Thiolates physical properties

Bismuth salts, 4 25 Bismuth sesquisulfide, 4 24 Bismuth subcarbonate, 4 36 Bismuth subgallate, 4 36 Bismuth subhalides, 4 19 Bismuth subnitrate, 4 36 Bismuth subsalicylate, 4 1, 36 medical applications of, 22 11-12 Bismuth(III) sulfate, 4 25 Bismuth(III) sulfide, 4 24 Bismuth sulfides, 4 24-25 Bismuth thiolates, 4 25 Bismuth-tin alloy waterfowl shot, 4 15 Bismuth triacetate, 4 25 Bismuth tribromide, 4 21 physical properties of, 4 20t Bismuth trichloride, 4 19-20 physical properties of, 4 20t Bismuth trifluoride, 4 19 physical properties of, 4 20t Bismuth trihalides, 4 19 Bismuth triiodide, 4 21-22 physical properties of, 4 20t Bismuth trinitrate pentahydrate, 4 25 Bismuth trioxide, 4 23-24 physical properties of, 4 20t Bismuth triperchlorate pentahydrate, 4 25... 

The kinetics of the deposition of In20i films have not been investigated by many groups, since most of them concentrate on the physical properties and possible applications. The published results are listed in Table 3-8. In addition, there are only two remarks about decomposition pathways. Maruyama andTabata [111] state that indium acetate needs no oxygen as reactant to form indium oxide, i.e., some of the metal-oxygen bonds are not broken during the deposition. Also, as proposed by Nomura and coworkers [122], the butylindium thiolate decomposes via formation of indium sulfides ... 

In the previous sections it has become apparent that Cd(II) thiolate complexes can be readily studied by a number of techniques. The to Cd(II) LMCT transitions observed by UV-visible and circular dichroism spectroscopy, provide a readily accessible technique for studying these systems. It has become apparent that both Cd NMR and Cd PAC spectroscopy are powerful tools with which to study these sites. Metal ion affinity, solvent exchange rates and pATa for Cd(II) binding are related to the nature of the coordination site as well as its location within the protein fold. This section will focus on the relationships that have been established between the physical properties of the Cd(II) thiolate site and the nature of these sites, using the three-stranded coiled coil family of de novo designed proteins. 

Pan, Q.-J. and Zhang, H.-X. (2003) Aurophilic attraction and excited-state properties of binuclear Au(I) complexes with bridging phosphine and/or thiolate ligands An ah initio study. Journal of Chemical Physics, 119, 4346-4352. 

The three different cyanoethyl-masked TTF units 973-975, make it possible to prepare a variety of TTF thiolates bearing one to four thiolate moieties, which allows their incorporation into macrocyclic systems with special physical and chemical properties <19968407, 1997SL1211, 1999S803>. 

Thiolato derivatives of main-group metals provide an interesting contrast to those of the transition metals, since despite the industrial application of compounds such as organotin sulfides, much remains to be done in the study of the chemistry of these interesting compounds. Methods for the preparation of organotin thiolates and selenolates have been reviewed, as have their physical and chemical properties. The preparation of tris(benzenethiolato)-indium by the reaction of InClj with NaSCgHj in methanol has recently been described, as have the properties of this compound. ... 

The first line of mucoadhesive polymers were based on polymer-mucin interaction through physical and/or chemical non-covalent bonds. However, there have been attempts to improve mucoadhesive properties via covalent bonds such as disulfide links between the polymer and the mucin-type glycoproteins. This approach has lead to the development of thiolated polymers where a small... 

The principle of functional group modification is to alter existing physical and chemical properties of chitosan in order to promote its capacity to deliver pDNA. Examples of vectors derived by functional group modification include thiolated chitosan (CSH) and A-acetylated chitosan. 

Abstract There have been remarkable advances in the development of gold nanoclusters protected by thiolates (Au (SR)m), and techniques for the synthesis and characterization of these materials have improved significantly, enabling Au (SR)m to be synthesized with atomic precision. Experiments on the stabilities of clusters synthesized in this way have revealed a series of magic clusters, and the structures and physical and chemical properties of these magic clusters have subsequently been elucidated. Furthermore, several methods have been established for the functionalization of magic clusters. This chapter describes recent developments in Au (SR)m cluster chemistry. 

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