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An infrared detector

Copolymers of methyl acrylate and methyl N-vinylcarbamate [4], styrene and vinyl stearate [6, 52], styrene and t-butyl methacrylate [53], styrene and acrylonitrile, and styrene and methyl methacrylate [54] can use a [Pg.118]

Instead of measuring chromatograms two or three times at different wavelengths for different functional groups, operation in a stop-and-go fashion was introduced for rapid determination of copolymer composition as a function of molecular mass [52]. Tetrachloroethylene was used as the mobile phase. An SEC chromatogram was monitored at 2930 cm for the C-H [Pg.119]

P(VC-VAc) copolymers were fractionated by analytical SEC and copolymer films made from the fractions were then subjected to IR analysis for the [Pg.120]

Several different techniques for the preparation of stereospecific block copolymers of styrene and butadiene have been studied using an SEC-RI system [56]. The block copolymers prepared free of impurities showed a single peak, and those prepared in the presence of impurities showed two peaks which were identified by fractionation and IR spectrophotometry. [Pg.121]

EVA copolymers and SBR were fractionated by preparative SEC, and the fractions were analysed by IR spectrophotometry [57]. The vinyl acetate content in EVA was almost constant over the whole molecular-mass range, except in the higher-molecular-mass species. The composition of SBR varied [Pg.121]


The eombination in a compact system of an infrared sensor and a laser as excitation source is called a photothermal camera. The surface heating is aehieved by the absorption of the focused beam of a laser. This localisation of the heating permits a three-dimensional heat diffusion in the sample to be examined. The infrared (IR) emission of the surface in the neighbourhood of the heating spot is measured by an infrared detector. A full surface inspection is possible through a video scanning of the excitation and detection spots on the piece to test (figure 1). [Pg.393]

Water Transport. Two methods of measuring water-vapor transmission rates (WVTR) ate commonly used. The newer method uses a Permatran-W (Modem Controls, Inc.). In this method a film sample is clamped over a saturated salt solution, which generates the desired humidity. Dry air sweeps past the other side of the film and past an infrared detector, which measures the water concentration in the gas. For a caUbrated flow rate of air, the rate of water addition can be calculated from the observed concentration in the sweep gas. From the steady-state rate, the WVTR can be calculated. In principle, the diffusion coefficient could be deterrnined by the method outlined in the previous section. However, only the steady-state region of the response is serviceable. Many different salt solutions can be used to make measurements at selected humidity differences however, in practice,... [Pg.500]

Carbon Dioxide Transport. Measuring the permeation of carbon dioxide occurs far less often than measuring the permeation of oxygen or water. A variety of methods ate used however, the simplest method uses the Permatran-C instmment (Modem Controls, Inc.). In this method, air is circulated past a test film in a loop that includes an infrared detector. Carbon dioxide is appHed to the other side of the film. AH the carbon dioxide that permeates through the film is captured in the loop. As the experiment progresses, the carbon dioxide concentration increases. First, there is a transient period before the steady-state rate is achieved. The steady-state rate is achieved when the concentration of carbon dioxide increases at a constant rate. This rate is used to calculate the permeabiUty. Figure 18 shows how the diffusion coefficient can be deterrnined in this type of experiment. The time lag is substituted into equation 21. The solubiUty coefficient can be calculated with equation 2. [Pg.500]

FIGURE 13.27 Urethane and some isocyanates on the same system, but including an infrared detector in series at 5.88 micron. The MDI and TDI have different retentions so they can be distinguished from each other in a urethane. [Pg.385]

With proper design, fabrication and clocking, most of these negative aspects can be overcome, but there are usually some bad columns due to blocked columns or hot pixels. There are many positive aspects of charge transfer, giving the CCD some very good and unique attributes vis-a-vis an infrared detector ... [Pg.147]

A Fourier transform infrared spectroscopy spectrometer consists of an infrared source, an interference modulator (usually a scanning Michelson interferometer), a sample chamber and an infrared detector. Interference signals measured at the detector are usually amplified and then digitized. A digital computer initially records and then processes the interferogram and also allows the spectral data that results to be manipulated. Permanent records of spectral data are created using a plotter or other peripheral device. [Pg.31]

In the infrared detection system, the sample is weighed into a special ceramic boat which is then placed into a combustion furnace at 1371°C (2500°F) in an oxygen atmosphere. Most of the sulfur present is converted to sulfur dioxide, which is then measured with an infrared detector after moisture and dust are removed by traps. The calibration factor is determined using standards approximating the material to be analyzed. [Pg.298]

An infrared detector and AC-amplifer converts this flux into an electrical signal... [Pg.91]

The coated foil is then processed to the next step, the drying compartment. The drying compartment essentially consists of a convection heater with two small slits for the traversing of the foil. The surface temperature of the foil is measured by an infrared detector. Temperature control is crudal in this process step, as the aqueous slurry must not be allowed to boil, which would deteriorate the coat evenness. During drying, the coat thickness shrinks (depending on the water content of the... [Pg.626]

The problems stated above are overcome in US-A-3808435 by a.c. coupling detector signals of an infrared detector array to a CTD array. The detector array and the CTD array... [Pg.123]

The problems mentioned above are overcome in US-A-3808435 by a.c. coupling detector signals of an infrared detector array to a CTD array. The detector array and the CTD array are formed in an HgCdTe chip and a silicon chip respectively and are connected by placing the chips on top of each other with intermediate conductor elements. This technique of connecting two chips is generally called the flip-chip technique. [Pg.269]

In US-A-4369458 the contact array of an infrared detector includes a substantially greater number of contacts than the contact array of a signal processor. At the flip-chip bonding operation it is not a prerequisite to precisely align the two integrated circuits in a one-to-one contact relationship. [Pg.269]

A support substrate 22 of CdTe is attached to the backside of an infrared detector array of HgCdTe having four fiducial through holes 20 which provide a means for visibly observing an indication of the position of the detector elements from the back side 26 of the support substrate 22. The hole 20 is used in the alignment of the detector array to indices formed upon a signal processing module. [Pg.288]

A problem encountered when aluminium is used as gate metal for a MIS structure is the significant etching of the aluminium by the bromine solution which is used to form vias or contacts in overlaying ZnS insulator films. To solve this problem, it is proposed in EP-A-0407062 to use refractory metals as the metallization layers of an infrared detector. [Pg.335]

Solvent-free conditions can be employed according to three main methods (a) using only neat reactants (b) reactants adsorbed onto solid supports or (c) reactants in the presence of phase transfer catalysts (in the case of anionic reactions). Besides the apparent potential benefits in solvent usage, reactions can be conducted conveniently and rapidly, often without temperature measurement in domestic microwave ovens. However, they now are often carried out under more precisely controlled conditions using monomode reactors initially introduced by the former French manufacturer Prolabo. Nowadays, several systems are available that provide facilities for the accurate measurement and monitoring of temperature throughout the reaction by modulation of emitted power with an infrared detector or an optical fibre. [Pg.206]

Fig. 7.1. Layout of the infrared spectrometer showing the Michelson Interferometer Optical System. An FTIR spectrometer s optical system requires two mirrors, an infrared light source, an infrared detector and a beamsplitter. The beamsplitter reflects about 50% of an incident light beam and transmits the remaining 50%. One part of this split light beam travels to a moving interferometer mirror, while the other part travels to the interferometer s stationary mirror. Both beams are reflected back to the beamsplitter where they recombine. Half of the recombined light is transmitted to the detector and half is reflected to the infrared source. Fig. 7.1. Layout of the infrared spectrometer showing the Michelson Interferometer Optical System. An FTIR spectrometer s optical system requires two mirrors, an infrared light source, an infrared detector and a beamsplitter. The beamsplitter reflects about 50% of an incident light beam and transmits the remaining 50%. One part of this split light beam travels to a moving interferometer mirror, while the other part travels to the interferometer s stationary mirror. Both beams are reflected back to the beamsplitter where they recombine. Half of the recombined light is transmitted to the detector and half is reflected to the infrared source.
Determination of the average chemical composition and polymer composition by size-exclusion chromatography (SEC) has been reported in the literature. Two different types of concentration detector or two different absorption wavelengths of an ultraviolet or an infrared detectors are employed the composition at each retention volume is calculated by measuring peak responses at the identical retention points of the two chromatograms. [Pg.446]

Thermal detector An infrared detector that produces heat as a result of absorption of radiation. [Pg.1119]

The noise equivalent power (NEP) of an infrared detector is a measure of the noise generated by the detector and is given by ... [Pg.10]

In spectroscopic investigations, the intensity transmitted or reflected by the sample is compared with the intensity of the incident light at a given wavelength or frequency thus, with a spectrometer, intensities and wavelengths are measured simultaneously. Intensities are determined by means of an infrared detector. Clearly, the performance of the detector is just as important to the spectroscopist, as that of the source, but these and other problems of infrared technique are beyond the scope of this introduction and the reader is referred to the literature 3.3). [Pg.75]

F) in an oxygen atmosphere. Moisture and dust are removed with traps, and the sulfur dioxide is measured with an infrared detector. [Pg.45]


See other pages where An infrared detector is mentioned: [Pg.182]    [Pg.258]    [Pg.193]    [Pg.396]    [Pg.38]    [Pg.687]    [Pg.314]    [Pg.199]    [Pg.139]    [Pg.139]    [Pg.274]    [Pg.274]    [Pg.251]    [Pg.276]    [Pg.42]    [Pg.447]    [Pg.276]    [Pg.583]    [Pg.51]    [Pg.99]    [Pg.347]    [Pg.785]   


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