Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Amines salt formation

These results pointed ont that quantitative gas-solid reactions with aliphatic amines (salt formation) must be carried out with powdered 2-mercaptobenzothiazole for obtaining reactive crystal faces. Also, solid-solid oxidation with l-oxo-2,2,6,6-tetramethyl-piperidinium nitrate required milling for breaking the self-protection. ... [Pg.687]

Salt Formation. Salt-forming reactions of adipic acid are those typical of carboxylic acids. Alkali metal salts and ammonium salts are water soluble alkaline earth metal salts have limited solubiUty (see Table 5). Salt formation with amines and diamines is discussed in the next section. [Pg.240]

AH corrosion inhibitors in use as of this writing are oil-soluble surfactants (qv) which consist of a hydrophobic hydrocarbon backbone and a hydrophilic functional group. Oil-soluble surfactant-type additives were first used in 1946 by the Sinclair Oil Co. (38). Most corrosion inhibitors are carboxyhc acids (qv), amines, or amine salts (39), depending on the types of water bottoms encountered in the whole distribution system. The wrong choice of inhibitors can lead to unwanted reactions. Eor instance, use of an acidic corrosion inhibitor when the water bottoms are caustic can result in the formation of insoluble salts that can plug filters in the distribution system or in customers vehicles. Because these additives form a strongly adsorbed impervious film at the metal Hquid interface, low Hquid concentrations are usually adequate. Concentrations typically range up to 5 ppm. In many situations, pipeline companies add their own corrosion inhibitors on top of that added by refiners. [Pg.186]

Hydantoin itself can be detected ia small concentrations ia the presence of other NH-containing compounds by paper chromatography followed by detection with a mercury acetate—diphenylcarba2one spray reagent. A variety of analytical reactions has been developed for 5,5-disubstituted hydantoias, due to their medicinal iaterest. These reactions are best exemplified by reference to the assays used for 5,5-diphenylhydantoiQ (73—78), most of which are based on their cycHc ureide stmcture. Identity tests iaclude the foUowiag (/) the Zwikker reaction, consisting of the formation of a colored complex on treatment with cobalt(II) salts ia the presence of an amine (2) formation of colored copper complexes and (3) precipitation on addition of silver(I) species, due to formation of iasoluble salts at N. ... [Pg.255]

Tertiary amines have been shown to react with isocyanates ia an analogous fashion to form ureas (41—43). Similarly, a2iridines (three-membered rings containing nitrogen) are found to react with isocyanates to yield cycHc ureas. Tertiary amines have also been shown to form labile dipolar 1 1 adducts with isocyanates reminiscent of salt formation. In contrast, formaldehyde acetal aminals form iasertion products with sulfonyl isocyanates (44,45). [Pg.449]

Aromatic Isocyanates. A variety of methods are described in the Hterature for the synthesis of aromatic isocyanates. Only the phosgenation of amines or amine salts is used on a commercial scale (5). Much process refinement has occurred to minimise the formation of disubstituted ureas arising by the reaction of the generated isocyanate with the amine starting material. A listing of the key commercially available isocyanates is presented in Table 1. [Pg.452]

In the presence of an anionic surfactant such as sodium dodecyl-benzenesulfonate [25155-30-0] any protonated amine salt present forms an insoluble salt (4). Salt formation results in an increase in the pH of the solution. [Pg.189]

Salt formation with Brmnsted and Lewis acids and exhaustive alkylation to form quaternary ammonium cations are part of the rich derivati2ation chemistry of these amines. Carbamates and thiocarbamates are formed with CO2 and CS2, respectively the former precipitate from neat amine as carbamate salts but are highly water soluble. [Pg.208]

Salt Formation. Amines react with inorganic and organic acids. [Pg.219]

Propylene oxide has found use in the preparation of polyether polyols from recycled poly(ethylene terephthalate) (264), haUde removal from amine salts via halohydrin formation (265), preparation of flame retardants (266), alkoxylation of amines (267,268), modification of catalysts (269), and preparation of cellulose ethers (270,271). [Pg.143]

Dialkyldimethyl and alkyltrknethyl quaternaries can be prepared direcdy from secondary and primary amines as shown ia equations 7 and 8, respectively. This process, known as exhaustive alkylation, is usually not the method of choice on a commercial scale. This technique requires the continuous addition of basic material over the course of the reaction to prevent the formation of amine salts (223,224). Furthermore, products such as inorganic salt and water must be removed from the quaternary. The salt represents a significant disposal problem. [Pg.381]

For extraction of uranium from sulfate leach Hquors, alkyl phosphoric acids, alkyl phosphates, and secondary and tertiary alkyl amines are used in an inert diluent such as kerosene. The formation of a third phase is suppressed by addition of modifiers such as long-chain alcohols or neutral phosphate esters. Such compounds also increase the solubihty of the amine salt in the diluent and improve phase separation. [Pg.317]

Reactions of the carboxyl group include salt and acid chloride formation, esterification, pyrolysis, reduction, and amide, nitrile, and amine formation. Salt formation occurs when the carboxyUc acid reacts with an alkaline substance (22)... [Pg.84]

Salt Formation. Citric acid forms mono-, di-, and tribasic salts with many cations such as alkahes, ammonia, and amines. Salts may be prepared by direct neutralization of a solution of citric acid in water using the appropriate base, or by double decomposition using a citrate salt and a soluble metal salt. [Pg.180]

Catalytic hydrogenation of the nitrile function of cyanohydrins can give amines. As in the case of ordinary nitriles, catalytic reduction of cyanohydrins can yield a mixture of primary, secondary, and tertiary amines. Addition of acid or acetic anhydride to the reaction medium minimizes formation of secondary or tertiary amines through formation of the amine salt or acetamide derivative of the primary amine. [Pg.411]

Primary and secondary amines, double bonds, aldehydes, sulfides and certain aromatic and dihydroaroraatic systems are also oxidized by chromium VI reagents under standard hydroxyl oxidizing conditions. Amines are commonly protected by salt formation or by conversion to amides. Aldehydes and... [Pg.226]

Experimental evidence, obtained in protonation (3,6), acylation (1,4), and alkylation (1,4,7-9) reactions, always indicates a concurrence between electrophilic attack on the nitrogen atom and the -carbon atom in the enamine. Concerning the nucleophilic reactivity of the j3-carbon atom in enamines, Opitz and Griesinger (10) observed, in a study of salt formation, the following series of reactivities of the amine and carbonyl components pyrrolidine and hexamethylene imine s> piperidine > morpholine > cthyl-butylamine cyclopentanone s> cycloheptanone cyclooctanone > cyclohexanone monosubstituted acetaldehyde > disubstituted acetaldehyde. [Pg.102]

Solvents influence the hydrogenation of oximes in much the same way as they do hydrogenation of nitriles. Acidic solvents prevent the formation of secondary amines through salt formation with the initially formed primary amine. A variety of acids have been used for this purpose (66 ), but acids cannot always be used interchangeably (43). Primary amines can be trapped also as amides by use of an anhydride solvent (2,/5,57). Ammonia prevents secondary amine formation through competition of ammonia with the primary amine in reaction with the intermediate imine. Unless the ammonia is anhydrous hydrolysis reactions may also occur. [Pg.100]

By structural complementarity, dicationic l,4-diazabicyclo[2.2.2]octane (VII) provides an appropriate recognition site for phosphate ions and two stearyl side chains attached to the amines add lipophilic properties 59,60). Such a carrier model can selectively extract nucleotides from aqueous solution to chloroform solution via lipophilic salt formation. The order of nucleotide affinity is ATP > ADP > AMP. The selectivity ratios were 45 for ADP/AMP and 7500 for ATP/AMP at pH 3. The relative transport rate was ATP > ADP > AMP. The ratios were 60 for ATP/AMP and 51 for ADP/AMP. The modes of interaction of ADP and ATP are proposed to be as shown in Fig. 6. [Pg.128]

Amine salts of a-sulfonated fatty acids and esters are also used as antistatic agents. Mixtures of alkyl a-sulfo fatty acid ester diethanolamine salts and hexa-decyl stearate or butyl stearate are coated onto nylon yarn after fiber formation and before stretching [97]. Polypropylene can be made antistatic with an amine salt of a-sulfolauric acid [C10H21CH(SO3Na)COO +NH(CH2CH(OH) CH3)3] [98]. [Pg.491]

Normally the reaction Is useful for the conversion of alkyl halides to primary amines without concomitant formation of secondary amines.29 Treatment of polymer 17 with hexamethylenetetramine in a mixture of ethanol/THF afforded an insoluble resin. Using diazabicyclooctane (DABCO), we demonstrated that the reaction could be limited to attack by a single nitrogen in a multifunctional amine, so we did not anticipate crosslinking via bis-quat salt formation. Hydrolysis of 2 with anhydrous HC1 in ethanol generated free amino groups as evidenced by a positive ninhydrin test, but quantitative hydrolysis could not be achieved and the product remained insoluble. One would have expected a simple bis-quat to hydrolyse and open the crosslinked structure. [Pg.19]

In practical terms, it is invariably a nitrogen atom that is protonated in salt formation. This always leads to a downfield shift for protons on carbons both alpha and beta to the nitrogen concerned. In alkyl amines, the expected shifts would be about 0.7 and 0.3 ppm respectively. Remember that some heterocyclic compounds (e.g., pyridine) contain nitrogen atoms that are basic enough to protonate and comparable downfield shifts can be expected (Spectrum 5.9). [Pg.97]

As a cationic polymer and a cationic amphiphile, poly(allyl amine hydrochloride) (PAA) and octadecylamine (ODA) shown in Fig. 6 were used, respectively. The stability of the monolayers of the anionic amphiphiles was increased by polyion-complexation with PAA added in the aqueous subphase in comparison with Ca2+ salt formation. Ion complexation (1 1) of each anionic amphiphile with ODA was also performed at the air-water interface by spreading a chloroform solution of a 1 1 surfactant mixture. [Pg.216]


See other pages where Amines salt formation is mentioned: [Pg.475]    [Pg.475]    [Pg.475]    [Pg.114]    [Pg.475]    [Pg.475]    [Pg.475]    [Pg.114]    [Pg.488]    [Pg.1038]    [Pg.121]    [Pg.454]    [Pg.454]    [Pg.131]    [Pg.219]    [Pg.61]    [Pg.95]    [Pg.222]    [Pg.551]    [Pg.157]    [Pg.370]    [Pg.285]    [Pg.1038]    [Pg.192]    [Pg.248]    [Pg.71]    [Pg.97]    [Pg.105]    [Pg.599]    [Pg.1365]    [Pg.223]   
See also in sourсe #XX -- [ Pg.48 , Pg.49 ]




SEARCH



Aminal formation

Aminals, formation

Amines amine salts

Amines formation

Amines salts

Formate salts

Salts formation

© 2024 chempedia.info