Barrier vapor

Hard baked goods such as cookies and crackers have a relatively low water and high fat content. Water can be absorbed, and the product loses its desirable texture and becomes subject to Hpid rancidity. Packagiag for cookies and crackers includes polyolefin-coextmsion film pouches within paperboard carton sheUs, and polystyrene trays overwrapped with polyethylene or oriented polypropylene film. Soft cookies are packaged in high water-vapor-barrier laminations containing aluminum foil. 

OPP producers have expanded the core, creating a foam stmcture with lower density, greater opacity, and a stiffer, more paper-Hke feel. Vacuum metallisation increases opacity and water-vapor barrier properties. 

Oriented polypropylene film has exceUent water-vapor barrier but poor gas barrier properties exceUent clarity, or opacity in newer forms and good heat-seal properties in packagiag appHcations. 

Polyester. Poly(ethylene terephthalate) [25038-59-9] (PET) polyester film has intermediate gas- and water- vapor barrier properties, very high tensile and impact strengths, and high temperature resistance (see Polyesters, thermoplastic). AppHcations include use as an outer web in laminations to protect aluminum foil. It is coated with PVDC to function as the flat or sealing web for vacuum/gas flush packaged processed meat, cheese, or fresh pasta. 

Ethylene vinyl acetate copolymer (EVA) forms a soft, tacky film with good water-vapor barrier but very poor gas-barrier properties. It is widely used as a low temperature initiation and broad-range, heat-sealing medium. The film also serves for lamination to other substrates for heat-sealing purposes. 

Polyacrylonitrile (PAN) films have outstanding oxygen and CO2 barrier properties, but only modest water-vapor barrier properties. They are for processed-meat and fresh pasta packaging laminations where an oxygen barrier is required for vacuum or gas flush packaging. 

Thermoform able sheet may be mono- or multilayer with the latter produced by lamination or coextmsion. Multilayers are employed to incorporate high oxygen-barrier materials between stmctural or high water-vapor barrier plastics. Both ethylene vinyl alcohol copolymers and poly(vinyhdene chloride) (less often) are used as high oxygen-barrier interior layers with polystyrene or polypropylene as the stmctural layers, and polyolefin on the exterior for sealing. 

Paraffin wax vapor barriers are used in water rinse removers that can disperse the wax without coating the substrate. In soak tank applications, water is sometimes doated on top of an ad-solvent, neutral pH, nonwater rinse remover to prevent evaporation. Flotation devices that cover the exposed surface area may be used with other formulas. 

In petroleum and oxygenate finish removers, the major ingredient is normally acetone, methyl ethyl ketone [78-93-3], or toluene. Cosolvents include methanol, / -butanol [71-36-3], j -butyl alcohol [78-92-2], or xylene [1330-20-7]. Sodium hydroxide or amines are used to activate the remover. Paraffin wax is used as an evaporation retarder though its effectiveness is limited because it is highly soluble in the petroleum solvents. CeUulose thickeners are sometimes added to liquid formulas to assist in pulling the paraffin wax from the liquid to form a vapor barrier or to make a thick formula. Corrosion inhibitors are added to stabili2e tbe formula for packaging (qv). 

Emerson Gumming, Inc. eventuaUy bought the rights to the Sohio process and produced a variety of microspheres. Union Carbide was Hcensed to produce the phenoHc microspheres offered under the name PhenoHc MicrobaUoons (Table 16). When PhenoHc MicrobaUoons are introduced into a cmde-oU storage tank, they form a fluid seal that rises and faUs with the level of the oU. A continuous vapor-barrier seal is formed, which reduces evaporational losses up to 90%. Tests have been conducted under various mechanical and weather conditions and with cmde oUs of varying vapor pressure. 

First ply or as vapor barrier under insulation. Coated on both sides with asphalt and surfaced on top side with fine mineral granules (2,9). 

The principal use of LDPE and LLDPE in building products is as a film water barrier under below-grade doors as a wall vapor barrier, though PVC is typically preferred and as temporary enclosure film during constmction. The film is made either by extmding a thin-waHed tube, which may be sHt or wound up direcdy, or by extmsion through a slot die and cast direcdy on to a cold roU, cooled, then wound up. The former method is more widely used. A much smaller use for low density polyethylene is in piping. 

Corrosion under insulation is also a concern, particularly in refrigeration systems. The specification of the insulation system needs to include painting, vapor barriers, and external metal jackets (16). 

Tanks with contents at lower than atmospheric temperature may require insulation to minimize heat absorption. The insulation must have a vapor barrier at the outside to prevent condensation of atmospheric moisture from reducing its effectiveness. An insulation not damaged by moisture is preferable. The insulation techniques presently used for refrigerated systems can be apphed (see subsection Fow-Temperature and Cryogenic Storage ). 

Duct board A rigid board of insulation material with one or both sides faced with a finishing material. The outer face is normally a vapor barrier and air bar rier. 

A vapor barrier should be applied to the outer surface of the insulation on cold piping. 

If aluminum sheet metal is used for this purpose, insulation should be protected by a vapor barrier. 

This is also based on watertight concrete construction but accepts that some seepage may occur through the external concrete wall. The water is kept away from a separate inner-skin wall by an intervening drained cavity. An internal vapor barrier may be applied to the inner-skin wall to limit humidity, but the cavity may then require ventilation to prevent condensation. 

The effectiveness of a vapor barrier can be rated in a term such as perms. An effective vapor barrier in buildings should have a rating no greater than, say, 0.2 perm. A rating of one perm means that one ft2 of the barrier is penetrated by one gram of water vapor per hour under a pressure differential of one in. of mercury. One in. of mercury equals virtually 0.5 psi one gram is one seven-thousandth of a pound. 

Geomembrane These liners chiefly provide impermeable barriers. They can be characterized as (1) solid waste containment hazardous landfill, landfill capping, and sanitary landfill (2) liquid containment canal, chemical/brine pond, earthen dam, fish farm, river/coastal bank, waste-water, and recreation (3) mining, leach pad and tailing ponds and (4) specialties floating reservoir caps, secondary containment, tunnel, erosion, vapor barrier, and water purification. Plastics used include medium to very low density PE, PVC, and chlorosulfonated PE (CSPE). (The Romans used in their land and road constructions what we call geomembrane.)... 

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