Viscosity grading

Viscosity Glassifications. The general ISO iatemational viscosity classification system for iadustrial oils is given ia Table 4 from ASTM D2422 (American National Standard Z11.232). For high speed machines, ISO viscosity-grade 32 turbiae and hydrauHc oils are a common choice. ISO grades 68 and 100 are appHed for more load capacity ia slower speed machines where power loss and temperature rise are less of a question. 

SAE Viscosity grade Viscosity, mPa-s(=cP) at °C Borderline pumping temperature, °C Minimum Maximum... 

Oil viscosity grades have also been developed with suitable additives for use in a variety of specific appHcations in two-cycle engines, refrigeration and air conditioning, oil mist lubricators, low outdoor temperatures, instmments, and office machines as partially reflected in Table 3. Equipment manufacturers and lubricant suppHers provide recommendations for individual cases. 

Depending on their stmctural type, PEPE oils are stable up to 300—400°C ia air. Pure oxygen ia a test bomb at 13 MPa (1886 psi) at temperatures up to 400°C was tolerated with no ignition (43). Densities at 20°C vary from 1.82 to 1.89 g/mL, and viscosities from 10 to 1600 mm /s. The pour poiat for low temperature operation usually ranges from —30 to —70° C, and the viscosity iadex varies from about 50 for low viscosity grades up to 150 for more viscous oils and considerably higher for fully linear polymers (43). 

Sodium carboxymethyl cellulose [9004-32-4] (CMC) and hydroxyethyl cellulose [9004-62-0] (HEC) are the ceUulosics most widely used in drilling fluids (43). CMC is manufactured by carboxymethylation of cellulose which changes the water-insoluble cellulose into the water-soluble CMC (44). Hydroxyethyl cellulose and carboxymethyl hydroxyethyl cellulose (CMHEC) are made by a similar process. The viscosity grade of the material is determined by the degree of substitution and the molecular weight of the finished product. 

The hquid cutback asphalts are prepared in a number of viscosity grades, ranging generally from 70 to 6000. The grade number indicates the viscosity at 60°C. 

If straight-mn asphalts are reduced to a hardness below 300 penetration (30 mm), they are termed asphalt cements. For hot-mix paving, either the AC-10 viscosity grade or the next harder AC-20 grade is commonly specified. 

Commercially, HEC is available in a wide range of viscosity grades, ranging from greater than 500 mPa-s(=cP) at 1% soHds to less than 100 mPa-s(=cP) at 5% total soHds. Because HEC is nonionic, it can be dissolved in many salt solutions that do not dissolve other water-soluble polymers. It is soluble in most 10% salt solutions and in many 50% (or saturated) salt solutions such as sodium chloride and aluminum nitrate. As a rule, the lower substitution grades are more salt-tolerant. 

HPC is available in a number of viscosity grades, ranging from about 3000 mPa-s(=cP) at 1% total soHds in water to 150 mPa-s(=cP) at 10% total sohds. HPC solutions are pseudoplastic and exceptionally smooth, exhibiting Htde or no stmcture or thixotropy. The viscosity of water solutions is not affected by changes in pH over the range of 2 to 11. Viscosities decrease as temperature is increased. HPC precipitates from water at temperatures between 40 and 45°C. Dissolved salts and other compounds can profoundly influence the precipitation temperature (50,81). 

Molecular weights for fully hydrolyzed and partially hydrolyzed grades of PVA (expressed in terms of 4% solution viscosity) from aqueous SEC-MALLS are summarized in Table 20.6. M values range from less than 20,000 Da for a 3 centipoise (cP) viscosity grade to over 230,000 Da for a super-high viscosity... 

Cotton linters and viscose grade wood pulp were partially xanthated under different conditions to study the effect of the degree of substitution on the acrylamide grafting of these pulps. Sodium hydroxide solutions of 2%, 4%, and 6% were used and the vapor phase xantha-tion process was applied for 0.5, 1.0, 1.5, and 2.0 h for... 

Cotton linters and viscose grade wood pulp were grafted with acrylamide using the xanthate method. The effects of monomer concentration, reaction time, hydrogen peroxide concentration, reaction temperature, and liquor ratio on the grafting process were studied. Optimum conditions for the grafting reaction were established [26]. 

Cotton linters and viscose grade wood pulp were partially acetylated and carboxymethylated. The samples were grafted under the same conditions with acrylamide. Grafting yield and efficiency depend on several factors, such as the kind of pulp, chemical and physical structure, type of the introduced substituent, and degree of substitution (DS). 

ISO viscosity grade Mid-point kinematic viscosity Kinematic viscosity limits cSt at 40° C(104°f) min. max. ... 

Class Types of lubricant Viscosity grade no. BS 4231) Typical application Detailed application Remarks... 

Physical constraints the processing times and the compatibility of tasks with different types of equipment. Colour, viscosity, grade, or aroma can be important factors that can affect the sequence of operations or campaigns and often are not taken into account in... 

Methylcellulose MC Cold water, GI fluids, organic solvents Useful polymer for aqueous films low-viscosity grade best... 

Hydroxypropylmethylcellulose HPMC Cold water, GI fluids, methanol/methylene chloride, alcohol/fluorohydrocarbons Excellent film former and readily soluble throughout GIT low-viscosity grades to be preferred, e.g., Methocel HG (Dow)... 

NR requires a certain degree of mastication (reduction in molecular weight) to facilitate processing, although the advent of constant viscosity grades, and oil extended grades has substantially reduced the need for mastication. 

Isoviolanthrone dyes, 9 331 ISO viscosity grades, 15 238 Isoxaben, 13 323 Isoxsuprine, 5 115... 

The chlorination of low molecular weight natural rubber from Guayule (Parthenium Argentatum Grey) has been accomplished. The structure of the chlorinated product is consistent with that of chlorinated Hevea rubber. The use of Azo-bis-isobutyronitrile was as a catalyst resulted in increased chlorine content with a concomitant reduction in molecular weight, thereby allowing the preparation of lower viscosity grades of chlorinated rubber. 

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