Thiolato derivatives

The polar tellurium(II)-nitrogen bond is readily susceptible to protolysis by weakly acidic reagents. Eor example, the reaction of [Te(NMe2)2]oo with two equivalents of Ph3CSH produces the monomeric thiolato derivative Te(SCPh3)2. Alkynyl tellurides may be prepared by the reaction of terminal acetylenes with arenetellurenamides (Eq. 10.13). ... 

DIAZACYCLOOCTANE, PENDANT ARM THIOLATO DERIVATIVES AND [7V,7V-BIS(2-MERCAPTOETHYL)-l,5-DIAZAC Y CLOOCTAN ATO]NICKEL(II)... 

Thiolato derivatives of Mo 4- were initially elusive,197 but the use of 2,4,6-alkyl-substituted aryl thiolates has permitted the isolation of several such compounds. l,2-[Mo2Q2(NMe2)4] reacts with LiSR (R = Me, Bu ) to produce l,2-[Mo(SR)2(NMe2)4]198 and this compound reacts with RSH (R = 2,4,6-Me3C6H2) to produce [Mo2(SR)6]. [M02L6] (L = NMe2, OPr OBu ... 

Thiolato derivatives of main-group metals provide an interesting contrast to those of the transition metals, since despite the industrial application of compounds such as organotin sulfides, much remains to be done in the study of the chemistry of these interesting compounds. Methods for the preparation of organotin thiolates and selenolates have been reviewed, as have their physical and chemical properties. The preparation of tris(benzenethiolato)-indium by the reaction of InClj with NaSCgHj in methanol has recently been described, as have the properties of this compound. ... 

Mohr and coworkers, inspired by the previous work on thiolato derivatives, combined the thiolato moieties with the NHC ligands (Figure 7.19) [20]. These complexes were studied with two human ovarian cancer cell lines (A2780S and... 

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