Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Two-dimensional detection

The validation of the peak purity is important for selectivity. The efficiency should be optimized to avoid co-elution of different analytes. Two-dimensional detection is a quick and convenient method to check peak purity. CE/UV coupling is most common,and instruments are commercially available. ° The possibilities of CE/MS have already been discussed. The use of several separation systems with different selectivity is a more time-consuming method to test peak purity. [Pg.231]

The first two-dimensional detector in X-ray diffraction was conventional film. It remained for decades the detector of choice for both single crystal as well as powder diffraction experiments. In the field of two-dimensional detection it was surpassed initially by image plates and later by CCD cameras (Figure 14.1). Today virtually no film is in use, with perhaps the exception of Polaroid used for single-crystal images. To be able to compare various detectors with one another, and to select the most appropriate detector for a specific experiment, certain key technical qualities are important. These are in general the detective quantum efficiency, the spatial response characteristics, the size, speed and dynamic range. ... [Pg.414]

Frontal affinity chromatography-mass spectrometry (FAC-MS) is very popular for ligand and inhibitor discovery and design [36], This two-dimensional detection method physically separates compounds by affinity chromatography and determines their identities by MS. Introduced in 1999 [37], FAC-MS is capable of ranking several compounds present in solution in terms of their binding... [Pg.132]

Figure 13. Spatially resolved, spark-excited spectra with a copper sample were obtained by using the two-dimensional detection capabilities of the SIT vidicon. Each spectrum was obtained from an approximately 120-pm-high spatial region along the spark interelectrode axis. The width of the spatial region viewed was approximately 35-iim wide. Emissionfrom 1.0 to 1.3 /is after spark firing was monitored by gating the SIT vidicon intensifier. Vidicon parameters 20 ps/channel, 5 prep scans, 100 readout scans, and 15 tracks each with a delta Y-4. Emission lines detected 1, Ar(II) 324.37 nm 2, Cu(I) 324.76 nm 3, Ar(II) 4, Cu(l) 327.40 nm 5, Ar(III) 328.59 nm 6, Ar(II) 329.36 and329.39 nm and 7, Ar(III) 330.19 nm. Figure 13. Spatially resolved, spark-excited spectra with a copper sample were obtained by using the two-dimensional detection capabilities of the SIT vidicon. Each spectrum was obtained from an approximately 120-pm-high spatial region along the spark interelectrode axis. The width of the spatial region viewed was approximately 35-iim wide. Emissionfrom 1.0 to 1.3 /is after spark firing was monitored by gating the SIT vidicon intensifier. Vidicon parameters 20 ps/channel, 5 prep scans, 100 readout scans, and 15 tracks each with a delta Y-4. Emission lines detected 1, Ar(II) 324.37 nm 2, Cu(I) 324.76 nm 3, Ar(II) 4, Cu(l) 327.40 nm 5, Ar(III) 328.59 nm 6, Ar(II) 329.36 and329.39 nm and 7, Ar(III) 330.19 nm.
The SIT vidicon is a unique and useful spectroscopic detector. Among the most important properties of the SIT vidicon are two-dimensional detection, high sensitivity, and rapid signal recovery. The flexibility of the SIT vidicon detection system is a result of the nature of the signal readout and its compatibility with an on-line computer for control, data acquisition, and data processing and is valuable for research and other nonroutine applications. This flexibility allows the detector to be used in a number of modes and with various degrees of temporal and spatial resolution as demonstrated by the applications described in this paper. [Pg.54]

Figure I represents a two-dimensional damage distribution of an impact in a 0/90° CFRP laminate of 3 mm thickness. Unlike in ultrasonic testing, which is usually the standard method for this problem, there is no shadowing effect on the successive layers by delamination echos. With the method of X-ray refraction the exact concentration of debonded fibers can be calculated for each position averaged over the wall thickness. Additionally the refraction allows the selection of the fiber orientation. The presented X-ray refraction topograph detects selectively debonded fibers of the 90° direction. Figure I represents a two-dimensional damage distribution of an impact in a 0/90° CFRP laminate of 3 mm thickness. Unlike in ultrasonic testing, which is usually the standard method for this problem, there is no shadowing effect on the successive layers by delamination echos. With the method of X-ray refraction the exact concentration of debonded fibers can be calculated for each position averaged over the wall thickness. Additionally the refraction allows the selection of the fiber orientation. The presented X-ray refraction topograph detects selectively debonded fibers of the 90° direction.
RDOs is much smaller than that for the vibration itself, not to mention that for the near-IR FT-Raman teclmique already discussed. This is particularly striking for high energy modes such as the C-H vibrations [108]. Modem applications of I CRS now utilize a two-dimensional time-frequency detection scheme... [Pg.1209]

Tokmakoff A, Lang M J, Larson D S and Fleming G R 1997 Intrinsic optical heterodyne detection of a two-dimensional fifth order Raman response Chem. Phys. Lett. 272 48-54... [Pg.1226]

Barbate G, Ikura M, Kay L E, Pastor R W and Bax A 1992 Backbone dynamics of calmodulin studied by N relaxation using inverse detected two-dimensional NMR spectroscopy the central helix is flexible S/oefrem/sf/ y 31 5269-78... [Pg.1516]

Muns ENDOR mvolves observation of the stimulated echo intensity as a fimction of the frequency of an RE Ti-pulse applied between tlie second and third MW pulse. In contrast to the Davies ENDOR experiment, the Mims-ENDOR sequence does not require selective MW pulses. For a detailed description of the polarization transfer in a Mims-type experiment the reader is referred to the literature [43]. Just as with three-pulse ESEEM, blind spots can occur in ENDOR spectra measured using Muns method. To avoid the possibility of missing lines it is therefore essential to repeat the experiment with different values of the pulse spacing Detection of the echo intensity as a fimction of the RE frequency and x yields a real two-dimensional experiment. An FT of the x-domain will yield cross-peaks in the 2D-FT-ENDOR spectrum which correlate different ENDOR transitions belonging to the same nucleus. One advantage of Mims ENDOR over Davies ENDOR is its larger echo intensity because more spins due to the nonselective excitation are involved in the fomiation of the echo. [Pg.1581]

Area Detectors. A two-dimensional or area detector attached to a powder diffractometer can gready decrease data collection time. Many diffraction appHcations require so much time with a conventional detector that they are only feasible if an area detector is attached to the iastmment. The Siemens General Area Detector Diffraction System (GADDS) uses a multiwire area detector (Fig. 17). This detector measures an x- and ajy-position for each x-ray photon detected. The appHcations foUow. [Pg.381]

Most sample components analyzed with electrophoretic techniques are invisible to the naked eye. Thus methods have been developed to visualize and quantify separated compounds. These techniques most commonly involve chemically fixing and then staining the compounds in the gel. Other detection techniques can sometimes yield more information, such as detection using antibodies to specific compounds, which gives positive identification of a sample component either by immunoelectrophoretic or blotting techniques, or enhanced detection by combining two different electrophoresis methods in two-dimensional electrophoretic techniques. [Pg.183]

Two-dimensional potential measurements on the concrete surface serve to determine the corrosion state of the reinforcing steel. This method has been proved for one-dimensional systems (pipelines), according to the explanation for Fig. 3-24 in Section 3.6.2.1 on the detection of anodic areas. [Pg.432]

Two-dimensional C//correlations such as C//COSY or HC HMQC and HSQC provide the Jqh connectivities, and thereby apply only to those C atoms which are linked to H and not to non-protonated C atoms. Modifications of these techniques, also applicable to quaternary C atoms, are those which are adjusted to the smaller Jqh and Jqh couplings (2-25 Hz, Tables 2.8 and 2.9) Experiments that probe these couplings include the CH COLOC (correlation via long range couplings) with carbon-13 detection (Fig. 2.16) and HC HMBC (heteronuclear multiple bond coherence) with the much more sensitive proton detection (Fig. 2.17)... [Pg.39]

A comparison of the methods of proton-proton NOE detection has shown that two-dimensional NOE detection such as NOESY and ROESY are better suited to the investigation of the stereochemistry of biopolymers whereas for small- to medium-sized molecules (up to 30 C atoms) NOE difference spectroscopy is less time consuming, more selective and thus more conclusive. [Pg.54]


See other pages where Two-dimensional detection is mentioned: [Pg.53]    [Pg.265]    [Pg.163]    [Pg.53]    [Pg.265]    [Pg.53]    [Pg.265]    [Pg.487]    [Pg.110]    [Pg.435]    [Pg.53]    [Pg.268]    [Pg.41]    [Pg.160]    [Pg.53]    [Pg.266]    [Pg.3289]    [Pg.63]    [Pg.53]    [Pg.265]    [Pg.163]    [Pg.53]    [Pg.265]    [Pg.53]    [Pg.265]    [Pg.487]    [Pg.110]    [Pg.435]    [Pg.53]    [Pg.268]    [Pg.41]    [Pg.160]    [Pg.53]    [Pg.266]    [Pg.3289]    [Pg.63]    [Pg.209]    [Pg.1456]    [Pg.2083]    [Pg.2498]    [Pg.290]    [Pg.132]    [Pg.83]    [Pg.482]    [Pg.5]    [Pg.317]    [Pg.109]    [Pg.401]    [Pg.476]    [Pg.194]    [Pg.203]    [Pg.67]    [Pg.70]   
See also in sourсe #XX -- [ Pg.537 ]




SEARCH



Two detection

© 2024 chempedia.info