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Acetic anhydride, reaction with

Acetals are readily formed with alcohols and cycHc acetals with 1,2 and 1,3-diols (19). Furfural reacts with poly(vinyl alcohol) under acid catalysis to effect acetalization of the hydroxyl groups (20,21). Reaction with acetic anhydride under appropriate conditions gives the acylal, furfuryUdene diacetate... [Pg.77]

Conversion of aniline to acetanilide [103-84-4] by reaction with acetic anhydride, is a convenient method for protecting the amino group. The acetyl group can later be removed by acid or base hydrolysis. [Pg.229]

Uses ndReactions. Linalool can be estetified to linalyl acetate by reaction with acetic anhydride. Linalyl acetate [115-95-7] has a floral-fmity odor, reminiscent of bergamot and lavender. The price of the acetate in 1995 was 14.30/kg (45). Linalool is subject to dehydration and to isomerization to nerol and geraniol during the esterification. However, if the acetic acid formed during the esterification is removed in a distillation column, the isomerization can be minimized and good yields of the acetate obtained (130). [Pg.421]

Although all four tocopherols have been synthesized as their all-rac forms, the commercially significant form of tocopherol is i7//-n7i a-tocopheryl acetate. The commercial processes ia use are based on the work reported by several groups ia 1938 (15—17). These processes utilize a Friedel-Crafts-type condensation of 2,3,5-trimethylhydroquinone with either phytol (16), a phytyl haUde (7,16,17), or phytadiene (7). The principal synthesis (Fig. 3) ia current commercial use iavolves condensation of 2,3,5-trimethylhydroquiQone (13) with synthetic isophytol (14) ia an iaert solvent, such as benzene or hexane, with an acid catalyst, such as ziac chloride, boron trifluoride, or orthoboric acid/oxaUc acid (7,8,18) to give the all-rac-acetate ester (15b) by reaction with acetic anhydride. Purification of tocopheryl acetate is readily accompHshed by high vacuum molecular distillation and rectification (<1 mm Hg) to achieve the required USP standard. [Pg.146]

Acetals. Acetal resins (qv) are polymers of formaldehyde and are usually called polyoxymethylene [9002-81-7]. Acetal homopolymer was developed at Du Pont (8). The commercial development of acetal resins required a pure monomer. The monomer is rigorously purified to remove water, formic acid, metals, and methanol, which act as chain-transfer or reaction-terminating agents. The purified formaldehyde is polymerized to form the acetal homopolymer the polymer end groups are stabilized by reaction with acetic anhydride to form acetate end groups (9). [Pg.36]

Pyrrole and alkylpyrroles can be acylated by heating with acid anhydrides at temperatures above 100 °C. Pyrrole itself gives a mixture of 2-acetyl- and 2,5-diacetyl-pyrrole on heating with acetic anhydride at 150-200 °C. iV-Acylpyrroles are obtained by reaction of the alkali-metal salts of pyrrole with an acyl halide. AC-Acetylimidazole efficiently acetylates pyrrole on nitrogen (65CI(L)1426). Pyrrole-2-carbaldehyde is acetylated on nitrogen in 80% yield by reaction with acetic anhydride in methylene chloride and in the presence of triethylamine and 4-dimethylaminopyridine (80CB2036). [Pg.51]

Enol acetates are readily prepared from saturated ketones by reaction with acetic anhydride alone or diluted, in the presence of acetyl chloride ... [Pg.390]

The dimethyl acetal (94) is readily prepared from the 22-aldehyde (93) by direct reaction with methanol in the presence of hydrogen chloride. Ena-mines (95) are formed without a catalyst even with the poorly reactive piperidine and morpholine.Enol acetates (96) are prepared by refluxing with acetic anhydride-sodium acetate or by exchange with isopropenyl acetate in pyridine.Reaction with acetic anhydride catalyzed by boron trifluoride-etherate or perchloric acid gives the aldehyde diacetate. [Pg.401]

By reaction of 3-thienyllithium with magnesium bromide, the Grignard reagent, free from entrainment Grignard reagent, was obtained,- which is useful for the preparation of 3-acetothiophene by reaction with acetic anhydride at —70 0 and for the preparation of 3-t-butoxythiophene through reaction with t-butyl perbenzoate. It is the opinion of the present author that most 3-substituted thiophenes are prepared more conveniently from 3-thienyllithium than from 3-thenyl bromide. The latter method, however, is superior if the introduction of the 3-thenyl group is desired. [Pg.43]

Koenigs-Knorr reaction of, 990 molecular model of, 119, 126, 985 mutarotation of, 985-986 pentnacetyl ester of, 988 pentamethyl ether of, 988 pyranose form of, 984-985 pyruvate from. 1143-1150 reaction with acetic anhydride, 988 reaction with ATP, 1129 reaction with iodomethane, 988 sweetness of. 1005 Williamson ether synthesis with. 988... [Pg.1299]

Fischer projections and, 977-978 glycosides of, 989-990 hemiacetals of, 984-986 osazones from, 1013 oxidation of, 992-994 phosphorylation of, 991 reaction with acetic anhydride, 988... [Pg.1307]

N-Nitroso N phenylglycine, 46, 96 reaction with acetic anhydride to yield 3 phenylsydnone, 46, 96 Nitrosyl chloride, addition to bicyclo-[2 2 ljhepta 2,5 diene, 46, 75 2,4-Nonanedione, 47, 92 Nonane, 1,1,3 trichloro-, 46,104 Nortricyclanol, 46, 74 oxidation by chromic acid, 46, 78 Nortricyclanone, 46, 77 Nortncj clyl acetate 46, 74 frombicyclo[2 2 ljhepta 2,5 dieneand acetic acid, 46, 74 saponification of, 46, 75... [Pg.134]

The tetrahydrotrithiepin 1 is oxidized to an 5-oxide of undetermined structure, which undergoes a Pummerer reaction with acetic anhydride to give 1,2,5-trithiepin (2) in low yield.432... [Pg.451]

Cyclization of 148 with l,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and a subsequent elimination reaction with acetic anhydride and pyridine furnished compound 149. °- Compound 149 was found to be an important key compound for the following synthesis of carba-sugars of the a-L-altro, fi-D-gluco, P-h-allo, and a-D manno modifications. [Pg.45]

Ether cleavage can also be effected by reaction with acetic anhydride and Lewis acids such as BF3, FeCl3, and MgBr2.97 Mechanistic investigations point to acylium ions generated from the anhydride and Lewis acid as the reactive electrophile. [Pg.240]

Bismuth(III) triflate is also a powerful acylation catalyst that catalyzes reactions with acetic anhydride and other less reactive anhydrides such as benzoic and pivalic anhydrides.113 Good results are achieved with tertiary and hindered secondary alcohols, as well as with alcohols containing acid- and base-sensitive functional groups. [Pg.246]

The Michael addition of lithium enolates to nitroalkenes followed by reaction with acetic anhydride gives acetic nitronic anhydrides, which are good precursors for 1,4-diketones, pyrroles, and pyrrolidines (Eq. 10.73).113... [Pg.349]

Symmetrical piperazines 364 have been obtained from the corresponding 4,5-dihydrazinofurazano[3,4- ]pyraz ne 363 in good yield on reaction with acetic anhydride in the presence of a Lewis acid (Equation 98) <1999CHE499>. When formaldehyde was used, the yield was slightly reduced at 76%. Acid chlorides can also be used in this reaction although the yield drops to 23% when trichloroacetyl chloride is used. [Pg.751]


See other pages where Acetic anhydride, reaction with is mentioned: [Pg.241]    [Pg.3]    [Pg.3]    [Pg.6]    [Pg.6]    [Pg.11]    [Pg.123]    [Pg.211]    [Pg.611]    [Pg.676]    [Pg.735]    [Pg.44]    [Pg.52]    [Pg.650]    [Pg.680]    [Pg.768]    [Pg.769]    [Pg.790]    [Pg.808]    [Pg.809]    [Pg.831]    [Pg.257]    [Pg.32]    [Pg.111]    [Pg.139]    [Pg.712]    [Pg.767]   
See also in sourсe #XX -- [ Pg.1005 , Pg.1017 ]




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2- Picoline reaction with acetic anhydride

Acetals reactions with

Acetates reactions with

Acetic acid anhydride, reaction with radical

Acetic anhydride Friedel-Crafts reaction with

Acetic anhydride reaction with amines

Acetic anhydride reaction with benzaldehyde

Acetic anhydride reaction with ethylene glycol

Acetic anhydride reaction with water

Acetic anhydride reactions

Acetic anhydride with acetals

Acetic anhydride, electrostatic reaction with alcohols

Acetic anhydride, electrostatic reaction with amines

Acetic anhydride, reaction with amino

Acetic anhydride, reaction with ethanol

Alkenes reaction with acetic anhydride

Anhydrides reactions

Cellulose reaction with acetic anhydride

Monosaccharide reaction with acetic anhydride

Pyridine 1-oxide reaction with acetic anhydride

Reaction with anhydrides

Reaction with nitric acid-acetic anhydride

Sulfoxides reaction with acetic anhydride

With acetic anhydride

With anhydrides

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