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Capturing the Essence of Time

A mathematical formulation based on uneven discretization of the time horizon for the reduction of freshwater utilization and wastewater production in batch processes has been developed. The formulation, which is founded on the exploitation of water reuse and recycle opportunities within one or more processes with a common single contaminant, is applicable to both multipurpose and multiproduct batch facilities. The main advantages of the formulation are its ability to capture the essence of time with relative exactness, adaptability to various performance indices (objective functions) and its structure that renders it solvable within a reasonable CPU time. Capturing the essence of time sets this formulation apart from most published methods in the field of batch process integration. The latter are based on the assumption that scheduling of the entire process is known a priori, thereby specifying the start and/or end times for the operations of interest. This assumption is not necessary in the model presented in this chapter, since water reuse/recycle opportunities can be explored within a broader scheduling framework. In this instance, only duration rather start/end time is necessary. Moreover, the removal of this assumption allows problem analysis to be performed over an unlimited time horizon. The specification of start and end times invariably sets limitations on the time horizon over which water reuse/recycle opportunities can be explored. In the four scenarios explored in... [Pg.97]

The constraints presented above complete the constraints necessary for the mass balances. Due to the discontinuous nature of the operation under consideration, constraints also have to be derived that capture the essence of time. These are presented in the scheduling module below. [Pg.161]

Like so many other reactions, the ene reaction has been given new life by metal catalysis. The use of metals ranges from common Lewis acids, which simply lower the barrier of activation of the hetero-ene reactions to transition metal catalysts which are directly involved in the bond-breaking and -forming events, rendering reactions formal ene processes. This review is meant to serve as a guide to the vast amount of data that have accumulated in this area over the past decade (1994-2004). If a particular subject has been reviewed recently, the citation is provided and only work done since the time of that review is included here. Finally, the examples included within are meant to capture the essence of the field, the scope, limitations, and synthetic utility therefore, this review is not exhaustive. [Pg.557]

At the time of this writing, it must be conceded that there have been no fundamental principles-based mathematical model for Nafion that has predicted significantly new phenomena or caused property improvements in a significant way. Models that capture the essence of percolation behavior ignore chemical identity. The more ab initio methods that do embrace chemical structure are limited by the number of molecular fragments that the computer can accommodate. Other models are semiempirical in nature, which limits their predictive flexibility. Nonetheless, the diversity of these interesting approaches offers structural perspectives that can serve as guides toward further experimental inquiry. [Pg.342]

Using the Hamiltonian, we can obtain attractive or repulsive forces that play a role of external forces in Equation (22). A spin analogy/ lattice gas model will be developed that can describe the oversimplified molecular structure, while still capturing the essence of the molecule/ surface interaction. The relaxation time in SRS-LBM will contain shear rate and other nanoscopic information. [Pg.92]

The parameters , A, and in (22a) can be determined from the equilibrium structure factor Sq at or close to the transition and, together with to and the shear rate y, they capture the essence of the rheological anomalies in dense dispersions. A divergent viscosity follows from the prediction of a strongly increasing final relaxation time in Q in the quiescent fluid phase [2, 38] ... [Pg.91]

This is where we stand as we enter the next phase of organic standards. We are completing our debate on the choice of words and it is time for fanners to state how well we have captured the essence of their best efforts for replication across the land. Every farm presents a different picture, although our standards are a common marketing language and seek to protect consumers. If these standards fulfil their promise, they will be flexible enough to accommodate individual iterations and evolutions in knowledge. [Pg.283]

This simple, analytically-solvable example captures the essence of the resonance phenomenon incident particle energies that match, or nearly match, bound-state energy levels of a particular potential can become trapped, even if such states are asymptotically unstable. In a time-dependent picture, an incident particle whose kinetic energy matches a bound-state energy level can be captured for some finite period of time, before ultimately tuimeHng out of this potential. Importantly, the incoming particle s wave function must be precisely matched to the wave function inside the potential well (or double-barrier, in this example), as shown in Figure 13. [Pg.418]

Enfieurage. This is an ancient process for capturing aromafic essential oils from flowers, such as jasmine and tuberose. In this now essentially obsolete process, freshly gathered flower petals are carefully spread on a sheet, usually glass, upon which is spread a very thin film of highly purified fat. The petals remain in contact with the fat film for 24 hours, after which the peials are removed and replaced with a fresh batch. The process requires from 30 to 40 repetitions before the fat becomes saturated with the essential oil. The fat at this point is called pomade, which is extracted with pure alcohol. Prior to the availability of more advanced technology, some essence manufacturers would have as many as a thousand petal frames in operation at one time. [Pg.646]


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