Antarctica ozone hole

During the mid-1980s, each September scientists began to observe a decrease in ozone in the stratosphere over Antarctica. These observations are referred to as "ozone holes." In order to understand ozone holes, one needs to know how and why ozone is present in the earth s stratosphere. 

The discovery of ozone holes over Antarctica in the mid-1980s was strong observational evidence to support the Rowland and Molina hypothesis. The atmosphere over the south pole is complex because of the long periods of total darkness and sunlight and the presence of a polar vortex and polar stratospheric clouds. However, researchers have found evidence to support the role of CIO in the rapid depletion of stratospheric ozone over the south pole. Figure 11-3 shows the profile of ozone and CIO measured at an altitude of 18 km on an aircraft flight from southern Chile toward the south pole on September 21, 1987. One month earlier the ozone levels were fairly uniform around 2 ppm (vol). 

J. C. Farman discovered the ozone hole (substantial seasonal depletion of ozone) over Halley Bay, Antarctica. 

Thus, the mean temperature of the atmosphere, which is about 20°C at sea level, falls steadily to about —55° at an altitude of 10 km and then rises to almost 0°C at 50 km before dropping steadily again to about —90° at 90 km. Concern was expressed in 1974 that interaction of ozone with man-made chlorofluorocarbons would deplete the equilibrium concentration of ozone with potentially disastrous consequences, and this was dramatically confirmed by the discovery of a seasonally recurring ozone hole above Antarctica in 1985. A less prominent ozone hole was subsequently detected above the Arctic Ocean. The detailed physical and chemical conditions required to generate these large seasonal depletions of ozone are extremely complex but the main features have now been elucidated (see p. 848). Several accounts of various aspects of the emerging story, and of the consequent international governmental actions to... 

The catalyzed decomposition of ozone is known to be responsible for the ozone hole (Figure A) that develops in Antarctica each year in September and October, at the end of winter in the Southern Hemisphere. No ozone is generated during the long, dark Antarctic winter. Meanwhile, a heterogeneous reaction occurring on clouds of ice... 

The development of the ozone hole over Antarctica is accelerated by heterogeneous catalysis on microciystals of ice. These microcrystals form in abundance in the Antarctic spring, which is when the ozone hole appears. Ice microciystals are less common in the Arctic atmosphere, so ozone depletion has not been as extensive in the Northern Hemisphere. 

An ozone hole over Antarctica was discovered with especially low concentrations of ozone above that continent in their spring (Northern Hemisphere s fall). This was linked to CFCs. 

The substantial concentration of ozone in the stratosphere can be significantly depleted by comparatively small amounts of other substances. The significantly depleted ozone level in polar regions (mostly over Antarctica) is referred to as the ozone hole. 

Figure 12.17 shows the ozone profiles over the U.S. Amundsen-Scott Station at the South Pole in 1993 on August 23 prior to formation of the ozone hole and on October 12 after the ozone hole had developed. The total column ozone decreased from 276 DU on August 23 to only 91 DU on October 12, and, in addition, there was essentially no ozone in the region from 14 to 19 km (Hofmann et al., 1994a). During the same period at the McMurdo Station in Antarctica, the total column ozone decreased from 275 to 130 DU (B. J. Johnson et al., 1995). While similar profiles have been observed since the discovery of the ozone hole, these data show some of the most extensive ozone destruction ever observed, although 1994 and 1995 showed almost as much 03... 

Stamnes, K., Z. Jin, and J. Slusser, Several-Fold Enhancement of Biologically Effective Ultraviolet Radiation Levels at McMurdo Station, Antarctica during the 1990 Ozone Hole, Geophys. Res. Lett., 19, 1013-1016 (1992). 

The process responsible for the "ozone hole over Antarctica is thought to be similar, though it may be heterogeneous, taking place on ice particles.58... 

FIGURE 9.18 A false- color satellite image of the ozone hole over Antarctica on September 26, 2002. The lowest ozone concentrations are represented by the black and violet regions, where ozone levels are up to 50% lower than normal. 

It has been estimated that one chlorine atom has an atmospheric lifetime of one to two years and may destroy 100,000 ozone molecules, thus contributing to the mysterious ozone hole. The British Antarctic Survey discovered the lowest ozone concentration in Earth s atmosphere ever recorded, in October 1984 nearly 40 percent less than the historical average for Antarctica. Atmospheric currents concentrate CFCs over Antarctica, creating the ozone hole that in 1984 was larger than the United States and taller than Mount Everest. The loss of ozone as a protective layer permits the penetration of increased levels of ultraviolet light to Earth s surface. 

The decomposition of Freons in the atmosphere contributes to the destruction of the ozone layer. In this image, the ozone hole is visible over Antarctica. 

In the winter of 1984, massive losses of stratospheric ozone were detected in Antarctica over the South Pole (Halley Bay). This ozone depletion is known as the ozone hole. We know now that it also forms over the Arctic, although not as dramatically as in the Antarctic. Stratospheric ozone protects life on the surface of the Earth by screening harmful UV radiation coming from the sun through a photodissociation mechanism (see Chapter 4). 

The Antarctic ozone holes typically develop at altitudes of 7.4-16 mi (12-25 km). The average decreases in springtime stratospheric ozone concentrations over Antarctica have been 30-40%. However, in some years the decrease in ozone has been over 60%. In the worst years, the ozone concentration over Antarctica was only 120 DU. In October 1999, the ozone concentrations were less than 50% of what they were in the 1960s. 

Ozone holes—Decreased concentrations of stratospheric ozone, occurring at high latitudes during the early springtime. Ozone holes are most apparent over Antarctica, where they develop under intensely cold conditions during September and November, allowing a greater penetration of deleterious solar ultraviolet radiation to Earth s surface. 

Thinning of the ozone layer over Antarctica is called the ozone hole. 

FIGURE 20.29 This false color image shows total stratospheric ozone amounts over the southern hemisphere for September 24, 2006, as recorded by the Ozone Monitoring Instrument (OMI) mounted on the Aura spacecraft. The dramatic depletion of the ozone layer over Antarctica is revealed with the help of the false color scale at the bottom of the figure. Ozone amounts are commonly expressed in Dobson units 300 Dobson units is a typical global average over the course of a year. The size of the Antarctic ozone hole was near a record high and the levels of ozone near a record low on this date. 

The ozone hole over Antarctica results from the storage of chlorine-containing molecules on the surfaces of polar stratospheric clouds during the Antarctic winter followed by sudden photolysis and release in the spring. 

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