Carpeting, polypropylene

Fluidized bed temperature 700°C. CPE cross-linked polyethylene CPP carpet polypropylene waste, MPW mixed plastic waste... 

Table 16.12 Compressive Stress (kPa) at 10% Axial Strain for Soil with Carpet, Polypropylene, and Apparel Fibers [87, 88]...

Polypropylene has the repeating unit -CH2-CH(CH3)-. Polypropylene is similar to high-density polyethylene, but is slightly harder and tougher. In addition to filament applications such as home furnishings, non-woven products and carpets, polypropylene is also used in pipes and films. 

Physical Properties. Table 1 (2) shows that olefin fibers differ from other synthetic fibers in two important respects (/) olefin fibers have very low moisture absorption and thus excellent stain resistance and almost equal wet and dry properties, and (2) the low density of olefin fibers allows a much lighter weight product at a specified size or coverage. Thus one kilogram of polypropylene fiber can produce a fabric, carpet, etc, with much more fiber per unit area than a kilogram of most other fibers. 

Polypropylene fibers are used in every aspect of carpet constmetion from face fiber to primary and secondary backings. Polypropylene s advantages over jute as carpet backing are dimensional stabiUty and minimal moisture absorption. Drawbacks include difficulty in dyeing and higher cost. Bulked-continuous-filament (BCF) carpet yams provide face fiber with improved crimp and elasticity. BCF carpet yams are especially important in contract carpets, characterized by low dense loops, where easy cleaning is an advantage. 

Such repositioning inevitably means reduced production volume, and for the first time this century production in the last decade has been below that a decade earUer (Eig. 9). Most capacity reductions have been in North America and especiaUy eastern Europe. This has been offset in part by capacity increases in the Ear East. Rayon is no longer a significant component of carpets, and has lost the disposable diaper coverstock business to cheaper and more easUy processed polypropylene. It has, however, gained share in health and hygiene products and is now a principal component of tampons worldwide. 

In the United States, fibers and injection mol ding are the main appHcations for polypropylene (Table 8), followed by film. In Europe and Japan, injection mol ding appHcations predominate (Table 10). This market area is more likely to decline in economic recession, as consumers postpone purchases of apphances and automobiles. Film appHcations are important in both regions, but fibers are a much less important use for polypropylene in Japan than in other developed regions. The heavy use of polypropylene nonwovens in the manufacture of disposable diapers and similar products, and the wide use of polypropylene carpets in the United States, account for the greater consumption of fibers. 

Fibers. Polypropylene fibers are extensively used in carpeting. Bulked continuous filament yams are commonly used in carpet facing in the level loop carpets used in commercial buildings however, nylon remains the dominant face yam in tufted household carpets. The advantages of polypropylene carpeting are superior stain resistance and low moisture absorbance. Polypropylene sHt tape fibers are heavily used in carpet backing. 

Another use of 4-/ f2 octylphenol is ia the productioa of uv stabilizers. 4-/ f2 -Octylpheaol reacts with sulfur dichloride to yield the thio-hisphenol derivative, which thea reacts with nickel acetate to form 2,2 -thiobis(4-/ f2 octylphenolate)-A/-butylamiQe nickel [14516-71 -3]. This type of stabilizer is widely used in the production of outdoor carpeting based on polypropylene fibers. Nickel compounds give a green discoloration which limits their apphcatioas. A second class of uv stabilizers based on the benzotriazole stmcture. 2-(2 -hydroxy-5 -/ f2 octylphenyl)benzotriazole [3147-75-9] is produced from 4-/ i -octylphenol (55). 

Polypropylene is used in battery cases and in the replacement of metal parts in automobiles. It is also widely used in consumer products, eg, kitchen wares, trays, toys, and packaging materials. Its future appHcations are expected to include an increased portion of the fibers and filaments markets, especially for continued growth in carpet backing and carpet face yams. Film, both oriented and unoriented, is also expected to be a significant growth market for polypropylene. 

Practical methods for synthesis and elucidation of the optimum physical forms were developed at Du Pont (13). The violets fill the void in the color gamut when the inorganics are inadequate. The quinacridones may be used in most resins except polymers such as nylon-6,6, polystyrene, and ABS. They are stable up to 275°C and show excellent weatherabiUty. One use is to shade phthalocyanines to match Indanthrone Blue. In carpeting, the quinacridones are recommended for polypropylene, acrylonitrile, polyester, and nylon-6 filaments. Predispersions in plastici2ers ate used in thermoset polyesters, urethanes, and epoxy resins (14). 

Amongst hydrocarbon polymers polypropylene has been uniquely successful as a fibre. Its comparatively low cost and excellent wear together with resistance to staining have led to a major use in carpets as the tufting material. It has also found some use for blankets. As softer grades of fibre become available and... 

Binder formulas for carpet backing, aluminum foil to paper, vinyl flooring, tire cord, paper labeling, masking tape, and oriented polypropylene tape applications are available from Midgley and Rea in Skiest [215]. 

Polypropylene fibers for use in carpets and automobile tires consumer items (luggage, appliances, etc.) packaging material. 

Polypropylene fibers are used for face pile of needle felt, tufted carpets, upholstery fabrics, etc. 

Ny lon-6 (108 g) carpet backed with calcium-carbonate-filled latex and polypropylene was charged to a 1000-mL three-neck round-bottom flask (equipped with a condenser) with 6 mL of 85% phosphoric acid. Superheated steam was injected continuously during a 45-min period. The vapor temperature of the reaction medium was 250-300°C. The volume of distillate collected was 1065 mL. The distillate contained 1.9% e-caprolactam (as determined by GC), which corresponded to a crude yield of 37.5%. The distillate was fractionated in a distillation column and the nonaqueous phase removed. The remaining aqueous phase was treated with 2% potassium permanganate at 40-50°C for 2 h. Evaporation of... 

Polypropylene was not developed until the 1950s when Ziegler and Natta invented coordination catalysts. The structural difference between polyethylene and polypropylene is the methyl group in the propylene unit. Its presence makes a difference because it makes possible three different polymer structures Isotactic, with all methyl groups in the same plane makes the best plastic syndiotactic, in which the methyl groups alternate in the same plane and atactic, with the methyl groups randomly in and out of the plane is soft and rubbery. Polypropylene is used as film and in many structural forms. It is also used as fibers for carpet manufacture and for thermal clothing. 

Polypropylene fibers are mainly used in outdoor carpets and in cold-weather clothing. 

Uses Used in the petroleum industry to make so-called alkylate for improved octane gasoline. Large quantities are polymerized to polypropylene for carpeting, upholstery, ropes, and other uses. Used in the chemical industry as a starting material for many large-volume chemicals such as acetone, acrylonitrile, and propylene oxide. 

The main use of propylene is for polymerization to polypropylene, a process similar to the manufacture of high-density polyethylene (i.e., a low-pressure, catalytic process). Textile hhers made from polypropylene are relatively low-cost and have particularly good properties, such as high resistance to abrasion and soiling for use in furniture upholstery and indoor/outdoor carpeting. 

Most automobile and furniture seating, foam mattresses, carpet underlay-ment, and other similar products are made from polyurethanes based on polypropylene glycol (PPG). PPG is the preferred raw material for these type of polymers because of the wide variation of possible properties of the end product and the relatively low cost. 

In an industrial application dissolution/reprecipitation technology is used to separate and recover nylon from carpet waste [636]. Carpets are generally composed of three primary polymer components, namely polypropylene (backing), SBR latex (binding) and nylon (face fibres), and calcium carbonate filler. The process involves selective dissolution of nylon (typically constituting more than 50wt% of carpet polymer mass) with an 88 wt % liquid formic acid solution and recovery of nylon powder with scCC>2 antisolvent precipitation at high pressure. Papaspyrides and Kartalis [637] used dimethylsulfoxide as a solvent for PA6 and formic acid for PA6.6, and methylethylketone as the nonsolvent for both polymers. 

This stretching, similar to the drawing of fibres, which promotes orientation and crystallite formation, is called biaxial orientation. It gives the film added strength and gas-barrier properties. In some processes, monoaxial (uniaxial) drawing is employed, e.g., polypropylene, which is then slit into thin strips and fabricated into heavy duty sacks, carpet backing, etc. The stenter process is used to make biaxial oriented poly(vinylidene dichloride) ("ding" film), polyester, polyamide and polypropylene films. 

Similar to phenols, they can cause staining and are often used in conjunction with carbon black filled elastomers (e.g., tyres) — although carbon black itself has antioxidant capacity. For non-staining applications, e.g., polypropylene carpets, a stoically hindered amine is used, e.g.,... 

Vinyl polymers [polystyrene, PVC, polyethylene, polypropylene, poly(vinyl acetate), poly(vinyl alcohol), polyacrylonitrile] -1920 Packaging, tubing, household goods, records, carpets, toys, water based paint, adhesives, varnishes Phthalate esters, poly(vinyl alcohol) ... 

Carpet backing, spunbonded polypropylene in, 17 483—484 Carpet principle, 18 255 Carpets... 

P.R.176 provides very lightfast polyacrylonitrile spin dyeing products. The samples equal step 6-7 on the Blue Scale. Dry and wet crocking may affect the objects to a certain extent. P.R.176 is also used in polypropylene spin dyeing, especially for coarse textiles, such as carpet fibers, split fibers, filaments, bristles, or tape, but also for finer denier yams. A special pigment preparation for this purpose is commercially available. 1/3 SD samples tolerate exposure to up to 300°C for one minute or up to 290°C for 5 minutes. In terms of lightfastness, 0.1% colorations equal step 5-6 on the Blue Scale, while 2% samples match step 7. 

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