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Vinyl alcohols esters

Carbon Cha.in Backbone Polymers. These polymers may be represented by (4) and considered derivatives of polyethylene, where n is the degree of polymeriza tion and R is (an alkyl group or) a functional group hydrogen (polyethylene), methyl (polypropylene), carboxyl (poly(acryhc acid)), chlorine (poly(vinyl chloride)), phenyl (polystyrene) hydroxyl (poly(vinyl alcohol)), ester (poly(vinyl acetate)), nitrile (polyacrylonitrile), vinyl (polybutadiene), etc. The functional groups and the molecular weight of the polymers, control thek properties which vary in hydrophobicity, solubiUty characteristics, glass-transition temperature, and crystallinity. [Pg.478]

Substitution at the Carbon—Chlorine Bond. Vinyl chloride is generally considered inert to nucleophilic replacement compared to other alkyl halides. However, the chlorine atom can be exchanged under nucleophilic conditions in the presence of palladium [7440-05-3] Pd, and certain other metal chlorides and salts. Vinyl alcoholates, esters, and ethers can be readily produced from these reactions. [Pg.414]

Polyphosphazenes with simple alkyl and aryl substituents directly attached to the backbone by P-C linkages can be prepared by the condensation polymerization of N-silylphosphoranimine precursors. These simple polymers can then be converted to a variety of functionalized polyphosphazenes by derivatization reactions. In this paper, the synthesis and characterization of some derivatives of poly(methylphenyl-phosphazene), [Me(Ph)P=N]and the copolymer, [Me(Ph)P=N]j [Me2P=N)y, are discussed. These polymers include grafted copolymers, water soluble carboxylated polymers, and polymers with silyl, vinyl, alcohol, ester, ferrocene, phosphine, thiophene, and/or fluoroalkyl groups. [Pg.333]

Prepared generally by ester interchange from polyvinylacelate (ethanoate) using methanol and base also formed by hydrolysis of the acetate by NaOH and water. The properties of the poly(vinyl alcohol) depend upon the structure of the original polyvinyl acetate. Forms copolymers. Used as a size in the textile industry, in aqueous adhesives, in the production of polyvinyl acetates (e.g. butynal) for safety glasses. U.S. production 1980... [Pg.323]

Almost all synthetic binders are prepared by an emulsion polymerization process and are suppHed as latexes which consist of 48—52 wt % polymer dispersed in water (101). The largest-volume binder is styrene—butadiene copolymer [9003-55-8] (SBR) latex. Most SBRlatexes are carboxylated, ie, they contain copolymerized acidic monomers. Other latex binders are based on poly(vinyl acetate) [9003-20-7] and on polymers of acrylate esters. Poly(vinyl alcohol) is a water-soluble, synthetic biader which is prepared by the hydrolysis of poly(viayl acetate) (see Latex technology Vinyl polymers). [Pg.22]

Small amounts of TAIC together with DAP have been used to cure unsaturated polyesters in glass-reinforced thermo sets (131). It has been used with polyfunctional methacrylate esters in anaerobic adhesives (132). TAIC and vinyl acetate are copolymerized in aqueous suspension, and vinyl alcohol copolymer gels are made from the products (133). Electron cure of poly(ethylene terephthalate) moldings containing TAIC improves heat resistance and transparency (134). [Pg.88]

Hydrolysis of vinyl acetate is catalyzed by acidic and basic catalysts to form acetic acid and vinyl alcohol which rapidly tautomerizes to acetaldehyde. This rate of hydrolysis of vinyl acetate is 1000 times that of its saturated analogue, ethyl acetate, ia alkaline media (15). The rate of hydrolysis is minimal at pH 4.44 (16). Other chemical reactions which vinyl acetate may undergo are addition across the double bond, transesterification to other vinyl esters, and oxidation (15—21). [Pg.459]

Solvent Resistance. Poly(vinyl alcohol) is virtually unaffected by hydrocarbons, chlorinated hydrocarbons, carboxyhc acid esters, greases, and animal or vegetable oils. Resistance to organic solvents increases with increasing hydrolysis. This resistance has promoted the use of PVA in the manufacture of gloves for use when handling organic solvents (73). [Pg.479]

Inorganic Esters. Boric acid and borax form cycHc esters with poly(vinyl alcohol) (85—100). The reaction is markedly sensitive to pH, boric acid concentration, and the cation-to-boron ratio. An insoluble gel is formed at pH above 4.5—5.0 ... [Pg.480]

Org inic Esters. An unlimited number of organic esters can be prepared by reactions of poly(vinyl alcohol) employing standard synthesis (82,84). Chloroformate esters react with poly(vinyl alcohol) to yield poly(vinyl carbonates) (118). [Pg.481]

Urea and poly(vinyl alcohol) form a polymeric carbamate ester (123—126) ... [Pg.481]

Reaction between poly(vinyl alcohol) and isocyanates yields substituted carbamate esters (127—134) ... [Pg.481]

Poly(vinyl alcohol) can be derived from the hydrolysis of a variety of poly(vinyl esters), such as poly(vinyl acetate), poly(vinyl formate), and poly(vinyl ben2oate), and of poly(vinyl ethers). However, all commercially produced poly(vinyl alcohol) is manufactured by the hydrolysis of poly(vinyl acetate). The manufacturing process can be viewed as one segment that deals with the polymeri2ation of vinyl acetate and another that handles the hydrolysis of poly(vinyl acetate) to poly(vinyl alcohol). [Pg.482]

Chemistry. Poly(vinyl acetate) can be converted to poly(vinyl alcohol) by transesterification, hydrolysis, or aminolysis. Industrially, the most important reaction is that of transesterification, where a small amount of acid or base is added in catalytic amounts to promote the ester exchange. [Pg.484]

Commercial Hydrolysis Process. The process of converting poly(vinyl acetate) to poly(vinyl alcohol) on a commercial scale is compHcated on account of the significant physical changes that accompany the conversion. The viscosity of the poly(vinyl acetate) solution increases rapidly as the conversion proceeds, because the resulting poly(vinyl alcohol) is insoluble in the most common solvents used for the polymeri2ation of vinyl acetate. The outcome is the formation of a gel swollen with the resulting acetic acid ester and the alcohol used to effect the transesterification. [Pg.484]

Barrier Layers. Depending on composition, barrier layers can function simply as spatial separators or they can provide specified time delays by swelling at controlled rates or undergoing reactions such as hydrolysis or dissolution. Suitable barrier materials include cellulose esters and water-permeable polymers such as gelatin and poly(vinyl alcohol) (see Barrier polymers). [Pg.496]

In contrast to the hydrolysis of prochiral esters performed in aqueous solutions, the enzymatic acylation of prochiral diols is usually carried out in an inert organic solvent such as hexane, ether, toluene, or ethyl acetate. In order to increase the reaction rate and the degree of conversion, activated esters such as vinyl carboxylates are often used as acylating agents. The vinyl alcohol formed as a result of transesterification tautomerizes to acetaldehyde, making the reaction practically irreversible. The presence of a bulky substituent in the 2-position helps the enzyme to discriminate between enantiotopic faces as a result the enzymatic acylation of prochiral 2-benzoxy-l,3-propanediol (34) proceeds with excellent selectivity (ee > 96%) (49). In the case of the 2-methyl substituted diol (33) the selectivity is only moderate (50). [Pg.336]

The use of a catalytic quantity of alkah equivalent to only a small fraction of the acetate has the advantage that contamination of the poly(vinyl alcohol) with salts, which are difficult to remove, is minimized. A variant of the process is the use of a mixture of alcohol with the acetate ester produced by the alcoholysis as the alcoholyzing agent. This provides a means of controlling the completeness of removal of the acetate groups from the poly(vinyl acetate) (111). [Pg.383]

Transesterification has a number of important commercial uses. Methyl esters of fatty acids are produced from fats and oils. Transesterification is also the basis of recycling technology to break up poly(ethylene terephthalate) [25038-59-9] to monomer for reuse (29) (see Recycling, plastics). Because vinyl alcohol does not exist, poly(vinyl alcohol) [9002-89-5] is produced commercially by base-cataly2ed alcoholysis of poly(vinyl acetate) [9003-20-7] (see Vinyl polymers). An industrial example of acidolysis is the reaction of poly(vinyl acetate) with butyric acid to form poly(vinyl butyrate) [24991-31-9]. [Pg.388]

Poly(vinyl alcohol) is thus prepared by alcoholysis of a poly(vinyl ester) and in practice poly(vinyl acetate) is used (Figure 14.5). [Pg.389]

Poly(vinyl carbazole) is insoluble in alcohols, esters, ethers, ketones, carbon tetrachloride, aliphatic hydrocarbons and castor oil. It is swollen or dissolved by such agents as aromatic and chlorinated hydrocarbons and tetrahydrofuran. [Pg.473]

Enols of simple ketones can be generated in high concentration as metastable species by special techniques. Vinyl alcohol, the enol of acetaldehyde, can be generated by very careful hydrolysis of any of several ortho ester derivatives in which the group RC02 is acetate acid or a chlorinated acetate acid. ... [Pg.430]

The PVF is made by acidic reaction between poly(vinyl alcohol) (PVA) and formaldehyde. The poly(vinyl alcohol) is, in turn, made by hydrolysis of poly(vinyl acetate) or transesterification of poly(vinyl acetate). Thus, residual alcohol and ester functionality is usually present. Cure reportedly occurs through reaction of phenolic polymer hydroxyls with the residual hydroxyls of the PVA [199]. The ester residues are observed to reduce bond strength in PVF-based systems [199]. This does not necessarily extend to PVF-P adhesives. PVF is stable in strong alkali, so participation of the acetals in curing is probably unimportant in most situations involving resoles. PVF is physically compatible with many phenolic resins. [Pg.928]

Poly(vinyl alcohol) Polymer derived from the hydrolysis of polyvinyl esters. [Pg.157]

Acetaldehyde is formed during the degradation of PET. Vinyl ester endgroups formed during thermal degradation of PET liberate vinyl alcohol on transesterification with hydroxyethylterephthalate polymeric endgroups (Fig. 10.6). The vinyl alcohol tautomerizes to form acetaldehyde, which can affect the taste of foods in PET food contact applications.1... [Pg.539]

Ester alcoholysis (transesterification) in organic media is an equilibrium reaction and must be shifted in the desired direction. For example, Bornscheuer and coworkers [61] reported the resolution of ibuprofen vinyl ester by transesterification tvith n-hexanol in the presence of CAL-B. The vinyl alcohol generated during the reaction tautomerizes to acetaldehyde, thus making the reaction irreversible, as illustrated in Figure 6.14. [Pg.140]

Frequently, when the enol content is high, both forms can be isolated. The pure keto form of acetoacetic ester melts at — 39°C, while the enol is a liquid even at — 78°C. Each can be kept at room temperature for days if catalysts such as acids or bases are rigorously excluded.Even the simplest enol, vinyl alcohol (CH2= CHOH), has been prepared in the gas phase at room temperature, where it has a half-life of 30min. " The enol Me2C=CCHOH is indefinitely stable in the solid state at —78°C and has a half-life of 24h in the liquid state at 25°C. When both forms cannot be isolated, the extent of enolization is often measured by NMR. [Pg.75]

An irreversible procedure for the lipase-catalyzed acylation using vinyl esters as acylating agent has been developed, where a leaving group of vinyl alcohol tautomerizes to acetaldehyde. In these cases, the reaction with the vinyl esters proceeds much faster to produce the desired compounds in higher yields, in comparison with the alkyl esters. [Pg.214]


See other pages where Vinyl alcohols esters is mentioned: [Pg.1683]    [Pg.380]    [Pg.1683]    [Pg.380]    [Pg.420]    [Pg.552]    [Pg.295]    [Pg.480]    [Pg.481]    [Pg.454]    [Pg.463]    [Pg.484]    [Pg.502]    [Pg.379]    [Pg.104]    [Pg.152]    [Pg.383]    [Pg.394]    [Pg.83]    [Pg.388]    [Pg.135]   
See also in sourсe #XX -- [ Pg.55 , Pg.207 , Pg.208 , Pg.213 ]




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Esters alcohols

Esters vinyl

Vinyl alcohol

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