reaction of 2 moles of cyanuric chloride derivatives with 1 mole of... [Pg.115]

Bis(azol-2-5l)stilbenes (2(i]ll such as (4) have been prepared. 4,4 -Dihydrazinostilbene-2,2 -disulfonic acid, obtained from the diamino compound, on treatment with 2 moles of oximinoacetophenone and subsequent ring closure, leads to the formation of (4) [23743-28 ]. Such compounds are used chiefly as washing powder additives for the brightening of cotton fabrics, and exhibit excellent light- and hypochlorite-stabiUty. [Pg.115]

A further group of whiteners was found in the acylamino (R,R ) derivatives (16) of 3,7-diaminodibenzothiophene-2,8-disulfonic acid-5,5-dioxide. The preferred acyl groups are aLkoxybenzoyls (72—74). These compounds give a greenish fluorescence and are relatively weak in comparison with stilbene derivatives on cotton however, they show good stabiUty to hypochlorite. [Pg.118]

Phthalocyanine Dyes. In addition to their use as pigments, the phthalocyanines have found widespread appHcation as dyestuffs, eg, direct and reactive dyes, water-soluble dyes with physical or chemical binding, solvent-soluble dyes with physical or chemical binding, a2o reactive dyes, a2o nonreactive dyes, sulfur dyes, and wet dyes. The first phthalocyanine dyes were used in the early 1930s to dye textiles like cotton (qv). The water-soluble forms Hke sodium salts of copper phthalocyanine disulfonic acid. Direct Blue 86 [1330-38-7] (Cl 74180), Direct Blue 87 [1330-39-8] (Cl 74200), Acid Blue 249 [36485-85-5] (Cl 74220), and their derivatives are used to dye natural and synthetic textiles (qv), paper, and leather (qv). The sodium salt of cobalt phthalocyanine, ie. Vat Blue 29 [1328-50-3] (Cl 74140) is mostly appHed to ceUulose fibers (qv). [Pg.506]

Anthraquinone can be sulfonated, nitrated, or halogenated. Sulfonation is of the greatest technical importance because the sulfonic acid group can be readily replaced by an amino or chloro group. Sulfonation with 20—25% oleum at a temperature of 130—135°C produces predominandy anthraquinone-2-sulfonic acid [84-48-0]. By the use of a stronger oleum, disulfonic acids are produced. The second sulfonic acid substituent never enters the same ring a mixture of 2,6- and 2,7-disulfonic acids is formed (Wayne-Armstrong rule). In order to sulfonate in the 1-, 1,5-, or 1,8-positions, mercury or one of its salts must be used as a catalyst. [Pg.421]

Benzenedisulfonic acid [831-59-4] (disodium salt), produced by the neutralization of the disulfonic acid with sodium sulfite [7757-83-7] is used in the manufacture of resorcinol [108-46-3] (1,3-benzenediol) (2), a chemical component found in mbber products and wood adhesives (72). The disodium salt is fused with sodium hydroxide, dissolved in water, and acidified to produce resorcinol, which is isolated via extraction (73). [Pg.100]

Changes in the backbone of the sulfonic acid azo dyes often produce drastic changes in properties of the materials. The disulfonic acid (5) is somewhat similar to (3), but is used to color leather red (77). More esoteric dyes have also been developed based on sulfonic acid metal complexes and chitosan-derived materials (78,79). [Pg.100]

Technologically, the most important examples of such couplers are 1-naphthylamine, 1-naphthol, and sulfonic acid derivatives of 1-naphthol (Fig. 2). Of great importance in the dyestuff industry are derivatives of l-naphthol-3-sulfonic acid, such as H-acid (8-amino-l-naphthol-3,6-disulfonic acid [90-20-0])... [Pg.428]

The Chemicaly3.bstractIndexis 2,7-naphthalene-disulfonic acid, 4-amino-5-hydroxy-3-[[4 -[(4-hydroxyphenyl)azo] [l,l -biphenyl]-4-yl]azo]-6-(phenylazo)-, disodium salt. [Pg.430]

Fastusol Yellow 66 [91-34-9] (25) (Cl Direct YeUow 4 Cl 24890) is a symmetrical primary disazo dye from a tetrazo component (4,4 diamino-2,2 stilbene-disulfonic acid [81-11-8],... [Pg.431]

Sulfonation. Benzene is converted iato benzenesulfonic acid [98-11-3] C H SO, upon reaction with fuming sulfuric acid (oleum) or chlorosulfonic acid. y -Benzenedisulfonic acid [98-48-6] CgHgS20, is prepared by reaction of benzene-sulfonic acid with oleum for 8 h at 85°C. Often under these conditions, appreciable quantities ofT -benzenedisulfonic acid [31375-02-7] are produced. 1,3,5-Benzenetrisulfonic acid [617-99-2] C H S Og, is produced by heating the disulfonic acid with oleum at 230°C (21). [Pg.40]


See other pages where Disulfonic acids is mentioned: [Pg.848]    [Pg.918]    [Pg.45]    [Pg.45]    [Pg.56]    [Pg.59]    [Pg.97]    [Pg.257]    [Pg.294]    [Pg.328]    [Pg.329]    [Pg.459]    [Pg.500]    [Pg.539]    [Pg.657]    [Pg.657]    [Pg.401]    [Pg.115]    [Pg.316]    [Pg.491]    [Pg.495]    [Pg.500]    [Pg.502]    [Pg.502]    [Pg.502]    [Pg.502]    [Pg.294]    [Pg.421]    [Pg.80]    [Pg.102]    [Pg.214]    [Pg.427]    [Pg.429]   
See also in sourсe #XX -- [ Pg.210 , Pg.288 ]




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