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Barium isolation

It is interesting that this name, plutonium, had once before been suggested for an element. About 1817 Edward Daniel Clarke (1769— 1822), professor of mineralogy at Cambridge University, suggested that this name be used instead of barium, since barium metal was not unusually heavy. He suggested this name because barium, isolated by electrolysis, owed its existence to the dominion of fire (70). [Pg.872]

Chlorine, bromine and iodine form halic(V) acids but only iodic(V) acid, HIO3, can be isolated. Solutions of the chloric) V) and bromic) V) acids can be prepared by the addition of dilute sulphuric acid to barium chlorate(V) and bromate(V) respectively, and then filtering (cf. the preparation of hydrogen peroxide). These two acids can also be prepared by decomposing the corresponding halic(I) acids, but in this case the halide ion is also present in the solution. [Pg.339]

Strontian, town in Scotland) Isolated by Davey by electrolysis in 1808 however, Adair Crawford in 1790 recognized a new mineral (strontianite) as differing from other barium minerals. [Pg.102]

Most of the heavy-metal impurities present in 2inc salt solutions must be removed before the precipitation reaction, or these form insoluble colored sulfides that reduce the whiteness of the 2inc sulfide pigment. This end is usually achieved by the addition of 2inc metal which reduces most heavy-metal ions to their metallic form. The brightness of 2inc sulfide can be improved by the addition of a small amount of cobalt salts (ca 0.04% on a Co/Zn basis) (20). Barium sulfate [7727-43-7] formed in the first step is isolated and can be used as an extender. [Pg.10]

OC-Hydroxycarboxylic Acid Complexes. Water-soluble titanium lactate complexes can be prepared by reactions of an aqueous solution of a titanium salt, such as TiCl, titanyl sulfate, or titanyl nitrate, with calcium, strontium, or barium lactate. The insoluble metal sulfate is filtered off and the filtrate neutralized using an alkaline metal hydroxide or carbonate, ammonium hydroxide, amine, or alkanolamine (78,79). Similar solutions of titanium lactate, malate, tartrate, and citrate can be produced by hydrolyzation of titanium salts, such as TiCl, in strongly (>pH 10) alkaline water isolation of the... [Pg.145]

The only known stable soHd neutral hypochlorites are those of lithium, calcium, strontium [14674-76-17, and barium [13477-10-6]. Calcium also forms two stable basic hypochlorites (calcium hydroxide hypochlorites) Ca(OCl)2 0.5Ca(OH)2 [62974-42-9] and Ca(OCl)2 2Ca(OH)2 [12394-14-8], Sodium hypochlorite [7681-52-9] does not have good stabiHty. Potassium hypochlorite [7778-66-7] exists only in solution. Attempts to isolate the soHd have... [Pg.468]

The process of isolation finally adopted by the former authors consists in precipitating as reineckates the water-soluble bases contained in a methyl alcoholic extract of the curare. The mixed reineckates are further purified, by solution in acetone and precipitation with water as often as may be necessary. The product so cleaned represents the bulk of the biological activity of the crude drug the mother liquors may contain curine (p. 374), which indicates a menisperm as one of the components of such curares. The mixed reineckates are then fractionated chromato-graphically over alumina and the components isolated as chlorides by the use of silver sulphate and barium chloride in succession. This process has been modified in detail by Schmid and Karrer, who have also found that with their curare, the more soluble reineckate fraction includes less potent quaternary alkaloids. [Pg.380]

Crystalline barium bromite Ba(Br02)2-H20 was first isolated in 1959 it can be made by treating the hypobromite with Br2 at pH 11.2 and 0°C, followed by slow evaporation. Sr(Br02)2.2H20 was obtained similarly. [Pg.862]

Sulfonation with sulfur trioxide, pyridine sulfur trioxide, pyridine bis-sulfur trioxide, and dioxane sulfur trioxide, which are useful sul-fonating agents for acidophobic substances, have been applied to the thiophene seriesd At room temperature the 2-monosulfonic acid (isolated as the barium salt) is obtained in 86% yield. Higher temperatures lead to a disulfonic acid. However, sulfonation with chloro-sulfonic acid appears to be more convenient,as the sulfonyl chloride obtained can be used directly for the preparation of derivatives. [Pg.36]

Erdal, B.R. Aguilar, R.D. Bayhurst, B.P. Daniels, W.R. Duffy, C.J. Lawrence, F.O. Maestas, S. Oliver, P.Q. Wolfsberg, K. "Sorption-Desorption Studies on Granite. I. Initial Studies of Strontium, Technetium, Cesium, Barium, Cerium, Europium, Uranium, Plutonium, and Americium", in "Proceedings of the Task 4 Waste Isolation Safety Assessment Program Second Contractor Information Meeting", Vol. II, Report PNL-SA-7352, Battelle Pacific Northwest Laboratory, 1978, pp. 7-67. [Pg.343]

Sm(DippForm)2(THF)2 is isomorphous with the related strontium and barium amidinates. The trivalent samarate complex [Na(THF)5][Sml2(Dipp-Form)2(THF)2] was isolated in small quantities as a colorless by-product. Dissolution of this compound in hexane led to ligand redistribution to give homoleptic Sm(DippForm)3 with concomitant precipitation of Nal and SmlsfTHFls.s. The monofluoro-bis(amidinate) SmF(DippForm)2(THF) could also be isolated from Sm(DippForm)2(THF)2. ... [Pg.228]

The barium phosphonium dibenzylide 18, first organobarium compound not belonging to the cyclopentadienyl series, was isolated at the same time (Scheme 12) [58]. In the latter, the Ba + ion is encapsulated by two C2-symmet-ric phosphonium ligands of opposite chirality. [Pg.50]

Dihydroepistephamiersine 6-acetate (7) was isolated from Stephania abyssinica as a homogeneous oil. The UV spectrum showed an absorption maximum at 286 nm, and the IR spectrum exhibited a band corresponding to an aliphatic ester carbonyl group at 1725 cm-1 (20). The H-NMR data are summarized in Table II. In chemical investigations, hydrolysis of 7 with barium methoxide gave an alcohol identical with 6-dihydroepistephamiersine (17), which on further treatment with mineral acid gave the known alkaloid, stephasunoline (17). Thus structure 7 was proposed for 6-dihydroepistephamiersine 6-acetate (20). [Pg.324]

Howell88 considered it to be a derivative of D-glucuronic acid, but this view was not confirmed by Charles and Scott,89 who isolated a crystalline barium heparinate from beef lung and detected the presence in it of an amino sugar. [Pg.198]

For this solid-phase approach, conventional iPrOCH2-functionalized polystyrene resin (Merrifield linker) was employed. After attachment of the requisite substrate, the resin was pre-swollen in a solution of barium(II) hydroxide in N,N-dimethyl-formamide within an appropriate sealed microwave vial. The vial was heated in the microwave cavity for 5 x 2 min cycles (overall 10 min) with the reaction mixture being allowed to cool to room temperature in between irradiation cycles (Scheme 7.50), leading to comparatively modest isolated yields of hydantoins. [Pg.331]

Since aldehydes are notoriously polymerizable and difficult to manipulate, the products of periodate oxidation are oftentimes further oxidized, with hypohalite, to carboxylic acids, or are reduced to the corresponding alcohols. Oxidation has been more usually employed than reduction, since acids frequently form crystalline salts and other conveniently prepared derivatives. A process of oxidation of these aldehydic products by hypo-bromite, in the presence of barium carbonate or strontium carbonate, was developed and used extensively by Hudson and his coworkers.107 110 194-199,90s Their method can best be illustrated by an example the further oxidation of the dialdehyde, VI, shown previously (see p. 16) to be obtained by the oxidation of the methyl a-D-aldohexopyranosides. The isolation of... [Pg.24]

Ethyl sulfate Flammable liquids Fluorine Formamide Freon 113 Glycerol Oxidizing materials, water Ammonium nitrate, chromic acid, the halogens, hydrogen peroxide, nitric acid Isolate from everything only lead and nickel resist prolonged attack Iodine, pyridine, sulfur trioxide Aluminum, barium, lithium, samarium, NaK alloy, titanium Acetic anhydride, hypochlorites, chromium(VI) oxide, perchlorates, alkali peroxides, sodium hydride... [Pg.1477]

Synthesis of sucrose 6 -phosphate by an enzymic method using uridine 5 -(a-D-glucopyranosyl diphosphate) plus D-glucose 6-phosphate has been reported.126-131 The first, unambiguous, chemical synthesis of sucrose 6 -phosphate was achieved by Buchanan and coworkers.18 The reaction of 2,3,4,6,l, 3, 4 -hepta-0-acetylsucrose, prepared by five steps of synthesis, with cyanoethyl phosphate in pyridine gave a crude product from which sucrose 6 -phosphate was isolated as the barium salt. [Pg.271]

It is also possible to isolate bis(carbene) complexes involving the heavier alkaline earth metals. Thus, the reaction of two equivalents of 4 (R = Me or (Bu, R = H) with calcium, strontium and barium bis(trimethylsilyl)amides [M N(SiMe3)2 2(thf)2] (M = Ca, Sr, Ba) resulted in the displacement of two thf molecules to afford the corresponding biscarbene species, 19 (19). The solubilities and stabilities of these complexes were found to decrease from calcium to barium. [Pg.16]

Because synthetic products are isolated as the barium or, more frequently, the calcium salt of leucovorin, common acid-base titrations are not reported. If this type of titration or one in which the cation is exchanged were feasible, the results would require careful interpretation because impurities containing the glutamic acid moiety would respond similarly to leucovorin when the carboxyl groups are being analyzed. [Pg.336]


See other pages where Barium isolation is mentioned: [Pg.155]    [Pg.550]    [Pg.515]    [Pg.471]    [Pg.197]    [Pg.262]    [Pg.333]    [Pg.630]    [Pg.723]    [Pg.108]    [Pg.125]    [Pg.269]    [Pg.131]    [Pg.177]    [Pg.390]    [Pg.214]    [Pg.340]    [Pg.963]    [Pg.1214]    [Pg.191]    [Pg.142]    [Pg.159]    [Pg.195]    [Pg.239]    [Pg.17]    [Pg.261]    [Pg.15]    [Pg.180]    [Pg.183]    [Pg.185]    [Pg.189]   
See also in sourсe #XX -- [ Pg.307 ]




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