Century scale

One has to look at the time averages. In the assessment we were most interested in, decadal to century scale trends, not annual averages [Note As mentioned above, I used decadal (10-year) moving averages ], so [we] would not be inclined to perform the test you did. Nevertheless we ran the test you did, but changed the averaging period. ... 

Socolow, R. 2003. The Century-Scale Problem of Carbon Management. The Carbon Dioxide Dilemma Promising Technologies and Policies. Proceedings of a Symposium, April 23-24, 2002, pp. 11—14. Washington, D.C. The National Academies Press. 

Sarmiento, J., and Le Quere, C. (1996). Oceanic carbon dioxide uptake in a model of century-scale global warming. Science 274, 1346—1350. 

Mackenzie F. T., Ver L. M., and Lerman A. (2002) Century-scale nitrogen and phosphorus controls of the carbon cycle. Chem. Geol 190, 13-32. 

Villanueva, J. and Hastings, D.W. (2000) A century-scale record of the preservation of chlorophyll and its transformation products in anoxic sediments. Geochimica et Cosmochimica Acta, 64, 2281-2294. 

Holton, J. R. (1992) An Introduction to Dynamic Meterology, 3rd ed., Academic Press, San Diego. Manabe, S., and Stouffer, R. J. (1993) Century-scale effects of increased atmospheric C02 on the ocean-atmosphere system, Nature 364, 215-218. 

Yu, Z. E. Ito, 1999. Possible solar forcing of century-scale drought frequency in the northern Great Plains. Geology 27 263-266. 

Cobalt compounds have been in use for centuries, notably as pigments ( cobalt blue ) in glass and porcelain (a double silicate of cobalt and potassium) the metal itself has been produced on an industrial scale only during the twentieth century. Cobalt is relatively uncommon but widely distributed it occurs biologically in vitamin B12 (a complex of cobalt(III) in which the cobalt is bonded octahedrally to nitrogen atoms and the carbon atom of a CN group). In its ores, it is usually in combination with sulphur or arsenic, and other metals, notably copper and silver, are often present. Extraction is carried out by a process essentially similar to that used for iron, but is complicate because of the need to remove arsenic and other metals. 

Besides particles, the forces of nature play also a key role. In the past century four fundamental forces were recognized the gravitational, electromagnetic, weak, and strong forces. Of these the weak and strong forces are less familiar, because they are nuclear forces and their strength rapidly diminishes over all but subatomic scales. 

Acetylene was discovered m 1836 by Edmund Davy and characterized by the French chemist P E M Berthelot m 1862 It did not command much attention until its large scale preparation from calcium carbide m the last decade of the nineteenth century stim ulated interest m industrial applications In the first stage of that synthesis limestone and coke a material rich m elemental carbon obtained from coal are heated m an electric furnace to form calcium carbide... 

During the late nineteenth century evidence began to accumulate that classical newtonian mechanics, which was completely successful on a macroscopic scale, was unsuccessful when applied fo problems on an atomic scale. 

It was not until the twentieth century that furfural became important commercially. The Quaker Oats Company, in the process of looking for new and better uses for oat hulls found that acid hydrolysis resulted in the formation of furfural, and was able to develop an economical process for isolation and purification. In 1922 Quaker announced the availability of several tons per month. The first large-scale appHcation was as a solvent for the purification of wood rosin. Since then, a number of furfural plants have been built world-wide for the production of furfural and downstream products. Some plants produce as Httie as a few metric tons per year, the larger ones manufacture in excess of 20,000 metric tons. 

Early in the twentieth century, the first attempts to manufacture formamide directiy from ammonia and carbon monoxide under high temperature and pressure encountered difficult technical problems and low yields (23). Only the introduction of alkaU alkoxides in alcohoHc solution, ie, the presence of alcoholate as a catalyst, led to the development of satisfactory large-scale formamide processes (24). 

The conversion of coal to gas on an industrial scale dates to the early nineteenth century (14). The gas, often referred to as manufactured gas, was produced in coke ovens or similar types of retorts by simply heating coal to vaporize the volatile constituents. Estimates based on modem data indicate that the gas mixture probably contained hydrogen (qv) (ca 50%), methane (ca 30%), carbon monoxide (qv) and carbon dioxide (qv) (ca 15%), and some inert material, such as nitrogen (qv), from which a heating value of approximately 20.5 MJ/m (550 Btu/fT) can be estimated (6). 

Coal gasification technology dates to the early nineteenth century but has been largely replaced by natural gas and oil. A more hydrogen-rich synthesis gas is produced at a lower capital investment. Steam reforming of natural gas is appHed widely on an iadustrial scale (9,10) and ia particular for the production of hydrogen (qv). 

Large-scale recovery of light oil was commercialized in England, Germany, and the United States toward the end of the nineteenth century (151). Industrial coal-tar production dates from the earliest operation of coal-gas faciUties. The principal bulk commodities derived from coal tar are wood-preserving oils, road tars, industrial pitches, and coke. Naphthalene is obtained from tar oils by crystallization, tar acids are derived by extraction of tar oils with caustic, and tar bases by extraction with sulfuric acid. Coal tars generally contain less than 1% benzene and toluene, and may contain up to 1% xylene. The total U.S. production of BTX from coke-oven operations is insignificant compared to petroleum product consumptions. 

Reciprocating Compressors. Prior to 1895, when Linde developed his air Hquefaction apparatus, none of the chemical processes used industrially required pressures much in excess of I MPa (145 psi) and the need for a continuous supply of air at 20 MPa provided the impetus for the development of reciprocating compressors. The introduction of ammonia, methanol, and urea processes in the early part of the twentieth century, and the need to take advantage of the economy of scale in ammonia plants, led to a threefold increase in the power required for compression from 1920 to 1940. The development of reciprocating compressors was not easy Htfle was known about the effects of cycles of fluctuating pressure on the behavior of the... 

Although a few simple hydrides were known before the twentieth century, the field of hydride chemistry did not become active until around the time of World War II. Commerce in hydrides began in 1937 when Metal Hydrides Inc. used calcium hydride [7789-78-8J, CaH2, to produce transition-metal powders. After World War II, lithium aluminum hydride [16853-85-3] LiAlH, and sodium borohydride [16940-66-2] NaBH, gained rapid acceptance in organic synthesis. Commercial appHcations of hydrides have continued to grow, such that hydrides have become important industrial chemicals manufactured and used on a large scale. 

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