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Physical-chemical characterizations

Chemical - Physical Characterization Data and Catalytic Cracking Properties for DUSY... [Pg.227]

E. Carone, L. D llario, A. Martinelli, New conductive thermoplastic elastomers. Part n. Physical and chemical-physical characterization, Journal of Applied Polymer Science 2002, 86, 1259. [Pg.146]

All programs agree on the need for basic chemical/physical characterization data, estimates of use, and volume distribution. In early tiers. [Pg.237]

This group of aluminum carboxylates is characterized mainly by its abiUty to gel vegetable oils and hydrocarbons. Again, monocarboxylate, dicarboxylate, and tricarboxylate salts are important. The chemical, physical, and biological properties of the various types of aluminum stearates have been reviewed (29). Other products include aluminum palmitate and aluminum 2-ethylhexanoate (30). [Pg.143]

The unique chemical, physical, and spectroscopic properties of organosiUcon compounds are reflected in the analytical methodology used for the detection, quantification, and characterization of these compounds. Several thorough, up-to-date reviews dealing with analytical methods appHed to siUcones have beenpubhshed (434—436). [Pg.59]

The term pseudosubstrate as used in this article will comprise sugar-related compounds that are chemically transformed by glycosidases, often forming long-lived intermediates and thereby acting as reversible inhibitors. Even in cases of weak inhibition, where the intermediate is too short-lived for chemical or physical characterization, the type of reaction catalyzed by the... [Pg.348]

A large number of considerations and factors must be entertained for the conception, development, preparation, assessment, characterization, and certification of RMs, including (a) end use requirements, (b) selection of materials, (c) preparation, (d) physical characterization, (e) chemical characterization, (f) certification, (g) documentation, and (h) distribution. Most of these have an overwhelming impact on the finally developed RM and on its credibility. This section deals with the steps, collectively denoted as collection and preparation, occurring early in the scheme of RM development. It treats general collection and preparation principles, and provides specific examples of preparative procedures. [Pg.20]

Interim collection of processed material Interim physical characterization Interim chemical characterization Stability testing Packaging I... [Pg.23]

Final physical characterization Chemical characterization (homogeneity)... [Pg.23]

Characterization of the finally-produced material includes final physical characterization along the lines described under interim physical characterization and chemical characterization (homogeneity). The latter includes selection, development, assessment, and validation of methodologies for homogeneity testing includ-... [Pg.25]

Identifying volumes or areas of media to which general response actions might be applied, taking into account the requirements for protectiveness as identified in the remedial action objectives and the chemical and physical characterization of the site... [Pg.604]

A review16 with 89 references is given on the excited state properties of the low valent (0 and + 1) bi- and trinuclear complexes of Pd and Pt. Physical characterization of the nature of the lowest energy excited states along with their photoinduced chemical reactivities toward oxidative additions is discussed. [Pg.557]

The release of non-Brownian particles (diameter s 5 pm) from surfaces has been studied. The influence of several variables such as flow rate, particle size and material, surface roughness, electrolyte composition, and particle surface charge has been considered. Experiments have been performed in a physically and chemically well-characterized system in which it has been observed that for certain particle sizes there exists a critical flow rate at which the particles are released from surfaces. This critical flow rate has been found to be a function of the particle size and composition. In addition, it has been determined that the solution pH and ionic strength has an effect on the release velocity. [Pg.547]

Migowski, P., Machado, G., Texeira, S.R., Alves, M.C.M., Morais, J., Traverse, A. and Dupont, J. (2007) Synthesis and characterization of nickel nanopartides dispersed in imidazolium ionic liquids. Physical Chemistry Chemical Physics,... [Pg.83]

We have emphasized here that the dynamic aspects of NMR studies are crucially important for structurally or dynamically heterogeneous systems such as synthetic or natural hydrogels, protein fibrils and membrane proteins. This is in order to characterize their unique chemical, physical and biological properties in terms of a variety of fluctuation frequencies, including high (> 108 Hz) or intermediate (104-105 Hz) frequency fluctuations. It turns out that the presence of the high-frequency motions, which are readily evaluated by comparative CPMAS and DDMAS studies, is... [Pg.79]

The quantitation of products that form in low yields requires special care with HPLC analyses. In cases where the product yield is <1%, it is generally not feasible to obtain sufficient material for a detailed physical characterization of the product. Therefore, the product identification is restricted to a comparison of the UV-vis spectrum and HPLC retention time with those for an authentic standard. However, if a minor reaction product forms with a UV spectrum and HPLC chromatographic properties similar to those for the putative substitution or elimination reaction, this may lead to errors in structural assignments. Our practice is to treat rate constant ratios determined from very low product yields as limits, until additional evidence can be obtained that our experimental value for this ratio provides a chemically reasonable description of the partitioning of the carbocation intermediate. For example, verification of the structure of an alkene that is proposed to form in low yields by deprotonation of the carbocation by solvent can be obtained from a detailed analysis of the increase in the yield of this product due to general base catalysis of carbocation deprotonation.14,16... [Pg.74]

As the analytical, synthetic, and physical characterization techniques of the chemical sciences have advanced, the scale of material control moves to smaller sizes. Nanoscience is the examination of objects—particles, liquid droplets, crystals, fibers—with sizes that are larger than molecules but smaller than structures commonly prepared by photolithographic microfabrication. The definition of nanomaterials is neither sharp nor easy, nor need it be. Single molecules can be considered components of nanosystems (and are considered as such in fields such as molecular electronics and molecular motors). So can objects that have dimensions of >100 nm, even though such objects can be fabricated—albeit with substantial technical difficulty—by photolithography. We will define (somewhat arbitrarily) nanoscience as the study of the preparation, characterization, and use of substances having dimensions in the range of 1 to 100 nm. Many types of chemical systems, such as self-assembled monolayers (with only one dimension small) or carbon nanotubes (buckytubes) (with two dimensions small), are considered nanosystems. [Pg.136]

In all of these applications, the emphasis to date has been on the use of lasers to study chemically and physically well characterized systems, that is, simple molecules in the gas phase, or in ordered phases such as molecular crystals, or in cryogenic matrices. There are exceptions to this statement, but the basic fact is that the great strides in chemical applications of lasers have been made by the chemical physics and analytical chemistry communities and largely ignored by inorganic, organic, and biological chemists. [Pg.455]

Microbial transformations and generally not chemical transformations characterize the sewer environment in terms of quality transformations of the wastewater. On the other hand, the physicochemical characteristics, e.g., diffusion in the biofilm and exchange of substances across the water-air interface, play an important role and must be integrated with the microbial transformations. The hydraulics and the sewer solids transport processes have a pronounced impact on the sewer performance. These physical processes, however, are typically dealt with in hydraulics and are, therefore, only included in the text when directly and closely related to the chemical and biological processes. [Pg.9]

Physical characterization of polymers is a common activity that research and development technologists at the Dow Chemical Company perform. A material property evaluation that is critical for most polymer systems is a tensile test. Many instruments such as an Instron test frame can perform a tensile test and, by using specialized software, can acquire and process data. Use of an extensometer eliminates calibration errors and allows the console to display strain and deformation in engineering units. Some common results from a tensile test are modulus, percent elongation, stress at break, and strain at yield. These data are then used to better understand the capabilities of the polymer system and in what end-use applications it may be used. [Pg.453]

Further investigations of chemical kinetics and transformation products will be carried out during the final phase of the project. In order to truly understand sonochemical effects, the behavior of the individual bubbles and the bubble clouds must be more finely resolved. Physical characterization of cavitation bubble clouds will also be performed. Thus, a more fundamental link will be established between bulk, observable parameters and sonochemistry, via the physics and hydrodynamics of the cavitating cloud. [Pg.9]

Although Van Hise attributed the gross deformation of rocks to physical causes, he believed that their alteration was a chemical, or physico-chemical, problem. Thus, he maintained that a different set of chemical reactions characterized the alteration of rocks in each zone. In the zone of fracture, reactions typically occurred with the expansion of volume and the liberation of heat oxidation, carbonation, and hydration. In the lower zone, these reactions were reversed as pressure rather than temperature became the factor controlling chemical change. [Pg.25]

While producing samples more efficiently is one aspect which can lead to more efficient materials discovery efforts, efficient characterization is also needed. In his 1970 paper, [1] Hanak spoke to the issue of materials testing and evaluation. He discussed advances in the measurement of a number of chemical, physical and mechanical properties, measurements which must be tailored to the specific materials problem under investigation. Ultimately it was difficulties in characterization that limited the impact of these approaches. Computers were not yet commonly available, and automated sample evaluation methods remained to be developed. [Pg.153]

A drug substance must be chemically and physically characterized prior to incorporation into a new dosage form. Preformulation work provides the type of information needed to define the nature of the drug substance, as thoroughly as possible, and this then provides the framework for the drug s combination with pharmaceutic ingredients in the fabrication of a dosage form. [Pg.382]


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