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Acetate reactions with

Unsubstituted 20-ketones readily form enol acetates. Reaction with isopropenyl acetate yields the kinetic A -isomer (86, R = CH3CO) which is equilibrated to the A -enol acetate (85, R = CH3CO) on exposure to acetic anhydride-/7-toluenesulfonic acid. Treatment of the 20-ketone according to the latter conditions gives the A -enol acetate directly. [Pg.399]

Ammonium acetate, reaction with tn-ethyl orthoformate to give form-amidine acetate, 46, 39 Ammonium p chlorophenyldithiocarba mate, 46, 21... [Pg.120]

Potassium acetate, reaction with N,N-dichlorocyclohexylamme, 46,17 Potassium t butoxide, 46, 33... [Pg.136]

Acetone dimethyl acetal, reaction with n-butanol, 42,1... [Pg.105]

Vicinal iodo carboxylates may also be prepared from the reaction of olefins either with iodine and potassium iodate in acetic acid/ or with N-iodosuccinimide and a carboxylic acid in chloroform. " A number of new procedures for effecting the hydroxylation or acyloxylation of olefins in a manner similar to the Prevost or Woodward-Prevost reactions include the following iodo acetoxylation with iodine and potassium chlorate in acetic acid followed by acetolysis with potassium acetate reaction with iV-bromoacetamide and silver acetate in acetic acid reaction with thallium(III) acetate in acetic acid and reaction with iodine tris(trifluoroacetate) in pentane. ... [Pg.88]

Potassium acetate, reaction with N,N-dichlorocyclohexylamine, 46,17 Potassium amide, 48, 41 Potassium / butoxide, 46, 33 alcohol-free, reaction with bromo-benzene, 46, 89... [Pg.80]

P3.04.04. DILATOMETRY. ACETAL REACTION WITH WATER The rate of the reaction... [Pg.177]

Mercuric acetate, reaction with cyclo-octatetraene, 50, 24 Mercuric oxide, use in oxidation of hydrazones, 50, 28 with 3-chlorocyclobutanecarboxylic acid and bromine to give 1-bromo-... [Pg.79]

An analogous scheme is used for the synthesis of the cardiotonic agent milrinone [28]. The key aminoformyl derivative (26-2) is obtained in this case by condensation of 4-pyridylacetone (26-1) with DMF acetal. Reaction with cyanoacetamide in the presence of a strong base proceeds exactly as above to give the pyridone (26-3) by a parallel set of transformations. Note that the nitrile is left as such in this drug. [Pg.338]

The synthesis of poly(vinyl acetals) (252) represents another example of generating a heterocycle, in this case the 1,3-dioxane nucleus, by application of a polymer modification reaction. Generally, the polymer modified is poly(vinyl alcohol) (180) or one of its copolymers. The 1,3-dioxane ring is generated (Scheme 122) by an acid-catalyzed acetalization reaction with an aldehyde, although ketones have also been reacted. A review (71MI11102) is available covering synthesis, properties and applications of the two most common and industrially important poly(vinyl acetals), poly(vinyl butyral) and poly(vinyl formal), as well as many other functional aldehydes that have been attached. [Pg.315]

Acetal, reaction with Br, III, 167 Acetaldehyde, effect on ketonuria, II, 148... [Pg.321]




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1,1 -Methylenebis diiodides, reaction with palladium acetate

1.3- Bis imidazolium bromide reaction with palladium acetate

1.3- Dimethylimidazolium iodide, formation reaction with nickel acetates

1.3- Dimethylimidazolium iodide, formation reaction with palladium acetate

1.4- Dimethyl-1,2,4-triazolium iodide reaction with nickel acetate

1.4- Dimethyl-1,2,4-triazolium iodide reaction with palladium acetate

1.5- Bis pentane reaction with palladium acetate

2- Picoline reaction with acetic anhydride

2- acetic acid, reaction with

2-Cyano-2- acetate reaction with hydrazine hydrate

4-Nitrophenyl acetate, reaction with

4-Nitrophenyl acetate, reaction with phenoxide ions

4-nitrophenyl acetate, reaction with phenolate

4.5- Diphenylimidazole, reaction with palladium acetate

Acetals addition reactions with alkylaluminum

Acetals reaction with Lewis acids

Acetals reaction with allylsilanes

Acetals reaction with bases

Acetals reaction with bromine

Acetals reaction with carboxylic acids

Acetals reaction with hydrogen fluoride

Acetals reaction with silyl enol ethers

Acetals reaction with triphenylmethyl

Acetals reactions with

Acetals reactions with

Acetals reactions with organocopper compounds

Acetals reactions with organomagnesium

Acetals reactions with organometallic compounds

Acetals reactions with wood

Acetals, a-hydroxy addition reactions with alkylaluminum

Acetals, allylic reaction with organocopper compounds

Acetals, cyclic, reaction with acyl trifluoroacetates

Acetals, reaction with carbene complexes

Acetals, silylketene reaction with imines

Acetate allyl, reaction with diketones

Acetate rhodium, reaction with

Acetate silver, reaction with bromine

Acetate thallium, reaction with

Acetates arylvinyl-, reaction with

Acetates reaction with organocuprates

Acetates, alkylidenecyanoaddition reactions with organomagnesium compounds

Acetates, alkylidenecyanoaddition reactions with organozinc compounds

Acetates, alkylidenephosphonoaddition reactions with organomagnesium compounds

Acetates, alkylidenephosphonoaddition reactions with organozinc compounds

Acetic acid anhydride, reaction with radical

Acetic acid esterification reaction with alcohols

Acetic acid reaction with ammonia

Acetic acid reaction with baking soda

Acetic acid reaction with ethanol

Acetic acid reaction with methylamine

Acetic acid reaction with potassium

Acetic acid reaction with pyridine

Acetic acid reaction with strong

Acetic acid reaction with strong base

Acetic acid reaction with water

Acetic acid, reaction with alkoxides

Acetic acid, reaction with bicyclo hepta-2,5-diene

Acetic acid, reaction with glycals

Acetic acid, tributylstannylethyl ester reaction with benzaldehyde

Acetic anhydride Friedel-Crafts reaction with

Acetic anhydride reaction with amines

Acetic anhydride reaction with benzaldehyde

Acetic anhydride reaction with ethylene glycol

Acetic anhydride reaction with water

Acetic anhydride, electrostatic reaction with alcohols

Acetic anhydride, electrostatic reaction with amines

Acetic anhydride, reaction with amino

Acetic anhydride, reaction with ethanol

Acetone dimethyl acetal, reaction with

Aldehydes reaction with ketene acetals

Aldehydes reaction with silyl ketene acetals

Alkenes reaction with acetic anhydride

Alkenes reaction with mercury acetate

Alkenes, reaction with mercuric acetate

Alkylidenecyclopropanone acetals reaction with furans

Alkynes mercuric acetate, reaction with

Allyl acetate, ozone reactions with

Allyl acetates reactions with carbonyl compounds

Allylic acetates reactions with carbonyl compounds

Aluminum, sulfatobis catalyst allylstannane reaction with acetals

Amide acetals, reaction with malonate

Ammonium acetate, reaction with

Ammonium acetate, reaction with ketones

Aromatic compounds reaction with acetals

Benzaldehyde dimethyl acetal, reaction with

Benzaldehyde reaction with acetals

Benzenetellurinyl acetate reactions with alkenes

Benzimidazole-2-acetate, reaction with

Boron trifluoride allylsilane reactions with acetals

Bromine, reaction with cyclic acetals

Butenolide anions reactions with acetals

Butyllithium, reaction with cyclic acetals

Calcium acetate, reaction with

Cellulose reaction with acetic anhydride

Crotylsilanes, reaction with acetals

Cupric acetate, reaction with

Cyano acetic acid ethyl ester, reaction with

Cyclohexanol, reaction with acetic acid

Cyclooctatetraene, chlorination reaction with mercuric acetate

Diels-Alder reactions with acetal

Diethyl acetal enaminones, reactions with

Enol acetates reaction with methyllithium

Enol acetates, reaction with

Enol acetates, reaction with organolithium reactions

Enol ethers reaction with acetals

Enol silanes reaction with acetals

Enol silanes reaction with chiral acetals

Enol silanes reaction with dimethyl acetals

Enol silyl ethers, reaction with acetals/ketals

Enol sulfonates reaction with acetals

Ethane reaction with acetic acid

Ethanol esterification reactions with acetic acid

Ethers, vinyl reaction with ketene acetals

Ethyl acetate reaction with pentylmagnesium bromide

Ethyl acetate, reaction with hydroxyl ions

Glucose, acetals reaction with pyruvic acid

Grignard reagents reaction with acetals

Hydrazine reaction with acetal

Imines, reaction with ketene acetals

Imines, reactions with silyl ketene acetals

Imino esters reaction with silyl ketene acetals

Iodosylbenzene reaction with acetic acid

Isopropenyl acetate reaction with acetals

Isopropenyl acetate reaction with triethylmethoxytin

Keten acetals Diels-Alder reaction with

Ketene acetals reaction with 1,2,4-triazines

Ketene acetals reaction with epoxides

Ketene acetals reactions with isocyanates

Ketene acetals, bis reaction with imines

Ketene acetals, reactions with amines

Ketones and aldehydes, distinguishing from reaction with alcohols to form acetal

Lewis acids reaction with cyclic acetals

LiAlH4, reaction with acetates

Lithium diisopropylamide, reaction with acetals

Lithium hydrate of bis acetate, reaction with niobium

Lithium hydrate of bis acetate, reaction with niobium complexes

Magnesium, alkylbromoboron trifluoride complex reactions with acetals

Malonate, enolates, reaction with palladium, acetates

Manganese acetate reaction with alkenes

Manganese acetate, reaction with aldehydes

Mercuric acetate, reaction with amines

Mercuric acetate, reaction with cyclooctatetraene

Miscellaneous reactions reaction with acetals

Monosaccharide reaction with acetic anhydride

Montmorillonite clays allylsilane, reaction with acetals

Montmorillonite clays enol ether, reaction with acetals

Mukaiyama aldol reaction with acetals

Nitrones reaction with silyl ketene acetals

Nitroso acetals reactions with nucleophiles

Nucleophiles reaction with amide acetal

Organolithium reagents reactions with acetals

Organolithium reagents, reaction with enol acetates

Oxygen reaction with bis-silyl ketene acetals

P-Diesters reaction with allylic acetate

Peroxides, hexamethyldisilyl reaction with enol acetates

Peroxy acids reaction with enol acetate

Phenyl acetates, reaction with

Phenyl acetates, reaction with imidazole

Phenyl mercury acetate, reaction with

Polyvinyl acetal reaction with isocyanates

Potassium acetate, reaction with

Potassium acetate, reaction with N,Ndichlorocyclohexylamine

Potassium hydroxide reaction with acetic acid

Propargylic acetates reaction with oxiranes

Propargylic acetates reactions with carbonyl compounds

Propionaldehyde, 3-phenylacetal reaction with isopropenyl acetate

Pyridine 1-oxide reaction with acetic anhydride

Pyridine-2-thione, reaction with acetate

Pyrimidine-2-thione, reaction with acetate

Reaction benzyl alcohol with acetic acid

Reaction with Alcohols Acetals and Ketals

Reaction with acetic anhydride

Reaction with allylic acetates

Reaction with dimethylformamide acetals

Reaction with ethyl acetate

Reaction with isopropyl acetate

Reaction with ketene acetals

Reaction with manganese acetate

Reaction with mercuric acetate

Reaction with nitric acid-acetic anhydride

Reaction with propargyl acetates

Reaction with silyl ketene acetals

Reactions with Cyclic Acetals

Reactions with lead acetates

Rhodium acetate, reaction with diazo

Rhodium acetate, reaction with diazo carbonyl

Salicylaldehyde, reaction with chloro acetic acid

Salicylaldehyde, reaction with ethyl acetate

Silane, allenylreaction with acetals Friedel-Crafts reaction

Silane, allenylreaction with acetals Mannich reaction

Silane, allenylreaction with acetals reactions

Silane, propargylacylation reaction with acetals

Silane, vinylepoxidation reaction with acetals

Silyl ketene acetals reaction with aldehydes, diastereoselectivity

Silyl ketene acetals reactions with N-silylimines

Silyl ketene acetals, chiral reaction with aldehydes

Silyl ketene acetals, chiral reaction with imines

Silyl ketene acetals, reaction with fluoropropionaldehydes

Sodium azide, reaction with allylic acetates

Sodium hydrogen carbonate reaction with acetic acid

Stannanes reactions with acetals

Subject reaction with acetals

Sulfoxides reaction with acetic anhydride

Thiazoline-2-thione, reaction with acetate

Thiophene-2-thiol, reaction with acetate

Titanium tetrachloride allylsilane reactions with acetals

Trimethylsilyl triflate allylsilane reaction with acetals

Trityl perchlorate allylsilane reaction with acetals

Vinyl acetate reaction with chlorosulfonyl isocyanate

Vinyl acetate reaction with methyl lithium

Vinyl acetate, reaction with

Vinylidene chloride, reaction with sodium 2-methoxyethoxide to yield ketene di acetal

Wittig reaction with ethyl acetate

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