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Benzene, toluene, and xylenes

BTX A mixture of low boiling point aromatics, i.e. benzene, toluene and xylenes. [Pg.69]

Benzene, toluene and xylenes are used either as solvents or as basic intermediates for the chemical and petrochemical industries. [Pg.273]

Benzene, toluene, and xylene are made mosdy from catalytic reforming of naphthas with units similar to those already discussed. As a gross mixture, these aromatics are the backbone of gasoline blending for high octane numbers. However, there are many chemicals derived from these same aromatics thus many aromatic petrochemicals have their beginning by selective extraction from naphtha or gas—oil reformate. Benzene and cyclohexane are responsible for products such as nylon and polyester fibers, polystyrene, epoxy resins (qv), phenolic resins (qv), and polyurethanes (see Fibers Styrene plastics Urethane POLYiffiRs). [Pg.216]

Aromatic Hydrocarbons. Sulfolane is used principally as a solvent for extraction of benzene, toluene, and xylene from mixtures containing aHphatic hydrocarbons (33—37). The sulfolane process was introduced in 1959 by SheU Development Company, and that process is Hcensed by Universal OH Products. A sulfolane extraction process is also Hcensed by the Atlantic Richfield Company. In 1994, worldwide consumption was estimated at ca 6974 t/yr of sulfolane for 137 sulfolane extraction units (see Bix processes Extraction, liquid-liquid Xylenes and ethylbenzene). [Pg.69]

Toluene, Benzene, and BTX Reeoveiy. The composition of aromatics centers on the C - and Cg-fraction, depending somewhat on the boihng range of the feedstock used. Most catalytic reformate is used directiy in gasoline. That part which is converted to benzene, toluene, and xylenes for commercial sale is separated from the unreacted paraffins and cycloparaffins or naphthenes by hquid—hquid extraction or by extractive distillation. It is impossible to separate commercial purity aromatic products from reformates by distillation only because of the presence of azeotropes, although comphcated further by the closeness in boihng points of the aromatics, t/o-paraffin, and unreacted C -, C -, and Cg-paraffins. [Pg.179]

Transall lation. Two molecules of toluene are converted iato one molecule of benzene and one molecule of mixed xylene isomers ia a sequence called transalkylation or disproportionation. Economic feasibiUty of the process strongly depends on the relative prices of benzene, toluene, and xylene. Operation of a transalkylation unit is practical only when there is an excess of toluene and a strong demand for benzene. In recent years, xylene and benzene prices have generally been higher than toluene prices so transalkylation is presendy an attractive alternative to hydrodealkylation (see also Btx... [Pg.42]

Bismuth ttiiodide may be prepared by beating stoichiometric quantities of the elements in a sealed tube. It undergoes considerable decomposition at 500°C and is almost completely decomposed at 700°C. However, it may be sublimed without decomposition at 3.3 kPa (25 mm Hg). Bismuth ttiiodide is essentially insoluble in cold water and is decomposed by hot water. It is soluble in Hquid ammonia forming a red triammine complex, absolute alcohol (3.5 g/100 g), benzene, toluene, and xylene. It dissolves in hydroiodic acid solutions from which hydrogen tetraiodobismuthate(Ill) [66214-37-7] HBil 4H2O, may be crystallized, and it dissolves in potassium iodide solutions to yield the red compound, potassium tetraiodobismuthate(Ill) [39775-75-2] KBil. Compounds of the type tripotassium bismuth hexaiodide [66214-36-6] K Bil, are also known. [Pg.129]

Processes for hydrogen gasification, hydrogen pyrolysis, or coking of coal usually produce Hquid co-products. The Hygas process produces about 6% Hquids as benzene, toluene, and xylene. Substitution of petroleum residuum for the coal-derived process oil has been used in studies of coal Hquefaction and offers promise as a lower cost technology (104). [Pg.237]

Some catalysts exposed to air stripping off-gas were subject to deactivation. However, using a catalytic oxidizer at a U.S. Coast Guard faciUty (Traverse City, Mich.) for the destmction of benzene, toluene, and xylene stripped from the groundwater, the catalytic oxidization unit operated at 260 to 315°C, and was able to achieve 90% destmction efficiency (see Groundwatermonitoring). [Pg.514]

An electrostatic precipitator is used to remove more tar from coke oven gas. The tar is then sent to storage. Ammonia liquor is also separated from the tar decanter and sent to wastewater treatment after ammonia recovery. Coke oven gas is further cooled in a final cooler. Naphthalene is removed in a separator on the final cooler. Light oil is then removed from the coke oven gas and is fractionated to recover benzene, toluene, and xylene. Some facilities may include an onsite tar distillation unit. The Claus process is normally used to recover sulfur from coke oven gas. During the coke quenching, handling, and screening operation, coke breeze is produced. The breeze is either reused on site (e.g., in the sinter plant) or sold offsite as a by-product. [Pg.73]

It is desired to separate a non-volatile material from an equimolal mixture of benzene, toluene, and xylene at 80°C. Vapor pressure data for these compounds are shown in several physical property sources. The following approximate values for the specific heats and latent heats of vaporization may be used ... [Pg.61]

The sulfolane process is a versatile extractant for producing high purity BTX aromatics (benzene, toluene, and xylenes). It also extracts aromatics from kerosines to produce low-aromatic jet fuels. [Pg.53]

Increasing the octane number of a low-octane naphtha fraction is achieved by changing the molecular structure of the low octane number components. Many reactions are responsible for this change, such as the dehydrogenation of naphthenes and the dehydrocyclization of paraffins to aromatics. Catalytic reforming is considered the key process for obtaining benzene, toluene, and xylenes (BTX). These aromatics are important intermediates for the production of many chemicals. [Pg.61]

The process consists of a reactor section, continuous catalyst regeneration unit (CCR), and product recovery section. Stacked radial-flow reactors are used to minimize pressure drop and to facilitate catalyst recirculation to and from the CCR. The reactor feed consists solely of LPG plus the recycle of unconverted feed components no hydrogen is recycled. The liquid product contains about 92 wt% benzene, toluene, and xylenes (BTX) (Figure 6-7), with a balance of Cg aromatics and a low nonaromatic content. Therefore, the product could be used directly for the recovery of benzene by fractional distillation (without the extraction step needed in catalytic reforming). [Pg.178]

Chemicals Based on Benzene, Toluene, and Xylenes 269 High temperatures are needed for this reaction, and the yields are low. [Pg.269]


See other pages where Benzene, toluene, and xylenes is mentioned: [Pg.273]    [Pg.232]    [Pg.172]    [Pg.175]    [Pg.165]    [Pg.163]    [Pg.170]    [Pg.42]    [Pg.306]    [Pg.201]    [Pg.234]    [Pg.236]    [Pg.607]    [Pg.54]    [Pg.79]    [Pg.286]    [Pg.919]    [Pg.680]    [Pg.14]    [Pg.262]    [Pg.262]    [Pg.263]    [Pg.265]    [Pg.267]    [Pg.275]    [Pg.279]    [Pg.283]    [Pg.285]    [Pg.287]    [Pg.291]    [Pg.293]    [Pg.295]   
See also in sourсe #XX -- [ Pg.556 , Pg.557 ]




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Benzene, toluene, ethylbenzene, and xylene

Benzene, toluene, ethylbenzene, and xylene BTEX)

Benzene-toluene-xylenes

Dealkylation of toluene and xylenes to benzene

Determination of Benzene, Toluene and Xylenes (BTX)

Production of benzene, toluene and xylenes

Toluene and xylene

Toluene xylenes

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