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Transformation diffuse

Fig. 1. (a) Diffuse reflectance spectra of P25 (thin line), TH (thick line), 3% [PtClJ/P25 (dashed line) and 4.0% H2[PtCl6]/TH (dotted line). The Kubelka-Munk function, F(R00), is used as the equivalent of absorbance, (b) Transformed diffuse reflectance spectra of P25 (thin line), TH (thick line), 3% [PtCl4]/P25 (dashed line) and 4.0% H2[PtCl6]/TH (dotted line). The bandgap energy was obtained by extrapolation of the linear part. [Pg.244]

Bandgap Energies of Some Titania-Based Catalysts Calculated from Transformed Diffuse Reflectance Spectra... [Pg.245]

As for the choice between direct discretisation on an arbitrarily spaced grid or the formulae for the semi-transformed or the transformed diffusion equation, the present author now inclines towards the first of these. Formulae for the derivatives on arbitrarily spaced points are given in Chap. 3 and Appendix A, and the general subroutine U DERIV is referred to in Appendix C. [Pg.111]

Transport from the atmosphere to land and water Dry deposition of particulate and gaseous pollutants Precipitation scavenging of particulate and gaseous pollutants Adsorption of gases onto particles and subsequent diy and wet deposition Transport within the atmosphere Turbulent dispersion and convection Atmospheric transformation Diffusion to the stratosphere Photochemical degradation Oxidation by free radicals and ozone Gas-to-particle conversion... [Pg.272]

Perhaps one of the greatest successes of the molecular dynamics (MD) method is its ability both to predict macroscopically observable properties of systems, such as thermodynamic quantities, structural properties, and time correlation functions, and to allow modeling of the microscopic motions of individual atoms. From modeling, one can infer detailed mechanisms of structural transformations, diffusion processes, and even chemical reactions (using, for example, the method of ab initio molecular dynamics).Such information is extremely difficult, if not impossible, to obtain experimentally, especially when detailed behavior of a local defect is sought. The variety of different experimental conditions that can be mimicked in an MD simulation, such as... [Pg.296]

Mao Z, Quintanilla-Martinez L, Raffeld M, et al. IgVH mutational status and clonality analysis of Richter s transformation Diffuse large B-cell lymphoma and Hodgkin lymphoma in association with B-cell chronic lymphocytic leukemia (B-CLL) represent 2 different pathways of disease evolution. Am Surg Pathol. 2007 31 1605-1614. [Pg.155]

Figure 7. Kubelka-Munk transformed diffuse reflectance spectrum of (A) untreated and (B) calcined catalyst 10-wt% Au on aluminium oxide "C" calcination conditions 400°C, air, 4 h. The change in the plasmon absorbance of the supported gold colloid due to change in particle size can be clearly seen c.f. Figure 2 curves B and C. (the Kubelka-Mumk function F(R) is not the simple absorbance spectrum but is divided by the scattering spectrum of the white alumina support, which is normally assumed to be monotonic F(R) = K/S)... Figure 7. Kubelka-Munk transformed diffuse reflectance spectrum of (A) untreated and (B) calcined catalyst 10-wt% Au on aluminium oxide "C" calcination conditions 400°C, air, 4 h. The change in the plasmon absorbance of the supported gold colloid due to change in particle size can be clearly seen c.f. Figure 2 curves B and C. (the Kubelka-Mumk function F(R) is not the simple absorbance spectrum but is divided by the scattering spectrum of the white alumina support, which is normally assumed to be monotonic F(R) = K/S)...
For unequal time intervals, we look at the example transformed diffusion equation 5.85. This is to be discretised at intervals of SO and H. We use index j to count 0 intervals and i to count X intervals (of H). [Pg.98]

As for the choice between direct discretisation on an arbitrarily spaced grid or the formulae for the semi-transformed or the transformed diffusion equation, the present... [Pg.132]

Of special importance for realization of the controlled gradient formation is an understanding of the reaction mechanism (polymer-analogous transformation /diffusion copolymerization) so that the dmation of the process can be determined in order to control the reaction product. Specifically, the refractive index change with time is investigated, i.e. the function n =J[t) is determined, where n is the refractive index, r is the duration of chemical reaction/diffusion. [Pg.34]

Value of the refractive index of the process product (polymer-analogous transformation/diffusion copolymerization) ... [Pg.34]

It should be specially noted that when radial distribution of the refractive index is formed from one and the same process (polymer-analogous transformation /diffusion copolymerization), two principally different results may be achieved - obtaining of a polymeric medium with the properties of a convex or concave plate lens. [Pg.35]

Actually, if ri (the initial polymer/homopolymer - the product of prepolymerization of gel-polymer) is greater than (the product of polymer-analogous transformation/diffusion copolymerization), then decrease of the process duration with the radius of the polymeric/gel-polymeric film/plate from its periphery to center gives a medium with properties of a convex lens and, vice versa, at the increase of the process duration with sample radius from periphery to center, a medium possessing properties of a concave lens may be obtained. [Pg.35]

The opposite results are obtained, when polymer-analogous transformation /diffusion copolymerization is accompanied by an increase of refractive index, i.e. when ri > 2 In this case, decrease of the process duration by the sample radius from the periphery to the center produces a medium with properties of a concave lens, and increase gives a medium with properties of a convex lens. In this process, the results mentioned are achieved under conditions of injection of an active medium/diffusate and an inert liquid into the reactor under different regimens. [Pg.35]

To set the required duration of the process (polymer-analogous transformation/ diffusion copolymerization) in given directions on the surface of the gradient carrier a device is used that allows use of a diaphragm mask in the contact zone of the gradient former with the gradient earrier. Several teehnical solutions of application of such devices have been... [Pg.35]


See other pages where Transformation diffuse is mentioned: [Pg.23]    [Pg.121]    [Pg.185]    [Pg.285]    [Pg.382]    [Pg.106]    [Pg.148]    [Pg.228]    [Pg.229]    [Pg.310]    [Pg.825]    [Pg.127]    [Pg.180]    [Pg.216]    [Pg.178]   
See also in sourсe #XX -- [ Pg.277 , Pg.280 ]




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Diffuse reflectance Fourier-transform spectroscopy

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Diffuse reflectance infrared Fourier transform spectroscopic

Diffuse reflectance infrared Fourier transform spectroscopy

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Diffuse-reflectance Fourier-transform

Diffuse-reflection Fourier-transform infrared

Diffuse-reflection Fourier-transform infrared spectroscopy

Diffused reflectance IR Fourier transform spectroscopy

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Diffusion Laplace transform

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Diffusion, coefficients transformation

Diffusive transformations

Fourier transform diffusion

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Siliceous, variable-temperature diffuse reflectance Fourier transform infrared

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