Unsaturated polyesters structure

Boenig, Unsaturated Polyesters Structure and Properties , Elsevier, NY (1964) 11) I. 

Boenig H (1964) Unsaturated polyesters structure and properties. Elsevier, Amsterdam, pp 6-13... 

H. Boenig, Unsaturated Polyesters Structures and Properties, Elsevier Science, Inc., New York, 1964. 

Methacrylates possess many advantages, and alternatives to them are rarely seen in the marketplace. An early example using styrene in a structural adhesive has been reported [26]. The combination of styrene with unsaturated polyester is commonly used as a filler and bonding putty. 

The final properties depend not only on unstaturated polyester structure but also on a number of other parameters, such as the nature and proportion of unsaturated comonomer, the nature of the initiator, and the experimental conditions of the crosslinking reaction. Moreover, since polyester resins are mainly used as matrices for composite materials, the nature and amount of inorganic fillers and of reinforcing fibers are also of considerable importance. These aspects have been discussed in many reviews and book chapters and are beyond the scope of this chapter.7-9... 

The effect of incorporating p-hydroxybenzoic acid (I) into the structures of various unsaturated polyesters synthesised from polyethylene terephthalate (PET) waste depolymerised by glycolysis at three different diethylene glycol (DEG) ratios with Mn acetate as transesterification catalyst, was studied. Copolyesters of PET modified using various I mole ratios showed excellent mechanical and chemical properties because of their liquid crystalline behaviour. The oligoesters obtained from the twelve modified unsaturated polyesters (MUP) were reacted with I and maleic anhydride, with variation of the I ratio with a view to determining the effect on mechanical... 

The largest single use of maleic anhydride is in the preparation of unsaturated polyester resins. It is first esterihed with a polyalcohol (two or more hydroxyls) and then the double bond is copolymerized (crosslinked) with a vinyl monomer such as styrene to form a rigid structure. Such resins are usually reinforced with hberglass (FRP). Maleic anhydride is also used to make oil additives and agricultural chemicals. 

Unsaturated polyesters that are terminated by carboxylic acid groups at both ends of the chain after neutralization are efficient emulsifiers for lipophilic monomers [110] and thus act as self-emulsifying crosslinking agents in the ECP of these systems. Normal emulsions of EUP and comonomers have a white, milky appearance. With an appropriate structure and molar mass of the EUP and within a certain range of EUP/comonomer ratios, however, microemulsions are... 

Microgels which have been prepared in emulsions or microemulsion have a more compact structure than those obtained by polymerization in solution. For microemulsion copolymerization, preferentially self-emulsifying comonomers, such as unsaturated polyesters, are used as polymerizable surfactants, because no emulsifier must be removed after the reaction. By choosing suitable monomer combinations the composition, size and structure of microgels can be widely varied, thus adjusting these macromolecules to special applications. 

The unsaturated polyester-styrene combination, is used as the resin matrix, in Fibre-reinforced plastics (FRP) structures. These resins also find use as decorative coatings. 

Bisphenols is a broad term that includes many chemicals with the common chemical structure of two phenolic rings joined together by a bridging carbon. Bisphenol A is a monomer widely used in the manufacture of epoxy and phenolic resins, polycarbonates, polyacrylates and corrosion-resistant unsaturated polyester-styrene resins. It can be found in a diverse range of products, including the interior coatings of food cans and filters, water containers, dental composites and sealants. [4]. BPA and BP-5 were selected for testing by the whole... 

Unsaturated polyesters are low-molecular-weight fumarate esters containing various chemical structures designed for their specific cost and performance purposes. The two most important features of unsaturated polyesters are the fumarates, which provide the active sites for radical cross-linking with the diluent monomer and the random, low molecular weight, irregular nature of the rest of the molecule, which provide the necessary solubility in the diluent monomer. The preparation of the polyester thus requires the following considerations ... 

Since unsaturated polyester resins alone would have insufficient strength for structural application, reinforcements are used to enhance the physical strength of such resins. Typically, tensile strength, impact strength and stiffness are the physical properties of most interest. Reinforcements can be regular particulates, as in glass microspheres, irregular particulates, as in flakes, or fibers. 

Transportation applications include exterior automotive body components, non-appearance automotive parts, structural components, plus numerous truck, bus and rail car applications. Unsaturated polyester resins compete on the basis of weight reduction, corrosion resistance and parts consolidation. Thermoplastic resins, however, offer steep competition. 

New and promising composite pre-form technology which can be in situ molded with unsaturated polyester resins to further improve structure and performance have been demonstrated. 

It is known that increased char yield is usually associated with improved flammability behavior ( 1). This can be understood if one considers that the volatile flammable products can only diffuse with difficulty through the char, and that the thermal conductivity of a porous char layer is relatively poor (2). The structure of the polymer can contribute to the amount of char formed based on the character of the functional groups present and the nature of the backbone (2,3). Ritchie ( ) found that for a series of unsaturated polyesters and their copolymers, the temperatures at which carbon dioxide is eliminated was in the range of 280 to 345°C depending on the structure of the polyester. Aliphatic polyesters and their copolymers have less thermal... 

In this paper, the effect of temperature and concentration on corrosion behavior and corrosion mechanism of epoxy and unsaturated polyester resins in NaOH solution were studied, and were discussed by considering their chemical structures. Corrosion rate studies were also made by applying the concept of metallic corrosion. 

Figure 1. Chemical structures of epoxy and unsaturated polyester resins.

Results are presented of experiments undertaken by Gaiker in the manufacture of sandwich panels containing foam cores based on PETP recycled by a solid state polyaddition process developed by M G Ricerche. Panels were produced with glass fibre-reinforced unsaturated polyester and epoxy resin skins, and allthermoplastic panels with PE, PP, PS and glass fibre-reinforced PETP skins were also produced. EVA hot melt adhesives and thermoset adhesives were evaluated in bonding glass fibre-reinforced PETP skins to the foam cores. Data are presented for the mechanical properties of the structures studied. 

Unsaturated polyesters have been produced from reaction of ethylene glycol with phthalic anhydride, or maleic anhydride (structure 4.46). These polyesters may be dissolved in organic solvents and used as cross-linking resins for the production of fibrous glass-reinforced composites ... 

Another resin application based on the same hyperbranched polyester structure described herein is low-VOC alkyds, which have very low viscosity and high reactivity compared to conventional high-solid alkyds. Other resin structures are unsaturated polyesters, polyurethane dispersions, and epoxides. ... 

At the same time, higher temperature of reaction in the 1-step process converts maleic configuration to fumaric configuration. On the contrary, unsaturated polyesters and chloropolyesters for inhibition of DB and CMDB propellants are synthesized by 2-step polyesterification process which imparts more regular structure, better flexibility and greater heat resistance to the resulting polyesters. 

The model structures of cross-linked unsaturated polyesters (on curing with styrene monomer) are depicted in Figure 4.16 A [Structures (4.42) and (4.43)] and Figure 4.16 B. [Structure (4.44)]. 

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