Vanadium biology

Vanadate, dioxybis(oxamato)-bond-length ratios, 1,57 Vanadate, heptacyano-potassium salt structure, I, 72 Vanadate, hexafluoro-dipotassium salt history, I, 21 potassium salt history, 1,21 tripotassium salt history, 1,21 Vanadate, pentachloro-stereochemistry, 1,40 Vanadate, pentafluorooxy-stereochemistry, I, 50 Vanadates biochemistry, 3,456 calcium/magnesium ATPase inhibition, 6, 567 competition with phosphates physiology, 6,665 protonation, 3,1026 sodium pump, 6, 557 in uranium purification from ore, 6, 899 Vanadates, hexafluoro-, 3. 482,531 Vanadates, oxoperoxo-, 3,501 Vanadates, pentacarbonyl-, 3, 457 Vanadium biology, 6,665 determination, 1. 548 extraction... 

Flan, C. and Liu, T. 2009. A comparison of hypoglycemic activity of three species of basidiomy-cetes rich in vanadium. Biological trace element research, 127(2), 177-82. 

Trace amounts of vanadium have been found in meteorites and seawater, and it has been identified in the spectmm of many stars including the earth s sun. The occurrence of vanadium in oak and beech trees and some forms of aquatic sea life indicates its biological importance. 

Tin plate, thickness of tin coating on, determination by x-ray spectrography, 148, 149, 157, 158 Tissues, determination of dry weight by absorptiometry, 297-300 Tissue sections, biological, determination of mineral elements in, 301-305 Titanium, as internal standard in vanadium determination, 188 determination by x-ray emission spectrography, 222, 329 trace analysis by x-ray emission spectrography, 163, 225-229 Topaz, as analyzing crystal, 116-118, 220, 318-327 Total reflection, 112, 117... 

Vanadium a versatile biochemical effector with an elusive biological function. D. W. Boyd and K. Kustin, Adv. Inorg. Biochem., 1984, 6, 311 (291). 

Sjbberg B-M (1997) Ribonucleotide Reductases - A Group of Enzymes with Different Metallosites and a Similar Reaction Mechanism. 88 139-174 Slebodnick C, Hamstra BJ, Pecoraro VL (1997) Modeling the Biological Chemistry of Vanadium Structural and Reactivity Studies Elucidating Biological Function. 89 51-108 Smit HHA, see Thiel RC (1993) 81 1-40... 

Byrne AR, and Kucera J (1991) Radiochemical neutron activation analysis of traces of vanadium in biological samples A comparison of prior dry ashing with post-irradiation wet ashing. Fresenius f Anal Chem 340 48-52. 

Byrne AR, and Versieck J (1990) Vanadium determination at the ultratrace level in biological reference materials and serum by radiochemical neutron activation analysis. Biol Trace Elem Res 27 529-540. 

Kucera J, and Soukal L (1998) Low uncertainty determination of manganese and vanadium in environmental and biological reference materials by instrumental neutron activation analysis. Fresenius J Anal Chem 360 415-418. 

Orvig, C. Thompson, K. H. Battell, M. McNeill, J. H. Metal Ions in Biological Systems Vanadium and its Role in Life In Metal Ions in Biological Systems, Sigel, H. Sigel, A. Eds. Marcel Dekker New York, 1995 Vol. 31, p 575. 

The organometallic chemistry of vanadium has been surveyed in COMC (1982) and COMC (1995).152 153 The chemical and biological importance of vanadium was reviewed in a dedicated edition of Coordination Chemistry Reviews.1 4 Relevant synthetic aspects of vanadium chemistry have also been reviewed,155-158 including early report by Hirao et al. on formation of ketones from organovanadium compounds and acid chlorides.159... 

Mixed liquor volatile suspended solids (MLVSS), in biological waste treatment, 25 829-830 Mixed-metal alkoxides, titanium-vanadium, 25 100... 

Vanadium, as V0S04, has been found to interfere with siderophore-mediated iron transport in bacteria and plants. This seems to imply that vanadium can be transported by siderophores, and a number of studies focussing on applications of hydroxamate V-complexes in biology have been initiated. 

Crans, D.C., Smee, J J., Gaidamauskas, E. and Yang, L. (2004) The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds, Chem. Rev., 104, 849-902. 

The lower oxidation states are stabilized by soft ligands e.g. CO (Prob. 3). The aquated vanadium ions represent an interesting series of oxidation states. They are all stable with respect to disproportionation and labile towards substitution. They undergo a number of redox reactions with one another, all of which have been studied kinetically. Many of the reactions are [H ]-dependent. There has been recent interest in the biological aspects of vanadium since the discovery that vanadate can mimic phosphate and act as a potent inhibitor (Prob. 4). 

Todaro A, Bronsato R, Buratti M, et al. 1991. Acute exposure to vanadium-containing dusts the health effects and biological monitoring in a group of workers employed in boiler maintenance. Med Lav 82(2) 142-147. 

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