Unsaturated polyester based thermosets

Unsaturated polyester-based thermosets account for >70 % of the total global volume of all the glass fiber-reinforced thermosetting composites currently used (Atkins 1978 Majumdar 2008). 

Bisphenol A Polyester A thermoset unsaturated polyester based on bisphenol A and fumaric acid. 

Polyester Resins. Reinforced polyester resins are thermosets based on unsaturated polyesters from glycols and dibasic acids, either or both of which contain reactive double bonds. The ratio of saturated to unsaturated components controls the degree of cross-linking and thus the rigidity of the product (see Polyesters, unsaturated). Typically, the glycols and acids are esterified until a viscous Hquid results, to which an inhibitor is added to prevent premature gelation. Addition of the monomer, usually styrene, reduces the viscosity to an easily workable level. 

Other uses for depolymerized PET bottles have been investigated. Used bottles have been glycolized and then used to make unsaturated polyester thermosets and polyol components in rigid polyurethane foam. Evco Research announced in 1999 its EvCote waterproof coatings and adhesives based on recycled PET [17, 18]. 

At the outset of the composites industry, the matrices were unsaturated polyesters. Then other thermosets were developed but some years ago the manufacture of thermoplastic composites began and their development is now faster than that of thermoset-based composites. 

Results are presented of experiments undertaken by Gaiker in the manufacture of sandwich panels containing foam cores based on PETP recycled by a solid state polyaddition process developed by M G Ricerche. Panels were produced with glass fibre-reinforced unsaturated polyester and epoxy resin skins, and allthermoplastic panels with PE, PP, PS and glass fibre-reinforced PETP skins were also produced. EVA hot melt adhesives and thermoset adhesives were evaluated in bonding glass fibre-reinforced PETP skins to the foam cores. Data are presented for the mechanical properties of the structures studied. 

Since the introduction of the first commercial thermoset, Bakelite, based on phenol formaldehyde condensation, a wide range of thermoset materials have been introduced. These are typically designed for specific properties related to their chemistry and processability. Some commercially important thermosets include phenolics, ureas, melamines, epoxy resins, unsaturated polyesters, silicones, rubbers, polyurethanes, acrylics, cyanates, polyimides, and benzocyclobutenes. ... 

Unsaturated resins are usually mixtures of vinyl monomers and prepolymers, such as unsaturated polyesters, polyurethane acrylates, and ac-rylated epoxides of the bisphenol A type. Polymerization of styrene-based resins involves the formation of a three-dimensional network via the cross-linking of prepolymer chains by styrene radicals. These standard thermoset resins are therefore characterized by great hardness (Shore D over 80, DIN 53505, arbitrary scale 0-100 based on the penetration of a needle point in the tested material), do not melt, and are not soluble in organic solvents. 

Plastics, particularly polymer-based composites (both thermoplastic and thermoset composites), have been exploited in transportation appUcations for decades. The use of common composites such as glass or carbon fiber reinforced unsaturated polyesters, epoxy, and poly(vinyl ester) matrices is well known. The unique advantage of composites is their strength (tensile strength 4-6 times that of steel) and stiffness, despite their lightweight. 

Such glass fiber-reinforced composites based on the unsaturated polyester thermosets are usually fabricated as sheet molding compounds (SMC) and bulk molding compounds (BMC). These are widely used in various metal replacement applications because of their cost-effectiveness, rigidity, light weight, and corrosion resistance properties particularly useful in transportation (cars and trucks), constmction, pipe, and tank applications. Automotive and tmck body panel and strucmral component applications of SMC include doors, hatchbacks, hoods, front grilles, etc. Some nonautomotive applications of SMC and BMC include sanitaryware (bathtubs, shower stalls, sinks), appliances, business machine, and electrical components. 

EN 1115 Parts 1-7 Plastics piping systems for underground drainage and sewerage under pressure - glass-reinforced thermosetting plastics (GRP) based on unsaturated polyester resin (UP). 

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